5,539 research outputs found
Ground state of two unlike charged colloids: An analogy with ionic bonding
In this letter, we study the ground state of two spherical macroions of
identical radius, but asymmetric bare charge ((Q_{A}>Q_{B})). Electroneutrality
of the system is insured by the presence of the surrounding divalent
counterions. Using Molecular Dynamics simulations within the framework of the
primitive model, we show that the ground state of such a system consists of an
overcharged and an undercharged colloid. For a given macroion separation the
stability of these ionized-like states is a function of the difference
((\sqrt{N_{A}}-\sqrt{N_{B}})) of neutralizing counterions (N_{A}) and (N_{B}).
Furthermore the degree of ionization, or equivalently, the degree of
overcharging, is also governed by the distance separation of the macroions. The
natural analogy with ionic bonding is briefly discussed.Comment: published versio
Strong Attraction between Charged Spheres due to Metastable Ionized States
We report a mechanism which can lead to long range attractions between
like-charged spherical macroions, stemming from the existence of metastable
ionized states. We show that the ground state of a single highly charged
colloid plus a few excess counterions is overcharged. For the case of two
highly charged macroions in their neutralizing divalent counterion solution we
demonstrate that, in the regime of strong Coulomb coupling, the counterion
clouds are very likely to be unevenly distributed, leading to one overcharged
and one undercharged macroion. This long-living metastable configuration in
turn leads to a long range Coulomb attraction.Comment: REVTEX-published versio
Analysis of the Reaction Rate Coefficients for Slow Bimolecular Chemical Reactions
Simple bimolecular reactions are analyzed
within the framework of the Boltzmann equation in the initial stage of a
chemical reaction with the system far from chemical equilibrium. The
Chapman-Enskog methodology is applied to determine the coefficients of the
expansion of the distribution functions in terms of Sonine polynomials for
peculiar molecular velocities. The results are applied to the reaction
, and the influence of the non-Maxwellian
distribution and of the activation-energy dependent reactive cross sections
upon the forward and reverse reaction rate coefficients are discussed.Comment: 11 pages, 5 figures, to appear in vol.42 of the Brazilian Journal of
Physic
Field theory of self-avoiding walks in random media
Based on the analogy with the quantum mechanics of a particle propagating in
a {\em complex} potential, we develop a field-theoretical description of the
statistical properties of a self-avoiding polymer chain in a random
environment. We show that the account of the non-Hermiticity of the quantum
Hamiltonian results in a qualitatively different structure of the effective
action, compared to previous studies. Applying the renormalisation group
analysis, we find a transition between the weak-disorder regime, where the
quenched randomness is irrelevant, and the strong-disorder regime, where the
polymer chain collapses. However, the fact that the renormalised interaction
constants and the chiral symmetry breaking regularisation parameter flow
towards strong coupling raises questions about the applicability of the
perturbative analysis.Comment: RevTeX, 9 pages; accepted for publication in J. Phys.
Direct observation of substitutional Ga after ion implantation in Ge by means of extended x-ray absorption fine structure
Collapse of Randomly Self-Interacting Polymers
We use complete enumeration and Monte Carlo techniques to study
self--avoiding walks with random nearest--neighbor interactions described by
, where is a quenched sequence of ``charges'' on the
chain. For equal numbers of positive and negative charges (), the
polymer with undergoes a transition from self--avoiding behavior to a
compact state at a temperature . The collapse temperature
decreases with the asymmetry Comment: 8 pages, TeX, 4 uuencoded postscript figures, MIT-CMT-
Conformation of a Polyelectrolyte Complexed to a Like-Charged Colloid
We report results from a molecular dynamics (MD) simulation on the
conformations of a long flexible polyelectrolyte complexed to a charged sphere,
\textit{both negatively charged}, in the presence of neutralizing counterions
in the strong Coulomb coupling regime. The structure of this complex is very
sensitive to the charge density of the polyelectrolyte. For a fully charged
polyelectrolyte the polymer forms a dense two-dimensional "disk", whereas for a
partially charged polyelectrolyte the monomers are spread over the colloidal
surface. A mechanism involving the \textit{overcharging} of the polyelectrolyte
by counterions is proposed to explain the observed conformations.Comment: 4 pages, 4 figures (6 EPS files
The effect of gender and age on the association between weight status and health-related quality of life in Australian adolescents
Evidence suggests an inverse relationship between excess weight and health-related quality of life (HRQoL) in children and adolescents, however little is known about whether this association is moderated by variables such as gender and age. This study aimed to investigate these relationships
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