Time to failure prediction in rubber components subjected to thermal ageing: A combined approach based upon the intrinsic defect concept and the fracture mechanics

In this contribution, we attempt to derive a tool allowing the prediction of the stretch ratioat failure in rubber components subjected to thermal ageing. To achieve this goal, the mainidea is to combine the fracture mechanics approach and the intrinsic defect concept. Using an accelerated ageing procedure for an Ethylene–Propylene–Diene Monomer (EPDM), it is first shown that the average molar mass of the elastically active chains (i.e. between crosslinks) can be used as the main indicator of the macromolecular network degradation. Byintroducing the time–temperature equivalence principle, a shift factor obeying to an Arrhenius law is derived, and master curves are built as well for the average molar mass as for the ultimate mechanical properties. Fracture mechanics tests are also achieved and the square root dependence of the fracture energy with the average molar mass is pointed out. Moreover, it is shown that the mechanical response could be approximated by the phantom network theory, which allows to relate the strain energy density function to the average molar mass. Assuming that the fracture of a smooth specimen is the consequence of a virtual intrinsic defect whose the size can be easily estimated, the stretch ratio at break can be therefore computed for any thermal ageing condition. The estimated values are found in a very nice agreement with EPDM experimental data, making this approach a useful tool when designing rubber components for moderate to high temperature environments

On Ternary FF-manifold Algebras and their Representations

We introduce a notion of ternary $F$-manifold algebras which is a generalization of $F$-manifold algebras. We study representation theory of ternary $F$-manifold algebras. In particular, we introduce a notion of dual representation which requires additional conditions similar to the binary case. We then establish a notion of a coherence ternary $F$-manifold algebra. Moreover, we investigate the construction of ternary $F$-manifold algebras using $F$-manifold algebras. Furthermore, we introduce and investigate a notion of a relative Rota-Baxter operator with respect to a representation and use it to construct ternary pre-$F$-manifold algebras.Comment: Comments are welcome. arXiv admin note: text overlap with arXiv:2102.05595; text overlap with arXiv:2002.10238 by other author

La conductivité électro-magnétique : application au suivi de la salinité des sols des périmètres irrigués de Tunisie

Le but de la mission était de présenter une méthode d'évaluation de la salinité des sols par conductivimétrie électromagnétique et de tester dans les conditions de la Tunisie son application à la cartographie de la salure des périmètres irrigués du territoire. La présentation de l'appareillage a d'abord fait l'objet d'un séminaire à Sidi Thabet, organisé par la Direction des Sols. Puis quatre études de cas représentatifs ont été réalisées sur le terrain avec la collaboration des ingénieurs des laboratoires d'arrondissements de la Direction des Sols : périmètre de Sidi Saad (Kairouan), périmètre de Zelba (Mahdia), périmètre de Hazeg (Sfax), périmètre de Sebala ben Amar (Tunis). Au total plus de 700 mesures ont été réalisées au cours de la tournée soit sur la totalité de chaque périmètre, soit sur des parcelles représentatives (cf rapport technique). La facilité de mise en oeuvre de l'appareillage par rapport aux mesures habituelles avec prélèvements, la rapidité de la mesure qui est immédiate, la sensibilité de l'appareil même aux faibles salinités, l'appréhension d'une salinité globale permettant de s'affranchir du problème de variabilité spatiale, font de cette méthodologie une technique bien adaptée au suivi simultané d'un grand nombre de périmètres irrigués dans le cadre d'un réseau national de surveillance de la salinité des sols. (Résumé d'auteur

Micromechanical based model for predicting aged rubber fracture properties

Environmental aging induces a slow and irreversible alteration of the rubber material’s macromolecular network. This alteration is triggered by two mechanisms which act at the microscale: crosslinking and chain scission. While crosslinking induces an early hardening of the material, chain scission leads to the occurrence of dangling chains responsible of the damage at the macromolecular scale. Consequently, the mechanical behavior as well as the fracture properties are affected. In this work, the effect of aging on the mechanical behavior up to fracture of elastomeric materials and the evolution of their fracture properties are first experimentally investigated. Further, a modeling attempt using an approach based upon a micro-mechanical but physical description of the aging mechanisms is proposed to predict the mechanical and fracture properties evolution of aged elastomeric materials. The proposed micro-mechanical model incorporates the concepts of residual stretch associated with the crosslinking mechanism and a so-called “healthy” elastic active chain (EAC) density associated with chain scission mechanism. The validity of the proposed approach is assessed using a wide set of experimental data either generated by the authors or available in the literature

Sensitivity of Melt Pool Dimensions and Keyhole to Laser Beam Diameter

The laser powder bed fusion process has witnessed a huge interest in recent years since it has the potential to produce challenging shapes in a broad range of applications. The process parameters have a considerable effect on melt pool size and on the development of defect porosity. This paper predicts numerically the effect of a large range of laser beam diameters on melt pool dimensions and on the occurrence of porosity defects such as keyhole. A series of single beads of Inconel IN625 was made using various combinations of beam diameters, scan speeds, and laser powers. The use of a large diameter was more suitable rather than a small diameter as it ensures a large and shallow heat affected zone, thus decreasing the development of the keyhole defect. Our numerical results correlate satisfactorily with experimental finding from literature

