Thermal calcination-based production of SnO2 nanopowder: an analysis of SnO2 nanoparticle characteristics and antibacterial activities

SnO2 nanoparticle production using thermal treatment with tin(II) chloride dihydrate and polyvinylpyrrolidone capping agent precursor materials for calcination was investigated. Samples were analyzed using X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), energy dispersive X-ray (EDX), transmission electron microscopy (TEM), Fourier Transform Infrared Spectroscopy (FT-IR), X-ray photoelectron spectroscopy (XPS), diffuse UV-vis reflectance spectra, photoluminescence (PL) spectra and the electron spin resonance (ESR). XRD analysis found tetragonal crystalline structures in the SnO2 nanoparticles generated through calcination. EDX and FT-IR spectroscopy phase analysis verified the derivation of the Sn and O in the SnO2 nanoparticle samples from the precursor materials. An average nanoparticle size of 4–15.5 nm was achieved by increasing calcination temperature from 500 °C to 800 °C, as confirmed through TEM. The valence state and surface composition of the resulting nanoparticle were analyzed using XPS. Diffuse UV-vis reflectance spectra were used to evaluate the optical energy gap using the Kubelka-Munk equation. Greater calcination temperature resulted in the energy band gap falling from 3.90 eV to 3.64 eV. PL spectra indicated a positive relationship between particle size and photoluminescence. Magnetic features were investigated through ESR, which revealed the presence of unpaired electrons. The magnetic field resonance decreases along with an increase of the g-factor value as the calcination temperature increased from 500 °C to 800 °C. Finally, Escherichia coli ATCC 25922 Gram (–ve) and Bacillus subtilis UPMC 1175 Gram (+ve) were used for in vitro evaluation of the tin oxide nanoparticle’s antibacterial activity. This work indicated that the zone of inhibition of 22 mm has good antibacterial activity toward the Gram-positive B. subtilis UPMC 1175

Comprehensive study on morphological, structural and optical properties of Cr2O3 nanoparticle and its antibacterial activities

Chromium (III) oxide (Cr2O3) nanoparticles are generated by thermal treatment (calcination) of precursor materials such as chromium nitrate along with a poly (vinyl pyrrolidone) capping agent. The samples produced were characterised by various techniques, including X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), transmission electron microscopy (TEM) and Fourier transform infrared spectroscopy (FT-IR). Examination results obtained from XRD showed that Cr2O3 nanoparticles exhibit hexagonal crystalline structures, with the presence of Cr and O in these novel materials being confirmed by results of analyses of both EDX and FT-IR. Results of TEM have pointed out that the average nanoparticle size was noticeably increased from 28 to 46 nm in relation to increase of calcination temperature of a range between 500 and 800 °C. The surface composition and valence state of the produced nanoparticles were examined by X-ray photoelectron spectroscopy (XPS), the optical energy gap has been evaluated using UV–visible reflectance spectra with the help of Kubelka–Munk equation. The energy band gap had a reversely proportional relationship with calcination temperature with a reduction in energy band gap from 3.12 to 3.01 eV. Photoluminescence (PL) spectra indicated an increase in photoluminescence with increasing particle size. The antibacterial activity of the Cr2O3 nanoparticles was evaluated in-vitro using gram-negative Escherichia coli ATCC 25922 and gram-positive Bacillus subtilis UPMC 1175

The effect of precursor concentration on the particle size, crystal size, and optical energy gap of CexSn1â’xO2 nanofabrication

