Spin-phonon coupling in Gd(Co1/2Mn1/2)O3 perovskite

We have investigated the temperature-dependent Raman-active phonons and the magnetic properties of Gd(Co1/2Mn1/2)O3 perovskite ceramics in the temperature range from 40 K to 300 K. The samples crystallized in an orthorhombic distorted simple perovskite, whose symmetry belongs to the Pnma space group. The data reveals spin-phonon coupling near the ferromagnetic transition occurring at around 120 K. The correlation of the Raman and magnetization data suggests that the structural order influences the magnitude of the spin-phonon coupling.Comment: 3 Figures, suplementary materia

Aportaciones desde la biomecánica de la natación de competición

A natação é uma modalidade individual, cíclica e fechada, pelo que, no respectivo quadro de factores determinantes do sucesso competitivo, a optimização do gesto técnico desempenha um papel determinante.info:eu-repo/semantics/publishedVersio

Energy cost and intracyclic variation of the velocity of the centre of mass in butterfly stroke

The purpose of this study was to examine the relationship between the intra-cycle variation of the horizontal velocity of displacement (dV) and the energy cost (EC) in butterfly stroke. Five Portuguese national level swimmers performed one maximal and two submaximal 200-m butterfly swims. The oxygen consumption was measured breath-by-breath by portable metabolic cart. A respiratory snorkel and valve system with low hydrodynamic resistance was used to measure pulmonary ventilation and to collect breathing air samples. Blood samples from the ear lobe were collected before and after each swim to analyse blood lactate concentration. Total energy expenditure (Etot) and EC were calculated for each swim. The swims were videotaped in the sagittal plane with a set of two cameras providing dual projection from both underwater and above the water surface. The APAS system was used to analyse dV for the centre of mass. The Etot increased linearly with the increasing V, presenting a significant correlation coefficient between these parameters (r=0.827, P<0.001). The increase in EC was significantly associated with the increase in the dV (r=0.807, P<0.001). All data were presented as the mean value and the standard deviation. It is concluded that high intra-cycle variation of the velocity of the centre of mass was related to less efficient swimming and vice versa for the butterfly stroke

Speed fluctuation as a determinant factor of energy cost in Butterfly stroke

The purpose of this study was to examine the relationships between the speed fluctuation of the centre of mass and the EC, in butterfly stroke. Five national level Portuguese swimmers performed one maximal and two sub-maximal (85% and 75%) 200-m butterfly swims in a 25-m swimming pool. Cardio-pulmonary and gas exchange parameters were measured breath by breath for each swim to analyze VO2 and other energetic parameters by portable metabolic cart (K4b2, Cosmed, Rome, Italy). A respiratory snorkel and valve system with low hydrodynamic resistance was used to measure pulmonary ventilation and to collect breathing air samples. Blood samples from the ear lobe were collected before and after each swim to analyze blood lactate concentration (YSI 1500L, Yellow Springs, US). Total energy expenditure (È-tot) and EC were calculated for each swim. The swims were videotaped (50 Hz) in sagital plane with a set of two cameras providing dual-media images from both underwater and above the water surface. The cameras were real time synchronised and the images were edited on a mixing table to create one single image of dual-media. APAS system (Ariel Dynamics Inc, USA) was used to analyse speed fluctuation for the centre of mass. Coefficients of variation for the horizontal velocity of the centre of mass along the stroke cycle (dV) were calculated. Linear regressions between the bioenergetic and biomechanical variables were computed, as well as, its 0.05). Coefficients of determination and correlation (p). There was a significant and linear relationship between È-tot and velocity (r=0.827, p=0.0005). Statistically significant correlation coefficient between the EC and the dV (r=0.807, p=0.0009) was found, the coefficient of determination being r2=0.651. This means that the increase in the EC being strongly associated with the increase in the speed fluctuation. The individual coefficients of correlation and determination between the EC and the dV were very high (mean r2 0.018, ranging from 0.973 to 1.000). The mean of individual correlation È= 0.986 0.009 coefficients was higher than the overall correlation coefficient (r=0.993 vs r=0.807) of the pooled data. It is concluded that the speed fluctuation of the centre of mass was related to less efficient swimming and vice versa in butterfly. We suggest that the swimmers should strive to improve their technique performances by avoiding large variations in the speed fluctuation.info:eu-repo/semantics/publishedVersio

Which mechanism underlies the water-like anomalies in core-softened potentials?

