palaeoproductivity in the ross sea antarctica during the last 15 kyr bp and its link with ice core temperature proxies

AbstractA detailed study of organic carbon content obtained from two sediment cores collected in the Joides basin, western Ross Sea, Antarctica, was carried out. The variations observed during the last deglaciation and the Holocene were compared to the high-resolution climatic records (EPICA DC and Taylor Dome) preserved in the ice. The importance of the carbon content as a proxy for palaeoclimatic and palaeoenvironmental changes was investigated. A dramatic decrease in the Ross Sea palaeoproductivity was observed during the Antarctic Cold Reversal (12.5–14 kyr BP). Another decrease in total organic carbon in the second half of the Holocene (after 5–6 kyr BP) confirms the climate worsening observed in previous studies

From precipitation to ice core: On the importance of surface processes for stable water-isotope records in East Antarctica

Stable water-isotope records from Antarctic ice cores allow the reconstruction of past temperature variability. However, accurate interpretation of the isotopic signal requires comprehensive understanding of the processes leading to its archiving in snow and ice, which can be documented by in situ measurements

Isotopic characterization of Italian industrial hemp (Cannabis sativa L.) intended for food use: a first exploratory study

In this study, Italian industrial hemp (Cannabis sativa L.) intended for food use was isotopically characterized for the first time. The stable isotope ratios of five bioelements were analyzed in different parts of the plant (i.e., roots, stems, inflorescences, and seeds) sampled in eight different regions of Italy, and in five hemp seed oils. The values of δ2H, δ13C, δ18O, and δ34S differed according to the latitude and, therefore, to the geographical origin of the samples and the climate conditions of plant growth, while the δ15N values allowed us to distinguish between crops grown under conventional and organic fertilization. The findings from this preliminary study corroborate the reliability of using light stable isotope ratios to characterize hemp and its derived food products and contribute to the creation of a first isotopic database for this plant, paving the way for future studies on authentication, traceability, and verification of organic labelin

Evaluation of water isotopic composition of Treviso Red Chicory and soil in northern Italy

The stable isotope approach in agricultural research is a fundamental method to understand and partition the water fluxes in the soil-plant-atmosphere continuum. Recent studies suggest that the water used by plant (soil water) could not be the same that contribute to groundwater recharge and streamflow (Evaristo et al., 2015). The aim of this work is to determine the relative contribution of the water reservoir that interest the growth of the Treviso Red Chicory (tardivo and precoce varieties). Two areas were investigated in Veneto (northern Italy): the former, located in Treviso province, is regulated by the Consortium of variegated Red Chicory of Treviso and Castelfranco; the latter is located in Padova province and is not regulated by the Consortium. Precipitation, stream water and groundwater samples have been collected from both sites to determine the isotopic composition (δ18O and δD) of the main water reservoir that could interact with plant physiology. In several studies, different procedures have been developed to extract water from soil and plant, such as lysimeter and centrifugation, respectively. Groundwater, stream water and precipitation samples were analyzed with the CO2 equilibration method using a Thermo Fisher Delta Plus Advantages Mass Spectrometer. We are now developing a cryogenic extraction apparatus to determine both the isotopic composition of plant water (leaves and roots) and soil water (topsoil and subsoil). The next step of the work will be partitioning the relative contribution of water fluxes in the soil-plant-atmosphere system. We think that this approach can be useful for future studies regarding regional traceability of food and to discriminate the plant transpiration process on land water cycle

Climate variability along latitudinal and longitudinal transects in East Antarctica

AbstractIn the framework of the International Trans-Antarctic Scientific Expedition (ITASE) programme, France and Italy carried out a traverse along one west–east and two north–south transects in East Antarctica from November 2001 to January 2002. Eighteen shallow snow–firn cores were drilled, and surface snow samples were collected every 5km along the traverse. Firn temperatures were measured in boreholes down to 30 m. The cores were analyzed for β radioactivity to obtain snow accumulation-rate data. The surface snow samples were analyzed for δ18O to correlate isotopic values with borehole temperatures. Multiple regression analysis shows a global near-dry-adiabatic lapse rate and a latitudinal lapse rate of 1.05˚C(˚ lat. S)–1, in the Dome C drainage area. Analysis of firn temperatures reveals a super-adiabatic lapse rate along the ice divide between Talos Dome and the Southern Ocean coast, and in some sectors along the ice divide between the Astrolabe Basin and D59. Snow accumulation rates and firn temperatures show warmer temperatures and higher accumulation values close to the ice divides extending from Talos Dome and Dome C to the Southern Ocean. The spatial pattern of data is linked with a katabatic-wind-source basin and moisture-source region