In the present work, a thermal treatment technique is applied for the synthesis of CexSn1−xO2 nanoparticles. Using this method has developed understanding of how lower and higher precursor values affect the morphology, structure, and optical properties of CexSn1−xO2 nanoparticles. CexSn1−xO2 nanoparticle synthesis involves a reaction between cerium and tin sources, namely, cerium nitrate hexahydrate and tin (II) chloride dihydrate, respectively, and the capping agent, polyvinylpyrrolidone (PVP). The findings indicate that lower x values yield smaller particle size with a higher energy band gap, while higher x values yield a larger particle size with a smaller energy band gap. Thus, products with lower x values may be suitable for antibacterial activity applications as smaller particles can diffuse through the cell wall faster, while products with higher x values may be suitable for solar cell energy applications as more electrons can be generated at larger particle sizes. The synthesized samples were profiled via a number of methods, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). As revealed by the XRD pattern analysis, the CexSn1−xO2 nanoparticles formed after calcination reflect the cubic fluorite structure and cassiterite-type tetragonal structure of CexSn1−xO2 nanoparticles. Meanwhile, using FT-IR analysis, Ce-O and Sn-O were confirmed as the primary bonds of ready CexSn1−xO2 nanoparticle samples, whilst TEM analysis highlighted that the average particle size was in the range 6−21 nm as the precursor concentration (Ce(NO3)3·6H2O) increased from 0.00 to 1.00. Moreover, the diffuse UV-visible reflectance spectra used to determine the optical band gap based on the Kubelka–Munk equation showed that an increase in x value has caused a decrease in the energy band gap and vice versa

Synthesis, structural and optical characterization of CuO, CeO₂ and (CuO)ₓ(CeO₂)₁-ₓ nanoparticles via thermal treatment method

Metal oxide semiconductor nanocrystals are regarded as one of the most important inorganic nanomaterials because of their electronic, optical, electrical and magnetic, properties. These properties are dependent on the chemical composition and microstructural characteristics in which the particle size and shape might be controlled in the fabrication processes. Amongst all metal oxide nanoparticles (NPs), copper oxide (CuO), cerium oxide (CeO2) and (CuO)x(CeO2)1-x NPs have intriguing properties for the development of novel electronic devices, solar cell, sensor, catalyst and medical applications due to their excellent optical and electronic properties. Therefore, further study is needed to synthesize by other methods and characterize these properties. CuO, CeO2 and binary (CuO)x(CeO2)1-x NPs were successfully synthesized by thermal treatment method.The XRD diffraction patterns reveal monoclinic structure for CuO NPs and cubic fluorite structure for CeO2 NPs. With no other impurities can be detected, indicating the high purity of the final products. The crystallite size was found to increase from 12.64-25.76, 8.71-22.74 and 5.12-15.34 nm for CuO and 6.45-22.18, 7.25-18.76 and 6.15-11.43 nm for CeO2 with evolution in calcination temperatures 500-800 οC at a concentration of PVP 0.03, 0.04 and 0.05 g/ml respectively. These results were in agreement with the transition electron microscopy results which showed the formation of CuO and CeO2 in nanoscale size. The average particle size estimated by TEM was found to increase from15.53 to 30.00 nm, 9.75 to 23.54 nm and 4.25 to 16.93 nm for CuO and 5.15 to 24.19 nm, 4.32 to 20.24 nm and 3.00 to 10.62 nm for CeO2 with increase in calcination temperature 500-800 οC at a concentration of PVP 0.03, 0.04 and 0.05 g/ml respectively. The FTIR results confirmed the removal of polymer and the presence of metal oxides nanoparticles at calcination temperatures 500-800 oC. The elemental composition of the samples obtained by EDX spectroscopy has further evidenced the formation highly pure CuO and CeO2 NPs. Furthermore, the optical band gap of the samples was calculated using Kubelka-Munk function for calcination temperatures 500-800 oC. The band gap was found to decrease from 2.56 to 2.34 eV, 2.75 to 2.42 eV and 2.78 to 2.46 eV for CuO and 3.37 to 3.31eV, 3.38 to 3.32 eV and 3.45 to 3.41 eV for CeO2 at a concentration of PVP 0.03, 0.04 and 0.05 g/ml respectively. A reduction in the energy band gap with increasing calcination temperatures is attributed to the increase in the particle size. The PL spectra at calcination temperatures 500-800 oC showed that the increment in the intensity with increasing calcination temperatures is attributed to the expansion in the particle size. Due to the control over particle sizes of CuO and CeO2 that this technique allows by the varying of PVP concentration and calcination temperature, semiconductor materials with wide band gaps can be produced. These materials are able to absorb UV–visible wavelengths of solar energy, making them suitable for use within solar cell applications. Furthermore, CeO2 materials produced by this method may be acceptable for use in manufacturing UV filters, catalysts and photoelectric devices. From the XRD diffraction patterns results, the prepared (CuO)x(CeO2)1-x NPs at different calcination temperatures range from 500-800 οC showed that the crystallite size was increased in the range of 11.25-34.17 nm for (CuO)0.6(CeO2)0.4 with monoclinic and cubic fluorite structures together with no other impurities can be detected, indicating the high purity of the final products. These results were in agreement with the transition electron microscopy results which showed the formation of (CuO)x(CeO2)1-x in nanoscale size. The average particle size determined by TEM was found to increase 11.96-31.83 nm for (CuO)0.8(CeO2)0.2 and 2.97-10.70 nm for (CuO)0.2(CeO2)0.8 with increase in calcination temperature 500-800 οC respectively. At the lower concentration of CuO and with calcination temperature, the particle size smaller and consistent for binary (CuO)x(CeO2)1-x. The FTIR results confirmed the removal of polymer and the presence of metal oxide nanoparticles at calcination temperatures 500-800 oC. The elemental composition of the samples obtained by EDX spectroscopy has further evidenced the formation of (CuO)x(CeO2)1-x nanoparticles. In addition, the optical band gap of the samples was calculated using Kubelka-Munk function for calcination temperatures 500-800 oC. The band gap was found to decrease from in the range of 2.82, 3.22 to 2.72, 3.13 eV for (CuO)0.8(CeO2)0.2 and 2.90, 3.30 to 2.83, 3.24 eV for (CuO)0.2(CeO2)0.8. A decrease in the energy band gap with increasing calcination temperatures is attributed to the increase in the particle size. The PL spectra at calcination temperatures 500-800 oC showed that the increment in the intensity with increasing calcination temperatures is attributed to the increase in the particle size. Due to the control over (CuO)x(CeO2)1-x particle sizes that this technique allows by the varying of PVP concentration and calcination temperature, semiconductor materials with multiple band gaps can be produced. These materials are able to absorb specific wavelengths of solar energy, making them very suitable for use within solar cell and sensor applications