Using molecular dynamics simulations we investigate the thermodynamic of particles interacting with a continuous and a discrete versions of a core-softened (CS) intermolecular potential composed by a repulsive shoulder. Dynamic and structural properties are also analyzed by the simulations. We show that in the continuous version of the CS potential the density at constant pressure has a maximum for a certain temperature. Similarly the diffusion constant, $D$, at a constant temperature has a maximum at a density $\rho_{\mathrm{max}}$ and a minimum at a density $\rho_{\mathrm{min}}<\rho_{\mathrm{max}}$, and structural properties are also anomalous. For the discrete CS potential none of these anomalies are observed. The absence of anomalies in the discrete case and its presence in the continuous CS potential are discussed in the framework of the excess entropy.Comment: 8 page

Determination Of Fluid Viscosity And Femto Newton Forces Of Leishmania Amazonensis Using Optical Tweezers

The displacements of a polystyrene microsphere trapped by an optical tweezers (OT) can be used as a force transducer for mechanical measurements in life sciences such as the measurement of forces of living microorganisms or the viscosity of local fluids. The technique we used allowed us to measure forces on the 200 femto Newtons to 4 pico Newtons range of the protozoa Leishmania amazonensis, responsible for a serious tropical disease. These observations can be used to understand the infection mechanism and chemotaxis of these parasites. The same technique was used to measure viscosities of few microliters sample with agreement with known samples better than 5%. To calibrate the force as a function of the microsphere displacement we first dragged the microsphere in a fluid at known velocity for a broad range of different optical and hydrodynamical parameters. The hydrodynamical model took into account the presence of two walls and the force depends on drag velocity, fluid viscosity and walls proximities, while the optical model in the geometric optics regime depends on the particle and fluid refractive indexes and laser power. To measure the high numerical (NA) aperture laser beam power after the objective we used an integration sphere to avoid the systematic errors of usual power meters for high NA beams. After this careful laser power measurement we obtained an almost 45 degrees straight line for the plot of the optical force (calculated by the particle horizontal displacement) versus hydrodynamic force (calculated by the drag velocity) under variation of all the parameters described below. This means that hydrodynamic models can be used to calibrate optical forces, as we have done for the parasite force measurement, or vice-versa, as we did for the viscosity measurements.593017Ashkin, A., Dziedzic, J.M., Bjorkholm, J.E., Chu, S., Observation of a single-beam gradient force optical trap for dieletric particles (1986) Optics Letters, 11, pp. 288-290Ashkin, A., Dziedzic, J.M., Optical trapping and manipulation of viruses and bacteria (1987) Science, 235, pp. 1517-1520Greulich, K.O., (1999) Micromanipulation by Light in Biology and Medicine, , Basel, Boston, Berlin: BirkhäuserSakata-Sogawa, K., Direct measurement of DNA molecular length in solution using optical tweezers: Detection of looping due to binding protein interactions (1998) Eur. Biophys. J., 27, pp. 55-61Konig, K., Determination of motility forces of human spermatozoa using an 800 nm optical trap (1996) Cell. Mol. Biol., 42, pp. 501-509Barjas-Castro, M.L., Elastic properties of irradiated RBCs measured by optical tweezers (2002) Transfusion, 42, pp. 1196-1199Huruta, R.R., Mechanical properties of stored red blood cells using optical tweezers (1998) Blood, 92, pp. 2975-2977Felgner, H., Muller, O., Schliwa, M., Calibration of light forces in optical tweezers (1995) Appl. Optics, 34, pp. 977-982Svoboda, K., Block, S., Biological applications of optical forces (1994) Annu. Rev. Biophys. Biomolec. Struct., 23, pp. 247-285Henon, S., Lenormand, G., Richert, A., Gallet, F., A new determination of the shear modulus of the human erythrocyte membrane using optical tweezers (1999) Biophys. J., 76, pp. 1145-1151Konig, K., Determination of motility forces of human spermatozoa using an 800nm optical trap (1996) Cell. Mol. Biol., 42, pp. 501-509Who, Whorld Health Organization, 2001Herwaldt, B.L., Leishmanias (1999) Lancet, 354, pp. 1191-1199Killick-Kendrick, R., The life-cycle of Leishmania in the sandfly with special reference to the form infective to the vertebrate host (1990) Ann. Parasitol. Hum. Comp., 65 (1 SUPPL.), pp. 37-42Handman, E., Cell biology of Leishmania (2000) Adv. Parasitol, 44, pp. 1-39Happel, J., Brenner, H., (1991) Low Reynolds Number Hydrodynamics with Special Applications to Particulate Media, , Klumer, Dordrecht(1971) Handbook of Chemistry and Physics, , Chemical Rubber, ClevelandPurcell, E.M., Life at low Reynolds number (1977) Am. J. Phys., 45, pp. 124-13

Relationships between energy cost, swimming velocity and speed fluctuation in elite butterfliers