Monitoring and lifetime prediction of pvc cables: methodology by multiscale and multidisciplinary approach

Monitoring of the PVC cables as well as the prediction of their residual lifetime are important issues for the maintenance of the French nuclear power plants (NPPs). To date, the unanimously end of life criterion admitted for these cables is a 50% value of elongation at break and, to our knowledge, only destructive tests give access to this parameter. This study reports a relationship between elongation at break of the PVC and their plasticizer content. This correlation opens the door to a monitoring directly on site or by micro sampling since all classic laboratory techniques able to measure this content become ways to judge the condition of the PVC sheaths and insulators. In addition, this study demonstrates the feasibility of prediction of industrial PVC behavior changes. This model, adapted to the case of thin films, involved tools of chemical kinetics and the implementation of a constitutive model

MRE11 Function in Response to Topoisomerase Poisons Is Independent of its Function in Double-Strand Break Repair in Saccharomyces cerevisiae

Camptothecin (CPT) and etoposide (ETP) trap topoisomerase-DNA covalent intermediates, resulting in formation of DNA damage that can be cytotoxic if unrepaired. CPT and ETP are prototypes for molecules widely used in chemotherapy of cancer, so defining the mechanisms for repair of damage induced by treatment with these compounds is of great interest. In S. cerevisiae, deficiency in MRE11, which encodes a highly conserved factor, greatly enhances sensitivity to treatment with CPT or ETP. This has been thought to reflect the importance of double-strand break (DSB) repair pathways in the response to these to agents. Here we report that an S. cerevisiae strain expressing the mre11-H59A allele, mutant at a conserved active site histidine, is sensitive to hydroxyurea and also to ionizing radiation, which induces DSBs, but not to CPT or ETP. We show that TDP1, which encodes a tyrosyl-DNA phosphodiesterase activity able to release both 5′- and 3′-covalent topoisomerase-DNA complexes in vitro, contributes to ETP-resistance but not CPT-resistance in the mre11-H59A background. We further show that CPT- and ETP-resistance mediated by MRE11 is independent of SAE2, and thus independent of the coordinated functions of MRE11 and SAE2 in homology-directed repair and removal of Spo11 from DNA ends in meiosis. These results identify a function for MRE11 in the response to topoisomerase poisons that is distinct from its functions in DSB repair or meiotic DNA processing. They also establish that cellular proficiency in repair of DSBs may not correlate with resistance to topoisomerase poisons, a finding with potential implications for stratification of tumors with specific DNA repair deficiencies for treatment with these compounds

Bacteriological and physico-chemical assessment of wastewater in different region of Tunisia: impact on human health

<p>Abstract</p> <p>Background</p> <p>In many parts of the world, health problems and diseases have often been caused by discharging untreated or inadequately treated wastewater. In this study, we aimed to control physico-chemical parameters in wastewater samples. Also, microbiological analyses were done to reveal <it>Salmonella </it>strains and each <it>Escherichia coli </it>(<it>E.coli</it>) pathotype.</p> <p>Findings</p> <p>Sixty wastewater samples were collected from fifteen different regions of Tunisia. All physico-chemical parameters (pH, residual free chlorine, total suspended solids, biological oxygen demand, and chemical oxygen demand) were evaluated.</p> <p>For microbiological analyses, samples were filtered to concentrate bacteria. DNA was extracted by boiling and subjected to polymerase chain reaction (PCR) using different pairs of primers.</p> <p>The mean pH values recorded for the sampling point were above the WHO pH tolerance limit. The total suspended solids (TSS) concentrations varied between 240 mg/L and 733 mg/L in entrance points and between 13 mg/L and 76 mg/L in exit points. In entrance points, the studied wastewater has an average COD concentration that varied between 795 mg/mL to 1420 mg/mL. Whereas, BOD concentration of the wastewater ranged between 270 mg/L to 610 mg/L. In exit points, COD concentration varied between 59 mg/L and 141 mg/L, whereas BOD concentration ranged from 15 mg/L to 87 mg/L.</p> <p>The bacteriological control of wastewaters showed that, in entrance points, <it>Escherichia coli </it>(<it>E.coli</it>) was detected at the rate of 76.6%. Three <it>E.coli </it>pathotypes were found: ETEC (53.3%), EAEC (16.6%) and EIEC (6.6%).</p> <p>Concerning the ETEC isolated strains, 8 of 16 (50%) have only the heat-labile toxin gene, 5 of 16 (31.2%) present only the heat-stable toxin gene and 3 of 16 (18.7%) of strains possess both heat-labile toxin gene and heat-stable toxin gene. In exist point, the same pathotypes were found but all detected ETEC strains present only the "est" gene.</p> <p>Concerning <it>Salmonella </it>isolated strains; percentages of 66.6% and 20% were found in entrance and exit points respectively.</p> <p>Conclusions</p> <p>Wastewaters contain a large amount of pathogenic bacteria that present a real impact on human health. Assessment wastewater treatment stations have to consider in account enterobacterial pathogens as potential pathogens that should be correctly controlled.</p