Influence of disordered porous media in the anomalous properties of a simple water model

The thermodynamic, dynamic and structural behavior of a water-like system confined in a matrix is analyzed for increasing confining geometries. The liquid is modeled by a two dimensional associating lattice gas model that exhibits density and diffusion anomalies, in similarity to the anomalies present in liquid water. The matrix is a triangular lattice in which fixed obstacles impose restrictions to the occupation of the particles. We show that obstacules shortens all lines, including the phase coexistence, the critical and the anomalous lines. The inclusion of a very dense matrix not only suppress the anomalies but also the liquid-liquid critical point

The Stellar Content of Obscured Galactic Giant HII Regions. VI: W51A

We present K-band spectra of newly born OB stars in the obscured Galactic giant H II region W51A and ~ 0.8'' angular resolution images in the J, H and K_S-bands. Four objects have been spectroscopically classified as O-type stars. The mean spectroscopic parallax of the four stars gives a distance of 2.0 \pm 0.3 kpc (error in the mean), significantly smaller than the radio recombination line kinematic value of 5.5 kpc or the values derived from maser propermotion observations (6--8 kpc). The number of Lyman continuum photons from the contribution of all massive stars (NLyc ~ 1.5 x 10^{50} s^{-1}) is in good agreement with that inferred from radio recombination lines (NLyc = 1.3 x 10^{50} s^{-1}) after accounting for the smaller distance derived here. We present analysis of archival high angular resolution images (NAOS CONICA at VLT and T-ReCS at Gemini) of the compact region W51 IRS2. The K_S--band images resolve the infrared source IRS~2 indicating that it is a very young compact HII region. Sources IRS2E was resolved into compact cluster (within 660 AU of projected distance) of 3 objects, but one of them is just bright extended emission. W51d1 and W51d2 were identified with compact clusters of 3 objects (maybe 4 in the case of W51d1) each one. Although IRS~2E is the brightest source in the K-band and at 12.6 \micron, it is not clearly associated with a radio continuum source. Our spectrum of IRS~2E shows, similar to previous work, strong emission in Br$\gamma$ and HeI, as well as three forbidden emission lines of FeIII and emission lines of molecular hydrogen (H_2) marking it as a massive young stellar object.Comment: 31 pages and 9 figures, submitted to A

Interações entre o sexo do bezerro e outros fatores ambientais para pesos do nascimento aos 24 meses em bovinos da raça Charolesa.

Interações entre o sexo do bezerro e outros fatores ambientais para pesos do nascimento aos 24 meses em bovinos da raça Charolesa

Properties of magnetic nanodots with perpendicular anisotropy

Nanodots with magnetic vortices have many potential applications, such as magnetic memories (VRAMs) and spin transfer nano-oscillators (STNOs). Adding a perpendicular anisotropy term to the magnetic energy of the nanodot it becomes possible to tune the vortex core properties. This can be obtained, e.g., in Co nanodots by varying the thickness of the Co layer in a Co/Pt stack. Here we discuss the spin configuration of circular and elliptical nanodots for different perpendicular anisotropies; we show for nanodisks that micromagnetic simulations and analytical results agree. Increasing the perpendicular anisotropy, the vortex core radii increase, the phase diagrams are modified and new configurations appear; the knowledge of these phase diagrams is relevant for the choice of optimum nanodot dimensions for applications. MFM measurements on Co/Pt multilayers confirm the trend of the vortex core diameters with varying Co layer thicknesses.Comment: 7 pages, 8 figure

Structural and chemical characterization of silica spheres before and after modification by silanization for trypsin immobilization.

In the last decades, silica particles of a variety of sizes and shapes have been characterized and chemically modified for several applications, from chromatographic separation to dental supplies. The present study proposes the use of aminopropyl triethoxysilane (APTS) silanized silica particles to immobilize the proteolytic enzyme trypsin for the development of a bioreactor. The major advantage of the process is that it enables the polypeptides hydrolysis interruption simply by removing the silica particles from the reaction bottle. Silanized silica surfaces showed significant morphological changes at micro- and nanoscale level. Chemical characterization showed changes in elemental composition, chemical environment, and thermal degradation. Their application as supports for trypsin immobilization showed high immobilization efficiency at reduced immobilization times, combined with more acidic conditions. Indirect immobilization quantification by reversed-phase ultrafast high performance liquid chromatography proved to be a suitable approach due to its high linearity and sensitivity. Immobilized trypsin activities on nonmodified and silanized silica showed promising features (e.g., selective hydrolysis) for applications in proteins/peptides primary structure elucidation for proteomics. Silanized silica system produced some preferential targeting peptides, probably due to the hydrophobicity of the nanoenvironment conditioned by silanization

Experimental analysis of lateral impact on planar brittle material: spatial properties of the cracks

The breakup of glass and alumina plates due to planar impacts on one of their lateral sides is studied. Particular attention is given to investigating the spatial location of the cracks within the plates. Analysis based on a phenomenological model suggests that bifurcations along the cracks' paths are more likely to take place closer to the impact region than far away from it, i. e., the bifurcation probability seems to lower as the perpendicular distance from the impacted lateral in- creases. It is also found that many observables are not sensitive to the plate material used in this work, as long as the fragment multiplicities corresponding to the fragmentation of the plates are similar. This gives support to the universal properties of the fragmentation process reported in for- mer experiments. However, even under the just mentioned circumstances, some spatial observables are capable of distinguishing the material of which the plates are made and, therefore, it suggests that this universality should be carefully investigated

Searching for Very High Energy Emission from Pulsars Using the High Altitude Water Cherenkov (HAWC) Observatory

There are currently over 160 known gamma-ray pulsars. While most of them are detected only from space, at least two are now seen also from the ground. MAGIC and VERITAS have measured the gamma ray pulsed emission of the Crab pulsar up to hundreds of GeV and more recently MAGIC has reported emission at $\sim2$ TeV. Furthermore, in the Southern Hemisphere, H.E.S.S. has detected the Vela pulsar above 30 GeV. In addition, non-pulsed TeV emission coincident with pulsars has been detected by many groups, including the Milagro Collaboration. These GeV-TeV observations open the possibility of searching for very-high-energy (VHE, > 100GeV) pulsations from gamma-rays pulsars in the HAWC field of view.Comment: Presented at the 34th International Cosmic Ray Conference (ICRC2015), The Hague, The Netherlands. See arXiv:1508.03327 for all HAWC contribution

Diffusion Enhancement in Core-softened fluid confined in nanotubes

We study the effect of confinement in the dynamical behavior of a core-softened fluid. The fluid is modeled as a two length scales potential. This potential in the bulk reproduces the anomalous behavior observed in the density and in the diffusion of liquid water. A series of $NpT$ Molecular Dynamics simulations for this two length scales fluid confined in a nanotube were performed. We obtain that the diffusion coefficient increases with the increase of the nanotube radius for wide channels as expected for normal fluids. However, for narrow channels, the confinement shows an enhancement in the diffusion coefficient when the nanotube radius decreases. This behavior, observed for water, is explained in the framework of the two length scales potential.Comment: 17 pages, 8 figures, accept for publication at J. Chem. Phy

Fontes alternativas de fósforo no desempenho e características dos ossos de suínos em crescimento e terminação.

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