Green Building Materials for Circular Economy - Geopolymer Foams

This study aims to design and investigate foamed geopolymers as a green material dedicated to the circular economy. For synthesis as raw material, the main waste materials of two Polish coal mines, Wieczorek and Staszic, are applied. Additionally, various foaming methods are employed to utilize the by-product of energy production, especially the fly ash generated by the Skawina power plant. In this study, the main issues addressed are related to the selection of the most appropriate foaming agent and the optimization of the process parameters, including temperature, time, and mixture components. Hydrogen peroxide, aluminum powder, and a commercial foaming agent are selected as foaming agents in this research. During the process of sample preparation, stabilizers are applied in the form of polyglycol and cellulose. Through the conducted test, the results show that hydrogen peroxide and aluminum powder emerged as the two most optimal foaming agents

<scp>ReSurveyEurope</scp>: A database of resurveyed vegetation plots in Europe

AbstractAimsWe introduce ReSurveyEurope — a new data source of resurveyed vegetation plots in Europe, compiled by a collaborative network of vegetation scientists. We describe the scope of this initiative, provide an overview of currently available data, governance, data contribution rules, and accessibility. In addition, we outline further steps, including potential research questions.ResultsReSurveyEurope includes resurveyed vegetation plots from all habitats. Version 1.0 of ReSurveyEurope contains 283,135 observations (i.e., individual surveys of each plot) from 79,190 plots sampled in 449 independent resurvey projects. Of these, 62,139 (78%) are permanent plots, that is, marked in situ, or located with GPS, which allow for high spatial accuracy in resurvey. The remaining 17,051 (22%) plots are from studies in which plots from the initial survey could not be exactly relocated. Four data sets, which together account for 28,470 (36%) plots, provide only presence/absence information on plant species, while the remaining 50,720 (64%) plots contain abundance information (e.g., percentage cover or cover–abundance classes such as variants of the Braun‐Blanquet scale). The oldest plots were sampled in 1911 in the Swiss Alps, while most plots were sampled between 1950 and 2020.ConclusionsReSurveyEurope is a new resource to address a wide range of research questions on fine‐scale changes in European vegetation. The initiative is devoted to an inclusive and transparent governance and data usage approach, based on slightly adapted rules of the well‐established European Vegetation Archive (EVA). ReSurveyEurope data are ready for use, and proposals for analyses of the data set can be submitted at any time to the coordinators. Still, further data contributions are highly welcome.</jats:sec

An Investigation of the Ground Walnut Shells&rsquo; Addition Effect on the Properties of the Fly Ash-Based Geopolymer

The development of geopolymers is in line with the requirements of sustainable development. Creating a new type of material from various industrial and bio-based wastes and by-products can lead to reduced energy consumption, reduced waste generation, reduced global CO2 emissions, as well as reduced resource extraction of natural resources. In this study, geopolymer composites based on class F fly ash with the addition of fine quartz sand and ground walnut shells used as a substitute for sand were examined. The study focused on investigating the effects of different weight percentages of ground walnut shells and quartz sand on the density and strength properties, including compressive and flexural strength, thermal conductivity, efflorescence formation, and water absorption of the fly ash-based geopolymer composites. The microstructure of the studied geopolymers was also analyzed using a scanning electron microscope (SEM). It was observed that the addition of ground walnut shells contributes to the decrease in density and mechanical properties, increase in absorption properties, and decrease in porosity of fly ash-based geopolymers. Furthermore, the addition of ground walnut shells allows for a significant reduction in efflorescence on the surface of the tested geopolymer composites. Moreover, partial or complete replacement of sand by ground walnut shells in geopolymer composites based on fly ash allows for a significant reduction in their thermal conductivity, which makes it possible to use these composites as insulation materials

The Influence of Nanographite Addition on the Compaction Process and Properties of AISI 316L Sintered Stainless Steel

This paper presents the effect of graphite addition on the pressing process and selected mechanical properties of AISI 316L austenitic stainless steel. The graphite powders used in this study differed in the value of the specific surface area of the particles, which were 15 (micropowder), 350, and 400 m2/g (nanopowder). Mixtures with the addition of lubricants&mdash;stearic acid and Kenolube&mdash;were also created, for comparison purposes. The scope of the tests included compressibility of blends, measurements of the ejection force while removing the compacts from the die, micro-structural studies, a static tensile test, a three-point bending test, a Kc impact test, Rockwell hardness, and Vickers microhardness measurements. The study demonstrated that the addition of graphite nanopowder to the studied steel acts as a lubricant, providing a significant improvement in lubricity during the pressing process. Moreover, the addition of nanographite allowed for a significant increase in the mechanical properties studied in this work; it was observed that, for the sinters made of mixtures with a higher graphite content and with a large specific surface area of its particles, better values for the tested properties were obtained

