Discovery of Li2(Pd,Pt)3B superconductors

Critical temperature Tc of the Li2(Pd1-xPtx)3B was reported to be 7-8K for x=0 and 2.2-2.8K for x=1. In this article we present our preliminary results on behavior of magnetization-temperature curves with starting composition of Pd-B precursor, y-Li concentration in LiyPd3B and post-annealing of the Pd-end compound. Results suggest that to maximize Tc ratio Pd:B should be close to 3:1, while y-Li has to be optimum. The lowest Tc for LiyPd3B was 4.4-4.6K, while post-annealings at 560 deg. C allowed enhancement of Tc up to 8.2-8.4K. Compositions Li2Z3B with Z=Ni, Ru, Rh, Re, Ag are not superconducting down to 1.8K. Exception is composition with Re showing superconductivity due to Re3B compound. All samples were prepared by arc melting.Comment: 6 pages, 5 figs. presented at M2S, 200

Non-centro-symmetric superconductors Li2Pd3B and Li2(Pd0.8Pt0.2)3B: amplitude and phase fluctuations analysis of the experimental magnetization data

We report on magnetization data obtained as a function of temperature and magnetic field in Li2 (Pd0.8Pt0.2)3B and Li2Pd3B non-centro-symmetric superconductors. Reversible magnetization curves were plotted as M1/2 vs. T. This allows study of the asymptotic behavior of the averaged order parameter amplitude (gap) near the superconducting transition. Results of the analysis show, as expected, a mean field superconducting transition for Li2Pd3B. On contrary, a large deviation from the mean field behavior is revealed for Li2(Pd0.8Pt0.2)3B. This is interpreted as due to the strength of the non s-wave spin-triplet pairing in this Pt-containing compound which produces nodes in the order parameter and consequently, phase fluctuations. The diamagnetic signal above Tc(H) in Li2Pd3B is well explained by superconducting Gaussian fluctuations, which agrees with the observed mean field transition. For Li2(Pd0.8Pt0.2)3B the diamagnetic signal above Tc(H) is much higher than the expected Gaussian values and appears to be well explained by three dimensional critical fluctuations of the lowest-Landau-level type, which somehow agrees with the scenario of a phase mediated transition.Comment: 7 pages (1 column) 3 figure

A Penetration Depth Study on Li2Pd3B and Li2Pt3B

In this paper we present a penetration depth study on the newly discovered superconductors Li$_2$Pd$_3$B and Li$_2$Pt$_3$B. Surprisingly, the low-temperature penetration depth $f(T)$ demonstrates distinct behavior in these two isostructural compounds. In Li$_2$Pd$_3$B, $f(T)$ follows an exponential decay and can be nicely fitted by a two-gap BCS superconducting model with a small gap $\delta_1=3.2$K and a large gap $\delta_2=11.5$K. However, linear temperature dependence of $f(T)$ is observed in Li$_2$Pt$_3$B below 0.3$T_c$, giving evidence of line nodes in the energy gap.Comment: 2 pages, submitted to LT2

Superconductivity in metal rich Li-Pd-B ternary Boride

8K superconductivity was observed in the metal rich Li-Pd-B ternary system. Structural, microstructural, electrical and magnetic investigations for various compositions proved that Li2Pd3B compound, which has a cubic structure composed of distorted Pd6B octahedrons, is responsible for the superconductivity. This is the first observation of superconductivity in metal rich ternary borides containing alkaline metal and Pd as a late transition metal. The compound prepared by arc melting has high density, is stable in the air and has an upper critical field, Hc2(0), of 6T.Comment: 4 pages, 5 figur

Landau and Ott scaling for the kinetic energy density and the low TcT_c conventional superconductors, Li2Pd3BLi_{2}Pd_{3}B and Nb