In swimming science, economy of movement is an interesting field of research. Several investigations have been conducted to understand the role of bioenergetical profile to performance. Most of those studies focused exclusively on the contribution of The individual correlations between E-tot and v ranged from R=0.95 aerobic system to produce energy for movement, even though all competitive swimming events also require significant (p=0.05) to R=0.90 (p&lt;0.01). For pooled data the relationship was contribution from anaerobic energetic system to cover total energy expenditure. R=0.70 (p&lt;0.01). The individual correlations between EC and d

Validation of a cable speedometer for butterfly evaluation

Getting fast results from the evaluation of swimmers is one of the most important goals to achieve with technological development in the field. The purpose of this study was to validate a real-time velocimetric device (speedometer) through the comparison of their results with computer assisted videogrametry. The sample included 7 international level swimmers (3 females and 4 males). Each swimmer performed four 25m trials, two at 200m race pace and two at 50m race pace. For each trial, two stroke cycles were studied, resulting on a total of 28 cycles SWIMMING EVALUATION, ADVICE AND BIOFEEDBACK Rev Port Cien Desp 6(Supl.2) 201–282 237 analysed. Hip v(t) curves obtained from speedometer and videogrametry were compared, as well as the speedometer hip curve with the one of the centre of mass (CM). The higher mean correlation obtained was between vhip1 and vhip2 (0.955±0.028), followed by vhip1 with vCM (0.920±0.049). The lower correlation was vhip2 vs. vCM (0.878±0.053). It was concluded that the speedometer is a reliable, fast and interactive tool for training advice

Time limit at the minimum velocity of VO2max and intracyclic variation of the velocity of the centre of mass

The purpose of this study was to analyse the relationship between time limit at the minimum velocity that elicits maximal oxygen consumption (TLim-vVO2max) and intra-cyclic variations of the velocity of the centre of mass (dv) in the four competitive swimming techniques. Twelve elite male swimmers SWIMMING BIOENERGETICS Rev Port Cien Desp 190 6(Supl.2) 185–197 swam their own best technique until exhaustion at their previously determined v O2max to assess TLim-v O2max. The test was videotaped in the sagittal plan and the APAS software was used to evaluate the horizontal velocity of the centre of mass (Vcm) and its intra-cyclic variation (dv) per swimming technique. Results pointed out that the strokes that presented higher intra-cyclic variations also presented larger values of TLim. Intra-cyclic speed fluctuations (dv) decreased during the TLim test in the four strokes studied, probably due to fatigue. Key words: VO2, intra-cyclic velocity variations, time limit, centre of mass.Authors want to express their gratitude to the Portuguese National Team, and the Portuguese Swimming Federation, for their cooperation

High Verdet Constant Ga:s:la:o Chalcogenide Glasses For Magneto-optical Devices

The magneto-optical rotation at room temperature was measured for three Ga:S:La:O chalcogenide glasses at several laser lines in the visible. The first sample was a binary system constituted by 70 mol % Ga2S3 and 30 mol % La2O3, whereas in the second and third ones the lanthanum oxide was partially substituted by lanthanum sulfide, keeping the amount of gallium sulfide fixed. A pulsed magnetic field between 50 and 80 kG was used for the Faraday rotation measurements. The Verdet constant for one of the ternary samples was found to be as high as 0.205 min G-1 cm-1 at 543 nm, indicating that these chalcogenide glasses are very promising for magneto-optical applications. The data for each sample were fitted using the expected analytical expression for the magneto-optical dispersion. Measurements of the refractive index of the glasses at 632.8 nm are also reported. Data on the magneto-optical properties of two high Verdet constant, heavy-metal oxide diamagnetic glasses are also included for comparison. © 1999 Society of Photo-optical Instrumentation Engineers.382214219Schweizer, T., Hewark, D.W., Payne, D.N., Jensen, T., Huber, G., Rare-earth doped chalcogenide glass laser (1996) Electron. Lett., 32 (7), pp. 666-667Hewark, D.W., Samson, B.N., Medeiros Neto, J.A., Laming, R.I., Payne, D.N., Emission at 1.3 μm from dysprosium-doped GaLaS glass (1994) Electron. Lett., 30 (12), pp. 968-970Kumta, P.N., Risbud, S.H., Rare-earth chalcogenides - An emerging class of optical materials (1994) J. Mater. Sci., 29 (5), pp. 1135-1157De Araujo, M.T., Vermelho, M.V.D., Gouveia Neto, A.S., Sombra, A.S., Medeiros Neto, J.A., Efficient second harmonic generation in praseodymium doped Ga:La:S glass for 1.3 μm optical fiber amplifiers (1996) IEEE Photonics Technol. Lett., 8 (6), pp. 821-823Schulz, P.A., Wavelength independent Faraday isolator (1989) Appl. 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