Electrochemical properties of redox mediators at carbon electrodes

Chapter1 gives an overview of the basic principles of electrochemistry.A rigorous electrochemical study on the solution phase and solid phase cobalt phthalocyanine (CoPC) is presented in chapter2. The formof CoPC on carbon electrodes was characterized by scanning electron microscope (SEM). The use of CoPC modified edge plane pyrolytic graphite (CoPC-EPPG) for sensing nitrite (NO₂⁻) was also investigated. It was found that the claimed mediator CoPC has no influence on the process. A bare glassy carbon (GC) electrode was successfully applied for the quantitative determination of nitrite as a simple alternative to the modified electrodes reported in the literature (chapter3).Chapter4 compares the voltammetric responses of an edge plane pyrolytic graphite electrode covalently modifed with 2-anthraquinonyl groups (EPPG-AQ2) and solution phase anthraquinone monosulphonate (AQMS) in the presence of a limited concentration of protons. The solution phase and surface bound species show analogous responses resulting in split waves. Digisim™ simulation of the AQMS voltammetry have shown that the pH adjacent to the electrode may be altered by up to 5-6 pH units in low buffered solutions; this is caused by the consumption of protons during the electrochemical reaction.Chapters5 and 6 compare the electrochemical properties of 2-anthraquinonyl groups covalently attached to an edge plane pyrolytic graphite (EPPG) and to a gold electrode. In both cases simulations using newly developedMarcus-Hush-Chidsey theory for a 2e⁻ process assuming a uniform surface did not achieve a good agreement between theory and experiment. Subsequently two models of surface inhomogeneity were investigated: a distribution of formal potentials, EӨ, and a distribution of electron tunneling distances, r₀. For both EPPG-AQ2 and Au-AQ2 modified electrodes the simulation involving EӨ distribution turned out to be the most adequate. This is the first time that Marcus-Hush-Chidsey theory has been applied to a 2e⁻ system.Chapter7 briefly summarizes the obtained results.</p

An Investigation of the Ground Walnut Shells’ Addition Effect on the Properties of the Fly Ash-Based Geopolymer

The development of geopolymers is in line with the requirements of sustainable development. Creating a new type of material from various industrial and bio-based wastes and by-products can lead to reduced energy consumption, reduced waste generation, reduced global CO2 emissions, as well as reduced resource extraction of natural resources. In this study, geopolymer composites based on class F fly ash with the addition of fine quartz sand and ground walnut shells used as a substitute for sand were examined. The study focused on investigating the effects of different weight percentages of ground walnut shells and quartz sand on the density and strength properties, including compressive and flexural strength, thermal conductivity, efflorescence formation, and water absorption of the fly ash-based geopolymer composites. The microstructure of the studied geopolymers was also analyzed using a scanning electron microscope (SEM). It was observed that the addition of ground walnut shells contributes to the decrease in density and mechanical properties, increase in absorption properties, and decrease in porosity of fly ash-based geopolymers. Furthermore, the addition of ground walnut shells allows for a significant reduction in efflorescence on the surface of the tested geopolymer composites. Moreover, partial or complete replacement of sand by ground walnut shells in geopolymer composites based on fly ash allows for a significant reduction in their thermal conductivity, which makes it possible to use these composites as insulation materials

Electrochemical properties of redox mediators at carbon electrodes

Chapter1 gives an overview of the basic principles of electrochemistry. A rigorous electrochemical study on the solution phase and solid phase cobalt phthalocyanine (CoPC) is presented in chapter2. The formof CoPC on carbon electrodes was characterized by scanning electron microscope (SEM). The use of CoPC modified edge plane pyrolytic graphite (CoPC-EPPG) for sensing nitrite (NO₂⁻) was also investigated. It was found that the claimed mediator CoPC has no influence on the process. A bare glassy carbon (GC) electrode was successfully applied for the quantitative determination of nitrite as a simple alternative to the modified electrodes reported in the literature (chapter3). Chapter4 compares the voltammetric responses of an edge plane pyrolytic graphite electrode covalently modifed with 2-anthraquinonyl groups (EPPG-AQ2) and solution phase anthraquinone monosulphonate (AQMS) in the presence of a limited concentration of protons. The solution phase and surface bound species show analogous responses resulting in split waves. Digisim™ simulation of the AQMS voltammetry have shown that the pH adjacent to the electrode may be altered by up to 5-6 pH units in low buffered solutions; this is caused by the consumption of protons during the electrochemical reaction. Chapters5 and 6 compare the electrochemical properties of 2-anthraquinonyl groups covalently attached to an edge plane pyrolytic graphite (EPPG) and to a gold electrode. In both cases simulations using newly developedMarcus-Hush-Chidsey theory for a 2e⁻ process assuming a uniform surface did not achieve a good agreement between theory and experiment. Subsequently two models of surface inhomogeneity were investigated: a distribution of formal potentials, EӨ, and a distribution of electron tunneling distances, r₀. For both EPPG-AQ2 and Au-AQ2 modified electrodes the simulation involving EӨ distribution turned out to be the most adequate. This is the first time that Marcus-Hush-Chidsey theory has been applied to a 2e⁻ system. Chapter7 briefly summarizes the obtained results.EThOS - Electronic Theses Online ServiceGBUnited Kingdo

An Overview for Modern Energy-Efficient Solutions for Lunar and Martian Habitats Made Based on Geopolymers Composites and 3D Printing Technology

Space missions will require the capability to build structures on site using local resources. Before 2040, NASA and the European Space Agency want to ensure the possibility of a permanent human residence in shelters on the Moon or Mars. The article analyzed the state of the art in this area based on the literature research. It shows innovative and energy efficient solutions for manufacturing the lunar and Martian shelters based on geopolymer composites. Firstly, the possible materials solutions, with particular attention to the geopolymer composites, are discussed. Next, the previous research is presented, including work based on different kinds of simulants of lunar and Martian regolith. Then, a different approach for manufacturing technologies is presented and the advantages of 3D printing technology are clarified. Eventually, the challenges for further projects are discussed, including energy and cost efficiency problems