2,089 research outputs found

    Direct conversion of rheological compliance measurements into storage and loss moduli

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    We remove the need for Laplace/inverse-Laplace transformations of experimental data, by presenting a direct and straightforward mathematical procedure for obtaining frequency-dependent storage and loss moduli (G(ω)G'(\omega) and G"(ω)G"(\omega) respectively), from time-dependent experimental measurements. The procedure is applicable to ordinary rheological creep (stress-step) measurements, as well as all microrheological techniques, whether they access a Brownian mean-square displacement, or a forced compliance. Data can be substituted directly into our simple formula, thus eliminating traditional fitting and smoothing procedures that disguise relevant experimental noise.Comment: 4 page

    Anisotropic charge transport in non-polar GaN QW: polarization induced charge and interface roughness scattering

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    Charge transport in GaN quantum well (QW) devices grown in non-polar direction has been theoretically investigated . Emergence of anisotropic line charge scattering mechanism originating as a result of anisotropic rough surface morphology in conjunction with in-plane built-in polarization has been proposed. It has shown that in-plane growth anisotropy leads to large anisotropic carrier transport at low temperatures. At high temperatures, this anisotropy in charge transport is partially washed out by strong isotropic optical phonon scattering in GaN QW.Comment: 4 pages, 4 figure

    Ion and polymer dynamics in polymer electrolytes PPO-LiClO4: II. 2H and 7Li NMR stimulated-echo experiment

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    We use 2H NMR stimulated-echo spectroscopy to measure two-time correlation functions characterizing the polymer segmental motion in polymer electrolytes PPO-LiClO4 near the glass transition temperature Tg. To investigate effects of the salt on the polymer dynamics, we compare results for different ether oxygen to lithium ratios, namely, 6:1, 15:1, 30:1 and infinity. For all compositions, we find nonexponential correlation functions, which can be described by a Kohlrausch function. The mean correlation times show quantitatively that an increase of the salt concentration results in a strong slowing down of the segmental motion. Consistently, for the high 6:1 salt concentration, a high apparent activation energy E_a=4.1eV characterizes the temperature dependence of the mean correlation times at Tg < T< 1.1T_g, while smaller values E_a=2.5eV are observed for moderate salt contents. The correlation functions are most nonexponential for 15:1 PPO-LiClO4, whereas the stretching is reduced for higher and lower salt concentrations. A similar dependence of the correlation functions on the evolution time in the presence and in the absence of ions indicates that addition of salt hardly affects the reorientational mechanism. For all compositions, mean jump angles of about 15 degree characterize the segmental reorientation. In addition, comparison of results from 2H and 7Li NMR stimulated-echo experiments suggests a coupling of ion and polymer dynamics in 15:1 PPO-LiClO4.Comment: 14 pages, 12 figure

    Food activities and identity maintenance in old age: a systematic review and meta-synthesis

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    This article has been made available through the Brunel Open Access Publishing Fund.Objectives: Services provided to older people should be developed based on active ageing policies. Nutrition is one aspect of active ageing, but little is known about how food activities contribute to psychological well-being in later life. This is a systematic review of qualitative and quantitative research that answers the question ‘What is known about the relationship between food activities and the maintenance of identities in old age?’

    On the origin of the λ\lambda-transition in liquid Sulphur

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    Developing a novel experimental technique, we applied photon correlation spectroscopy using infrared radiation in liquid Sulphur around TλT_\lambda, i.e. in the temperature range where an abrupt increase in viscosity by four orders of magnitude is observed upon heating within few degrees. This allowed us - overcoming photo-induced and absorption effects at visible wavelengths - to reveal a chain relaxation process with characteristic time in the ms range. These results do rehabilitate the validity of the Maxwell relation in Sulphur from an apparent failure, allowing rationalizing the mechanical and thermodynamic behavior of this system within a viscoelastic scenario.Comment: 5 pages, 4 eps figures, accepted in Phys. Rev. Let

    An effective mass theorem for the bidimensional electron gas in a strong magnetic field

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    We study the limiting behavior of a singularly perturbed Schr\"odinger-Poisson system describing a 3-dimensional electron gas strongly confined in the vicinity of a plane (x,y)(x,y) and subject to a strong uniform magnetic field in the plane of the gas. The coupled effects of the confinement and of the magnetic field induce fast oscillations in time that need to be averaged out. We obtain at the limit a system of 2-dimensional Schr\"odinger equations in the plane (x,y)(x,y), coupled through an effective selfconsistent electrical potential. In the direction perpendicular to the magnetic field, the electron mass is modified by the field, as the result of an averaging of the cyclotron motion. The main tools of the analysis are the adaptation of the second order long-time averaging theory of ODEs to our PDEs context, and the use of a Sobolev scale adapted to the confinement operator
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