Acoustical transducer calibrating system and apparatus

An acoustical transducer calibrating system includes a differential pressure actuating device having an inner chamber for applying differential pressures to the transducer, and an outer chamber for vacuum sealing. Mounted within the inner chamber is an electrostatic actuator for exciting the transducer at selected frequencies so that its sensitivity can be determined for different operating ambient pressures

Anomalous isotopic predissociation in the F³Πu(v=1) state of O₂

Using a tunable, narrow-bandwidth vacuum-ultraviolet source based on third-harmonic generation from excimer-pumped dye-laser radiation, the F³Πu←X³Σg-(1,0)photoabsorption cross sections of ¹⁶O₂ and ¹⁸O₂ have been recorded in high resolution. Rotational analyses have been performed and the resultant F(v=1) term values fitted to the ³Π Hamiltonian of Brown and Merer [J. Mol. Spectrosc. 74, 488 (1979)]. A large rotationless isotope effect is observed in the F(v=1)predissociation, wherein the Lorentzian linewidth component for ¹⁸O₂ is a factor of ∼50 smaller than the corresponding ¹⁶O₂linewidth. This effect, a consequence of the nonadiabatic rotationless predissociation mechanism, is described using a coupled-channel treatment of the strongly Rydberg-valence-mixed 3Πu states. Significant J, e/f-parity, and sublevel dependencies observed in the isotopic F(v=1) rotational widths are found to derive from an indirect predissociation mechanism involving an accidental degeneracy with the E³Σ−u(v=3) level, itself strongly predissociated by ³Σ−u Rydberg-valence interactions, together with L-uncoupling (rotational) interactions between the Rydberg components of the F and E states. Transitions into the E(v=3) level are observed directly for the first time, specifically in the ¹⁸O₂ spectrumPartial support was provided by an NSF International Opportunities for Scientists and Engineers Program Grant No. INT-9513350, and Visiting Fellowships for G.S. and J.B.W. at the Australian National University

Elastic precursor of the transformation from glycolipid-nanotube to -vesicle

By the combination of optical tweezer manipulation and digital video microscopy, the flexural rigidity of single glycolipid "nano" tubes has been measured below the transition temperature at which the lipid tubules are transformed into vesicles. Consequently, we have found a clear reduction of the rigidity obviously before the transition as temperature increasing. Further experiments of infrared spectroscopy (FT-IR) and differential scanning calorimetry (DSC) have suggested a microscopic change of the tube walls, synchronizing with the precursory softening of the nanotubes.Comment: 9 pages, 6 figure

Neighborhood and Individual Level Socioeconomic Variation in Perceptions of Racial Discrimination

In approaching the study of racial discrimination and health, the neighborhood and individual-level antecedents of perceived discrimination need further exploration. We investigated the relationship between neighborhood and individual-level socioeconomic position (SEP), neighborhood racial composition, and perceived racial discrimination in a cohort of African-American and White women age 40-79 from Connecticut, USA. Design. The logistic regression analysis included 1249 women (39% African- American and 61% White). Neighborhood-level SEP and racial composition were determined using 1990 census tract information. Individual-level SEP indicators included income, education, and occupation. Perceived racial discrimination was measured as lifetime experience in seven situations. Results. For African-American women, living in the most disadvantaged neighborhoods was associated with fewer reports of racial discrimination (odds ratio (OR) 0.44; 95% confidence interval (CI) 0.26, 0.75), with results attenuated after adjustment for individual-level SEP (OR 0.54, CI: 0.29, 1.03), and additional adjustment for neighborhood racial composition (OR 0.70, CI: 0.30, 1.63). African-American women with 12 years of education or less were less likely to report racial discrimination, compared with women with more than 12 years of education (OR 0.57, CI: 0.33, 0.98 (12 years); OR 0.51, CI: 0.26, 0.99 (less than 12 years)) in the fully adjusted model. For White women, neither neighborhood-level SEP nor individual-level SEP was associated with perceived racial discrimination. Conclusion. Individual and neighborhood-level SEP may be important in understanding how racial discrimination is perceived, reported, processed, and how it may influence health. In order to fully assess the role of racism in future studies, inclusion of additional dimensions of discrimination may be warranted

Correlation inequalities for noninteracting Bose gases

For a noninteracting Bose gas with a fixed one-body Hamiltonian H^0 independent of the number of particles we derive the inequalities _N < _{N+1}, _N _N _N for i\neq j, \partial _N/\partial \beta >0 and ^+_N _N. Here N_i is the occupation number of the ith eigenstate of H^0, \beta is the inverse temperature and the superscript + refers to adding an extra level to those of H^0. The results follow from the convexity of the N-particle free energy as a function of N.Comment: a further inequality adde

Friction and wear in railway ballast stone interfaces

Particle friction in railway ballast influences strongly the behaviour of ballasted tracks. New challenges posed on railway infrastructure increase the requirement for simulations, which need the friction coefficient as an input parameter. Measured friction coefficients of ballast stone contacts were found only in two studies, both under constant loads. In this work, two types of ballast were investigated in cyclic friction tests with incremental increase of the applied load after several cycles. Before each load increase, 3D-scans of some ballast stones allowed to calculate the contact area. Estimating the stress in the contact, the stress-dependency of the friction coefficient and wear were investigated. These experimental observations are discussed regarding their impact for friction modelling in the simulation of railway ballast

Assignment of the excess absorption underlying the Schumann–Runge bands of molecular oxygen

A long-standing problem, pertaining to the origin of the excess absorption found experimentally to underlie the high-vibrational Schumann–Runge bands of molecular oxygen, is resolved. Through new calculations, with parameter sets based on recently obtained experimental information, it is shown that the excess absorption arises from transitions into the lowest valence states of ³Πu and ³Πg symmetry

High-resolution photoelectron spectroscopy of linear ← bent polyatomic photodetachment transitions: The electron affinity of CS₂

A combination of high-resolution velocity-map-imaging photoelectron spectroscopy and isotopic substitution is used to show that precise electron affinities can be obtained from polyatomic photodetachment spectra, even for cases involving significant changes in equilibrium geometry between the molecular neutral and anion.This research was supported by the Australian Research Council (Grant Nos. DP0666267 and DP0880850)

Experimental verification of line- and band-shape asymmetry in the Schumann–Runge system of O[sub 2]

High-resolution, laser-based photoabsorption cross-section measurements in the weakly absorbing windows between the (11,0) and (16,0) Schumann–Runge bands of O₂ have been performed at liquid-nitrogen temperature and the results compared with corresponding coupled-channel Schrödinger-equation (CSE) and line-by-line model calculations. While the symmetric-line- shape-based line-by-line model cross sections differ significantly from experiment, the excellent agreement found between the CSE and experimental window cross sections serves to confirm clearly for the first time the CSE-model predictions of band shape asymmetry and quantum-mechanical interference effects, especially in the (11,0)–(14,0) band region