45,667 research outputs found
1/t pressure and fermion behaviour of water in two dimensions
A variety of metal vacuum systems display the celebrated 1/t pressure, namely
power-law dependence on time t, with the exponent close to unity, the origin of
which has been a long-standing controversy. Here we propose a chemisorption
model for water adsorbates, based on the argument for fermion behaviour of
water vapour adsorbed on a stainless-steel surface, and obtain analytically the
power-law behaviour of pressure, with an exponent of unity. Further, the model
predicts that the pressure should depend on the temperature T according to
T^(3/2), which is indeed confirmed by our experiment. Our results should help
elucidate the unique characteristics of the adsorbed water.Comment: 11 pages, 4 figure
Conformational Instability of Rodlike Polyelectrolytes due to Counterion Fluctuations
The effective elasticity of highly charged stiff polyelectrolytes is studied
in the presence of counterions, with and without added salt. The rigid polymer
conformations may become unstable due to an effective attraction induced by
counterion density fluctuations. Instabilities at the longest, or intermediate
length scales may signal collapse to globule, or necklace states, respectively.
In the presence of added-salt, a generalized electrostatic persistence length
is obtained, which has a nontrivial dependence on the Debye screening length.
It is also found that the onset of conformational instability is a re-entrant
phenomenon as a function of polyelectrolyte length for the unscreened case, and
the Debye length or salt concentration for the screened case. This may be
relevant in understanding the experimentally observed re-entrant condensation
of DNA.Comment: 8 pages, 4 figure
Wigner crystal model of counterion induced bundle formation of rod-like polyelectrolytes
A simple electrostatic theory of condensation of rod-like polyelectrolytes
under influence of polyvalent ions is proposed. It is based on the idea that
Manning condensation of ions results in formation of the Wigner crystal on a
background of a bundle of rods. It is shown that, depending on a single
dimensionless parameter, this can be the densely packed three-dimensional
Wigner crystal or the two-dimensional crystal on the rod surfaces. For DNA the
location of charge on the spiral results in a model of the one-dimensional
Wigner crystal. It is also argued that the Wigner crystal idea can be applied
to self-assembly of other polyelectrolytes, for example, colloids and DNA-lipid
complexes.Comment: 4 pages; typos corrected, references adde
Finite Size Polyelectrolyte Bundles at Thermodynamic Equilibrium
We present the results of extensive computer simulations performed on
solutions of monodisperse charged rod-like polyelectrolytes in the presence of
trivalent counterions. To overcome energy barriers we used a combination of
parallel tempering and hybrid Monte Carlo techniques. Our results show that for
small values of the electrostatic interaction the solution mostly consists of
dispersed single rods. The potential of mean force between the polyelectrolyte
monomers yields an attractive interaction at short distances. For a range of
larger values of the Bjerrum length, we find finite size polyelectrolyte
bundles at thermodynamic equilibrium. Further increase of the Bjerrum length
eventually leads to phase separation and precipitation. We discuss the origin
of the observed thermodynamic stability of the finite size aggregates
Persistence length of a polyelectrolyte in salty water: a Monte-Carlo study
We address the long standing problem of the dependence of the electrostatic
persistence length of a flexible polyelectrolyte (PE) on the screening
length of the solution within the linear Debye-Huckel theory. The
standard Odijk, Skolnick and Fixman (OSF) theory suggests ,
while some variational theories and computer simulations suggest . In this paper, we use Monte-Carlo simulations to study the conformation
of a simple polyelectrolyte. Using four times longer PEs than in previous
simulations and refined methods for the treatment of the simulation data, we
show that the results are consistent with the OSF dependence . The linear charge density of the PE which enters in the coefficient of
this dependence is properly renormalized to take into account local
fluctuations.Comment: 7 pages, 6 figures. Various corrections in text and reference
Green Function of the Sutherland Model with SU(2) internal symmetry
We obtain the hole propagator of the Sutherland model with SU(2) internal
symmetry for coupling parameter , which is the simplest nontrivial
case. One created hole with spin down breaks into two quasiholes with spin down
and one quasihole with spin up. While these elementary excitations are
energetically free, the form factor reflects their anyonic character. The
expression for arbitrary integer is conjectured.Comment: 13pages, Revtex, one ps figur
Exactly Solvable Pairing Model Using an Extension of Richardson-Gaudin Approach
We introduce a new class of exactly solvable boson pairing models using the
technique of Richardson and Gaudin. Analytical expressions for all energy
eigenvalues and first few energy eigenstates are given. In addition, another
solution to Gaudin's equation is also mentioned. A relation with the
Calogero-Sutherland model is suggested.Comment: 9 pages of Latex. In the proceedings of Blueprints for the Nucleus:
From First Principles to Collective Motion: A Festschrift in Honor of
Professor Bruce Barrett, Istanbul, Turkey, 17-23 May 200
Pre- and Post-Adaptation Effects of Buffers in High-Concentrate Lamb Diets
A gradual increase in grain cover a period of 2 to 4 weeks is commonly required before ruminant animals become adapted to high-concentrate diets. Various dietary materials including sodium bicarbonate, sodium betonite, limestone and forage have been indicated as potential adis in the prevention of acidosis during adaptation. Benefits from feeding of these materials following adaptation have been less pronounced or lacking. Objectives of studies reported herein were (1) to investigate the effects of buffers and limited quantitites of alfalfa hay on physiological and rumen fermentation changs occuring in lambs during the early phase of adaptation to high-concentrate diets and (2) to study ruminal and systemic parameters and nutrient utilization as influenced by buffers in the diets of lambs previously adapted to the high-concentrate diet
Machine learning applied to enzyme turnover numbers reveals protein structural correlates and improves metabolic models.
Knowing the catalytic turnover numbers of enzymes is essential for understanding the growth rate, proteome composition, and physiology of organisms, but experimental data on enzyme turnover numbers is sparse and noisy. Here, we demonstrate that machine learning can successfully predict catalytic turnover numbers in Escherichia coli based on integrated data on enzyme biochemistry, protein structure, and network context. We identify a diverse set of features that are consistently predictive for both in vivo and in vitro enzyme turnover rates, revealing novel protein structural correlates of catalytic turnover. We use our predictions to parameterize two mechanistic genome-scale modelling frameworks for proteome-limited metabolism, leading to significantly higher accuracy in the prediction of quantitative proteome data than previous approaches. The presented machine learning models thus provide a valuable tool for understanding metabolism and the proteome at the genome scale, and elucidate structural, biochemical, and network properties that underlie enzyme kinetics
Single-particle Green's functions of the Calogero-Sutherland model at couplings \lambda = 1/2, 1, and 2
At coupling strengths lambda = 1/2, 1, or 2, the Calogero-Sutherland model
(CSM) is related to Brownian motion in a Wigner-Dyson random matrix ensemble
with orthogonal, unitary, or symplectic symmetry. Using this relation in
conjunction with superanalytic techniques developed in mesoscopic conductor
physics, we derive an exact integral representation for the CSM two-particle
Green's function in the thermodynamic limit. Simple closed expressions for the
single-particle Green's functions are extracted by separation of points. For
the advanced part, where a particle is added to the ground state and later
removed, a sum of two contributions is found: the expected one with just one
particle excitation present, plus an extra term arising from fractionalization
of the single particle into a number of elementary particle and hole
excitations.Comment: 19 REVTeX page
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