Radiation-induced synthesis, electrical and optical characterization of conducting polyaniline of PANI/ PVA composites

This study employs the gamma radiation technique to produce conducting polyaniline from an aqueous solution. The solution comprises four materials: ANI, PVA, CaCl2 and distilled H2O, which serve as a binder or film support, precursor, Cl ions provider, and a solvent. To obtain the conducting polyaniline (PANI/PVA) composite, a film of ANI/ PVA/ CaCl2 was subjected to gamma radiation under ambient conditions. Conducting polyaniline composite was seen to form once the colour began to change from white to green in accordance with the doses of radiation. The results demonstrated that the level of gamma radiation increased to 30 KGy, thereby confirming that the electrical insulation ANI/ PVA/ CaCl2 film was converted into electrically conductive polyaniline composite film. In addition, the measurements of UV–Visible spectrophotometer revealed an absorption band of 795 nm rises alongside the radiation dose which produced PANI/PVA with a green hue that increases in intensity in accordance with rises in the doses of radiation

Morphological, structural and optical behaviour of PVA capped binary (NiO)0.5 (Cr2O3)0.5 nanoparticles produced via single step based thermal technique

In this research study, a thermal treatment approach based on a novel single-step has been utilised to addresses the synthesis of binary NiO0.5 Cr2O3 0.5 nanoparticles. Characteristics of these binary metal oxide nanoparticles were examined by employing appropriate characterization tools. Sample patterns of X-ray diffractions were used, calcined with temperature (Temp), set to 500 °C revealed the existence of face-centred cubic (fcc) and hexagonal crystalline structures (hcs). It was noted that with a rising calcination temperature, the nanoparticle dispersal was enhanced further. On the other hand, TEM micrographs have been used to calculate the size of the mean particle. It was found that there was a rising tendency with the increased calcination temperature and this the growth of the mean particle. Increased particle size inherited a rise of nanoparticles' photoluminescence intensity, as suggested by recorded spectra, and various energy band gaps. This result would have been reduced as an effect once calcination temperature was increased. Resulting NiO0.5 Cr2O3 0.5 nanoparticles could be used in the realm of semiconductors and energy applications