Estimation of moisture fluxes in East Antarctica and their impact on the isotopic composition of the snow surface

The ability to infer past temperatures from ice core records has in the past relied on the assumption that after precipitation, the stable water isotopic composition of the snow surface layer is not modified before being buried deeper into the snowpack and transformed into ice. However, in extremely dry environments, such as the East Antarctic plateau, the precipitation is so sparse that the surface is exposed to the atmosphere for significant time before burial. During that exposure, several processes have been recently identified as impacting the snow isotopic composition after snowfall: (1) exchanges with the atmosphere (i.e. sublimation/condensation cycles), (2) wind effects (i.e. redistribution and pumping) and (3) exchanges with the firn below (i.e. metamorphism and diffusion). Here we present the data over several seasons and years of the atmospheric water vapor and snow surface isotopic composition at Dome C, East Antarctica. To understand the link between these two elements, we investigate the moisture fluxes at the surface of the ice sheet, at the snowair interface. No eddy-covariance measurements are available for the recent years, we therefore make use of the available primary meteorological parameters measured continuously on site to estimate the surface moisture fluxes using the bulk method. We estimate that the cumulative effect of the moisture fluxes is positive: about 12% of the mean annual accumulation is sublimated away. Alongside, we see an enrichment in d18O in the snow surface during the summer months, when most of the moisture fluxes are taking place. The snow d-excess is also affected and evolving in anti-phase with d18O. This indicates occurrence of fractionation during sublimation in line with previous field and laboratory studies. The moisture fluxes could be a key driver of changes in the snow isotopic composition between precipitation events influencing the climate signal stored in the isotopic record of ice cores

Characterization of a customized calibration unit for continuous measurements of the isotopic composition of water vapor

The objective of this work is the development, standardization and creation of a method to carry out continuous measurement of oxygen and hydrogen isotopic composition of the atmospheric water vapor using a wavelengthscanned cavity ring down spectroscopy (WS-CRDS) instrument produced by Picarro, L1102-i model. Some technical improvements of the standard instrument configuration have been made to create three different inlet gas lines: a “standard” line, a calibration line and a line connected with the external sampler. The calibration line is composed of a syringe-pump that continuously injects standard water into a steel tee heated at the temperature of 170◦C and flushed with dry nitrogen gas. In this way, instantaneous and complete vaporization of the standard water takes place. The resulting steam is characterized by a well-defined composition in δD e δ18O values. To allow comparison with other international data, we have characterized the individual instrumental response to variation of the isotopic composition of the water vapor. Several humidity-isotope response functions (6000-26000 ppmv) have been estimated with three different internal standards (0.35h -8.75h -29.11h and -40.28h for δ18O; 2.31h -58.91h -222.19h and -317.78h for δD). Moreover, we have measured the instrumental drift at regular time intervals to apply the opportune corrections to instrument data. The setup has been tested using a 3.5 day continuous measurements carried out with the Picarro sampling the water vapor outside our campus in Venice and parallel sampling using the classical cryogenic trapping procedure, obtaining excellent results. Furthermore, our analysis technique has given good results for the standards with values which are similar to those obtained with the isotope ratio mass spectrometry (IRMS) technique

Stable isotopes in water vapor and precipitation for a coastal lagoon at mid latitudes