The scaling approach recently proposed by Landau and Ott for isothermal magnetization curves is extended to the average kinetic energy density of the condensate. Two low $T_c$ superconductors, Nb and $Li_{2}Pd_{3}B$ are studied and their isothermal reversible magnetization shown to display Landau and Ott scaling. Good agreement is obtained for the upper critical field $H_{c2}(T)$, determined from the Abrikosov approximation for the reversible region (standard linear extrapolation of the magnetization curve), and from the maximum of the kinetic energy curves. For the full range of data, which includes the irreversible region, the isothermal $d.M.B/H^2$ curves for $Li_2Pd_3B$ show an impressive collapse into a single curve over the entire range of field measurements. The Nb isothermal $d.M.B/H^2$ curves exhibit the interesting feature of a constant and temperature independent minimum value

Evidence of large anisotropy in the magnetization of Na0.35CoO2.1.3H2O quasi-single-crystal superconductors

Quasi-single crystals (up to 2x2x1 mm3) of Na0.35CoO2.1.3H2O-superconductor have been grown. Magnetization M(H, T) and M(T, H) curves with magnetic field approximately parallel and perpendicular to c-axis indicates on large anisotropy, comparable with Bi-based high-temperature superconducting (HTS) phases.Comment: 14 pages, 4 figure

Full Bulk Spin Polarization and Intrinsic Tunnel Barriers at the Surface of Layered Manganites

Transmission of information using the spin of the electron as well as its charge requires a high degree of spin polarization at surfaces. At surfaces however this degree of polarization can be quenched by competing interactions. Using a combination of surface sensitive x-ray and tunneling probes, we show for the quasi-two-dimensional bilayer manganites that the outermost Mn-O bilayer, alone, is affected: it is a 1-nm thick insulator that exhibits no long-range ferromagnetic order while the next bilayer displays the full spin polarization of the bulk. Such an abrupt localization of the surface effects is due to the two-dimensional nature of the layered manganite while the loss of ferromagnetism is attributed to weakened double exchange in the reconstructed surface bilayer and a resultant antiferromagnetic phase. The creation of a well-defined surface insulator demonstrates the ability to naturally self-assemble two of the most demanding components of an ideal magnetic tunnel junction.Comment: 19 pages, 5 figure

Temperature Dependent Polarized XANES Spectra for Zn-doped LSCO system

The cuprates seem to exhibit statistics, dimensionality and phase transitions in novel ways. The nature of excitations [i.e. quasiparticle or collective], spin-charge separation, stripes [static and dynamics], inhomogeneities, psuedogap, effect of impurity dopings [e.g. Zn, Ni] and any other phenomenon in these materials must be consistently understood. Zn-doped LSCO single crystal were grown by TSFZ technique. Temperature dependent Polarized XANES [near edge local structure] spectra were measured at the BL13-B1 [Photon Factory] in the Flourescence mode from 10 K to 300 K. Since both stripes and nonmagnetic Zn impurities substituted for Cu give rise to inhomogeneous charge and spin distribution it is interesting to understand the interplay of Zn impurities and stripes. To understand these points we have used Zn-doping and some of the results obtained are as follows: The spectra show a strong dependence with respect to the polarization angle, $\theta$, as is evident at any temperature by comparing the spectra where the electric field vector is parallel with ab-plane to the one where it is parallel to the c-axis. By using the XANES [temperature] difference spectra we have determined T* [experimentally we find, T* $\approx$ 160-170 K] for this sample. The XANES difference spectra shows that the changes in XANES features are larger in the ab-plane than the c-axis, this trend is expected since zinc is doped in the ab-plane at the copper site. Our study also complements the results in literature namely that zinc doping does not affect the c-axis transport.Comment: To appear in Physica C [ISS2001 Special Issue], related talk presented at ISS2001 as PC-16, 10 pages revtex and 7 pages of figures (pdf

Magnetization measurements on Li2Pd3B superconductor

Magnetization in DC magnetic fields and at different temperatures have been measured on the Li2Pd3B compound. This material was recently found to show superconductivity at 7-8K. Critical fields Hc1(0) and Hc2(0) have been determined to be 135Oe and 4T, respectively. Critical current density, scaling of the pinning force within the Kramer model and the irreversibility field data are presented. Several superconductivity parameters were deduced: x(csi)=9.1 nm, l(lamda)=194nm and k=21. The material resembles other boride superconductors from the investigated points of view.Comment: 10 pages, 5 figure