57 research outputs found
Ion beam induced enhanced diffusion from gold thin films in silicon
Enhanced diffusion of gold atoms into silicon substrate has been studied in
Au thin films of various thicknesses (2.0, 5.3, 10.9 and 27.5 nm) deposited on
Si(111) and followed by irradiation with 1.5 MeV Au2+ at a flux of 6.3x10^12
ions cm-2 s-1 and fluence up to 1x10^15 ions cm-2. The high resolution
transmission electron microscopy measurements showed the presence of gold
silicide formation for the above-mentioned systems at fluence greater than
equal to 1x1014 ions cm-2. The maximum depth to which the gold atoms have been
diffused at a fluence of 1x10^14 ions cm-2 for the cases of 2.0, 5.3, 10.9 and
27.5 nm thick films has been found to be 60, 95, 160 and 13 nm respectively.
Interestingly, at higher fluence of 1x1015 ions cm-2 in case of 27.5 nm thick
film, gold atoms from the film transported to a maximum depth of 265 nm in the
substrate. The substrate silicon is found to be amorphous at the above fluence
values where unusually large mass transport occurred. Enhanced diffusion has
been explained on the basis of ion beam induced, flux dependent amorphous
nature of the substrate, and transient beam induced temperature effects. This
work confirms the absence of confinement effects that arise from spatially
confined structures and existence of thermal and chemical reactions during ion
irradiation.Comment: 15 pages, 3 figure
Self-assembled ge nanostructures on polymer-coated silicon: growth and characterization
Self-assembled Ge nanoparticles have been grown on polymer-coated Si substrates by thermal evaporation under high vacuum utilizing the nonwetting condition given by the surface free-energy relation σ Ge»σpolymer. The nanostructures have been characterized by Raman spectroscopy, atomic-force microscopy (AFM), and optical microscopy. Raman spectrum shows a prominent Ge-Ge vibration peak at 302cm-1. AFM and optical microscopy show the formation of isolated Ge islands (>~100nm base, <~25nm height), nanowires (160 nm base, 25 nm height), and islands in linear chains. The possibility of embedding such nanostructures in waveguide structures are discussed
Flux dependent 1.5 MeV self-ion beam induced sputtering from Gold nanostructured thin films
We discuss four important aspects of 1.5 MeV Au2+ ion-induced flux dependent
sputtering from gold nanostrcutures (of an average size 7.6 nm and height 6.9
nm) that are deposited on silicon substrates: (a) Au sputtering yield at the
ion flux of 6.3x10^12 ions cm-2 s-1 is found to be 312 atoms/ion which is about
five times the sputtering yield reported earlier under identical irradiation
conditions at a lower beam flux of 10^9 ions cm-2 s-1, (b) the sputtered yield
increases with increasing flux at lower fluence and reduces at higher fluence
(1.0x10^15 ions cm-2) for nanostructured thin films while the sputtering yield
increases with increasing flux and fluence for thick films (27.5 nm Au
deposited on Si) (c) Size distribution of sputtered particles has been found to
vary with the incident beam flux showing a bimodal distribution at higher flux
and (d) the decay exponent obtained from the size distributions of sputtered
particles showed an inverse power law dependence ranging from 1.5 to 2.5 as a
function of incident beam flux. The exponent values have been compared with
existing theoretical models to understand the underlying mechanism. The role of
wafer temperature associated with the beam flux has been invoked for a
qualitative understanding of the sputtering results in both the nanostructured
thin films and thick films.Comment: 25 pages, 5 figures, 1 table To be Appeared in J. Phys. D: Appl. Phy
Shape variation in epitaxial microstructures of gold silicide grown on br-passivated Si(1 1 1) surfaces
Kinetic Monte Carlo simulations for growth on substrates of three-fold symmetry predict the growth of islands of various shapes depending on the growth temperature [Phys. Rev. Lett. 71 (1993) 2967]. On Br-Si(1 1 1) substrates growth of epitaxial gold silicide islands of equilateral triangular and trapezoidal shapes have earlier been observed by annealing at the Au-Si eutectic temperature, 363 °C [Phys. Rev. B 51 (1995) 14330]. We carried out annealing with temperature variation within a small window--(363 ± 30) °C. This has led to island growth of additional shapes like regular hexagon, elongated hexagon, walled hexagon and dendrite. Some of the observed island shapes have not been predicted
Effect of Fe Doping on Photocatalytic Dye-Degradation and Antibacterial Activity of SnO2 Nanoparticles
A simple hydrothermal method is utilized to synthesize iron-doped tin oxide nanoparticles (Fe-SnO2 NPs) at various doping concentrations. The structural characterization using XRD, Raman, and FTIR measurements confirmed the incorporation of Fe ions into the SnO2 lattice without any deviation in the tetragonal crystal system of SnO2 nanoparticles. SEM and HRTEM images show the spherical-shaped nanoparticles with agglomeration. The values of interplanar spacing (
d
-value) calculated from the HRTEM lattice are consistent with the XRD results. Further, optical analysis revealed a red shift in the optical absorption band and a decrease in the band gap energy with an increase in Fe-dopant concentration. The decrease of PL emission peak intensity with Fe doping revealed the generation of singly charged oxygen vacancies. The H2O2-assisted photocatalytic degradation efficiency of Fe-SnO2 NPs investigated against crystal violet dye indicated an efficiency of 98% for 0.05 M Fe-SnO2 NPs within 30 minutes under visible light illumination. In addition, the effects of pH, scavengers, and reusability of the catalyst are tested. The antibacterial behavior of Fe-SnO2 NPs against Escherichia coli is examined by using the colony count method, and the inhibition rate was found to be 49, 65, 70, and 78% for pure, 0.01, 0.03, and 0.05 M Fe-SnO2 NPs, respectively
'Spillout' effect in gold nanoclusters embedded in c-Al2O3(0001) matrix
Gold nanoclusters are grown by 1.8 MeV Au^\sup{2+} implantation on
c-Al\sub{2}O\sub{3}(0001)substrate and subsequent air annealing at temperatures
1273K. Post-annealed samples show plasmon resonance in the optical (561-579 nm)
region for average cluster sizes ~1.72-2.4 nm. A redshift of the plasmon peak
with decreasing cluster size in the post-annealed samples is assigned to the
'spillout' effect (reduction of electron density) for clusters with ~157-427
number of Au atoms fully embedded in crystalline dielectric matrix with
increased polarizability in the embedded system.Comment: 14 Pages (figures included); Accepted in Chem. Phys. Lett (In Press
Ion channeling studies on mixed phases formed in metalorganic chemical vapor deposition grown Mg-doped GaN on Al₂O₃(0001)
Author name used in this publication: W. K. FongAuthor name used in this publication: C. SuryaVersion of RecordPublishe
Shape Transition in the Epitaxial Growth of Gold Silicide in Au Thin Films on Si(111)
Growth of epitaxial gold silicide islands on bromine-passivated Si(111)
substrates has been studied by optical and electron microscopy, electron probe
micro analysis and helium ion backscattering. The islands grow in the shape of
equilateral triangles up to a critical size beyond which the symmetry of the
structure is broken, resulting in a shape transition from triangle to
trapezoid. The island edges are aligned along directions. We have
observed elongated islands with aspect ratios as large as 8:1. These islands,
instead of growing along three equivalent [110] directions on the Si(111)
substrate, grow only along one preferential direction. This has been attributed
to the vicinality of the substrate surface.Comment: revtex version 3.0, 11 pages 4 figures available on request from
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