The stable oxygen and hydrogen isotope composition in precipitation can be used in hydrology to describe the signature of local meteoric water. The isotopic composition of water vapor is usually obtained indirectly from measurements of δD and δ18O in precipitation, assuming the isotopic equilibrium between rain and water vapor. Only few studies report isotopic data in both phases for the same area, thus providing a complete Local Meteoric Water Line (LMWL). The goal of this study is to build a complete LMWL for the lagoon of Venice (northern Italy) with observations of both water vapor and precipitation. The sampling campaign has started in March 2015 and will be carried out until the end of 2016. Water vapor is collected once a week with cold traps at low temperatures (−77◦C). Precipitation is collected on event and monthly basis with a custom automatic rain sampler and a rain gauge, respectively. Liquid samples are analyzed with a Picarro L1102-i and results are reported vs VSMOW. The main meteorological parameters are continuously recorded in the same area by the campus automatic weather station. Preliminary data show an LMWL close to the Global Meteoric Water Line (GMWL) with lower slope and intercept. An evaporation line is clearly recognizable, considering samples that evaporated between the cloud base and the ground. The deviation from the GMWL parameters, especially intercept, can be attributed to evaporated rain or to the humidity conditions of the water vapor source. Water vapor collected during rainfall shows that rain and vapor are near the isotopic equilibrium, just considering air temperature measured at ground level. Temperature is one of the main factor that controls the isotopic composition of the atmospheric water vapor. Nevertheless, the circulation of air masses is a crucial parameter which has to be considered. Water vapor samples collected in different days but with the same meteorological conditions (air temperature and relative humidity) show differences in terms of δ18O up to 3h. Isotopic ratios in rain events and water vapor are in fact dominated by a seasonal component but outliers are clearly linked to air parcel origin. The monthly measurements of δD and δ18O in precipitation of August 2015, for instance, are lower than in colder months, considering monthly average temperatures. Single rain events show a small sequence of precipitation, that leads to 40% of total precipitation of August, which lowers δ−values considerably. The sampling on event basis during occasional and discontinuous rain also allows to identify the rainout effect, which leads to lightening water during a rainfall. Statistics based on back trajectories (48 hours) show that the major part of air parcels travels across central Europe and derives from sources located in the north Atlantic, whereas, a smaller fraction of the water vapor can be attributed to editerranean sources

Volcanic Fluxes Over the Last Millennium as Recorded in the Gv7 Ice Core (Northern Victoria Land, Antarctica)

Major explosive volcanic eruptions may significantly alter the global atmosphere for about 2-3 years. During that period, volcanic products (mainly H2SO4) with high residence time, stored in the stratosphere or, for shorter times, in the troposphere are gradually deposited onto polar ice caps. Antarctic snow may thus record acidic signals providing a history of past volcanic events. The high resolution sulphate concentration profile along a 197 m long ice core drilled at GV7 (Northern Victoria land) was obtained by Ion Chromatography on around 3500 discrete samples. The relatively high accumulation rate (241 +/- 13 mm we yr (-1)) and the 5-cm sampling resolution allowed a preliminary counted age scale. The obtained stratigraphy covers roughly the last millennium and 24 major volcanic eruptions were identified, dated, and tentatively ascribed to a source volcano. The deposition flux of volcanic sulphate was calculated for each signature and the results were compared with data from other Antarctic ice cores at regional and continental scale. Our results show that the regional variability is of the same order of magnitude as the continental one

The spatial variability in isotopic composition of surface snow and snowpits on the East Antarctic Ice Sheet

The water isotope composition of snow precipitations, archived in the Antarctic ice sheet every year, is an important proxy of climatic conditions. This signal depends on several parameters such as local temperature, altitude, moisture source areas and air mass pathways. However, especially in areas where snow accumulation is very low (as on the East Antarctic Plateau), the isotopic composition is affected by additional spatial variability induced by the interactions between the atmosphere and snow surface, and the pristine signal may be modified through isotopic exchanges, sublimation processes and mechanical mixing originated from wind action. Here, we present the isotopic composition (D and 18O) and the second-order parameter d-excess of surface snow and snowpit samples collected during the Italian-French campaign in Antarctica (2019-2020). The sampling sites cover the area from Dumont D'Urville to Concordia Station and from Concordia Station towards the South Pole (EAIIST – East Antarctic International Ice Sheet Traverse). These data, compared with a previous dataset of Antarctic surface snow isotopic composition (Masson-Delmotte et al. 2008), are analyzed to determine the variability of the spatial relationship between precipitation isotopic composition and local temperature in relation to geographical parameters (latitude, distance from the coast and elevation). The interpretation of these factors determining the isotope signature is the base to better define the amount of the effects caused by subsequent interaction between atmosphere and surface snow, and by the wind action. Understanding the spatial variability of this proxy, which strongly decreases the signal-to-noise ratio, could permit to improve the use of the “isotopic thermometer” to quantify past changes in temperature based on the stable isotopic record of deep ice cores