The intensity contrast of solar granulation: comparing Hinode SP results with MHD simulations

The contrast of granulation is an important quantity characterizing solar surface convection. We compare the intensity contrast at 630 nm, observed using the Spectro-Polarimeter (SP) aboard the Hinode satellite, with the 3D radiative MHD simulations of V{\"o}gler & Sch{\"u}ssler (2007). A synthetic image from the simulation is degraded using a theoretical point-spread function of the optical system, and by considering other important effects. The telescope aperture and the obscuration by the secondary mirror and its attachment spider, reduce the simulated contrast from 14.4 % to 8.5 %. A slight effective defocus of the instrument brings the simulated contrast down to 7.5 %, close to the observed value of 7.0 %. A proper consideration of the effects of the optical system and a slight defocus, lead to sufficient degradation of the synthetic image from the MHD simulation, such that the contrast reaches almost the observed value. The remaining small discrepancy can be ascribed to straylight and slight imperfections of the instrument, which are difficult to model. Hence, Hinode SP data are consistent with a granulation contrast which is predicted by 3D radiation MHD simulations.Comment: 5 pages, 4 figures, to be published in A&

Vacuum-Ultraviolet Photoionization and Mass Spectrometric Characterization of Lignin Monomers Coniferyl and Sinapyl Alcohols

The fragmentation mechanisms of monolignols under various energetic processes are studied with jet-cooled thermal desorption molecular beam (TDMB) mass spectrometry (MS), 25 keV Bi3+ secondary ion MS (SIMS), synchrotron vacuum-ultraviolet secondary neutral MS (VUV-SNMS) and theoretical methods. Experimental and calculated appearance energies of fragments observed in TDMB MS indicate that the coniferyl alcohol photoionization mass spectra contain the molecular parent and several dissociative photoionization products. Similar results obtained for sinapyl alcohol are also discussed briefly. Ionization energies of 7.60 eV ? 0.05 eV for coniferyl alcohol and<7.4 eV for both sinapyl and dihydrosinapyl alcohols are determined. The positive ion SIMS spectrum of coniferyl alcohol shares few characteristic peaks (m/z = 137 and 151) with the TDMB mass spectra, shows extensive fragmentation, and does not exhibit clear molecular parent signals. VUV-SNMS spectra, on the other hand, are dominated by the parent ion and main fragments also present in the TDMB spectra. Molecular fragmentation in VUV-SNMS spectra can be reduced by increasing the extraction delay time. Some features resembling the SIMS spectra are also observed in the desorbed neutral products. The monolignol VUV-SNMS peaks shared with the TDMB mass spectra suggest that dissociative photoionization of ion-sputtered neutral molecules predominate in the VUV-SNMS mass spectra, despite the extra internal energy imparted in the initial ion impact. The potential applications of these results to imaging mass spectrometry of bio-molecules are discussed

New empiricisms in the Anthropocene: Thinking with speculative fiction about science and social inquiry

Interest in new empiricisms and transdisciplinary methods has led many social inquirers to engage with 20th-century post-classical physical science. Many of these projects have focused on alternative matter–mind mixtures and in/organic variation, concerned that past theories of sociality have dismissed the vibrancy and animacy of the nonhuman material world. This paper explores the power of speculative fiction to help us rethink empiricism in posthuman ecologies of the Anthropocene, in the midst of post-truth conditions and growing science denialism. We foreground speculative fiction as a way to open up scientific imaginaries, rethinking the relationship between nature, technics, and human “sense” making. We show how such texts offer alternative images of research methods for studying pluralist ecologies and new forms of worldly belonging

Emergence of complexity inhierarchically organized chiral particles

The structural complexity of composite biomaterials and biomineralized particles arises from the hierarchical ordering of inorganic building blocks over multiple scales. While empirical observations of complex nanoassemblies are abundant, physicochemical mechanisms leading to their geometrical complexity are still puzzling, especially for non-uniformly sized components. Here we report the assembly of hierarchically organized particles (HOPs) with twisted spikes and other morphologies from polydisperse Au-Cys nanoplatelets. The complexity of Au-Cys HOPs is higher than biological counterparts or other complex particles as enumerated by graph theory methods. Their intricate organization emerges from competing chirality-dependent assembly restrictions that render assembly pathways primarily dependent on nanoparticle symmetry rather than size. These findings and HOPs phase diagrams open a pathway to a large family of colloids with complex architectures and unusual chiroptical and chemical properties