1,088 research outputs found
Cultural political economy and urban heritage tourism
The paper explains a cultural political economy âframingâ for interpreting heritage tourism in urban contexts. Key ideas behind this research perspective are explained and illustrated through discussion of past research studies of urban heritage tourism. It is underpinned by a relational view of the inter-connectedness of societal relations, and an emphasis on taking seriously both the cultural/semiotic and the economic/political in the co-constitution of urban heritage tourismâs social practices and features. A case study of heritage tourism in Nanjing, China considers cultural political economyâs relevance and value, including the distinctive research questions it raises. It reveals, for example, how economic relations in the built environment were related to tourist meaning-making and identities in the cultural/semiotic sphere
ESR Studies of Phosphorescent Corannulene; Evidence for Pseudorotation
Electron spin resonance (ESR) spectra have been recorded for the lowest triplet state of corannulene. The experiments were performed by ultraviolet irradiation of the molecule in rigid glass solutions at 77 and 15°K. In the highâfield (Îmâ = â1)(Îm=1) region the line shape and line positions of the absorptions associated with the XX and YY magnetic axes were strongly temperature dependent. From an analysis of the spectra the following conclusions were drawn: Corannulene in its first triplet state has a configuration of lowest energy which is not fivefold symmetric; at 15°K corannulene gives in the highâfield region the spectrum of a molecule âfrozenâ in conformations of less than threefold symmetry; tunneling between equivalent conformations at 77°K is believed to occur at a rate of about 109 Hz.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/69781/2/JCPSA6-52-11-5656-1.pd
Comment on "Universal Fluctuations in Correlated Systems"
This is a Comment on "Universal Fluctuations in Correlated Systems".Comment: to appear in Phys. Rev. Let
ESR studies of the triplet state of [n.n] paracyclophanes
ESR experiments were performed on the triplet state of randomly oriented paracyclophanes in a variety of rigid glasses at temperatures ranging from 103 to 15°K. Spectra were recorded for [2.2]; [3.3]; (4,7,12,15)âtetramethyl [2.2]âparacyclophane and staggerâring paracyclophane. For all the samples except stagger ring, a fourâringed paracyclophane, only the Hmin feature was observed from which D*, the rootâmeanâsquare zeroâfield splitting, was calculated. For stagger ring the triplet spectrum has two features in the Îms = 1Îms=1 region in addition to the Hmin feature. From these, the zeroâfield splittings, D and E, were calculated. The triplet spectra for the paracyclophanes show that there is strong transannular interaction with electron delocalization over all benzene rings. There is evidence for strongly coupled intramolecular exciton effects. The effect of increasing the interâring separation from [2.2] paracyclophane to [3.3] paracyclophane is to decrease the transannular interaction. The effect of methyl substitution is to increase transannular effects relative to the parent compound. Transannular interactions in stagger ring are greater than in [2.2] paracyclophane despite the increased electron delocalization possible through the introduction of more than two rings. The large value of E for stagger ring represents a significant deviation from axial symmetry for the zeroâfieldâsplitting tensor and indicates that the methylene bridges, the methyl substituents, or the ring distortion, may make important contributions to the electronic distribution of the triplet state.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/70725/2/JCPSA6-58-2-420-1.pd
Universal Magnetic Fluctuations with a Field Induced Length Scale
We calculate the probability density function for the order parameter
fluctuations in the low temperature phase of the 2D-XY model of magnetism near
the line of critical points. A finite correlation length, \xi, is introduced
with a small magnetic field, h, and an accurate expression for \xi(h) is
developed by treating non-linear contributions to the field energy using a
Hartree approximation. We find analytically a series of universal non-Gaussian
distributions with a finite size scaling form and present a Gumbel-like
function that gives the PDF to an excellent approximation. We propose the
Gumbel exponent, a(h), as an indirect measure of the length scale of
correlations in a wide range of complex systems.Comment: 7 pages, 4 figures, 1 table. To appear in Phys. Rev.
Statistics of extremal intensities for Gaussian interfaces
The extremal Fourier intensities are studied for stationary
Edwards-Wilkinson-type, Gaussian, interfaces with power-law dispersion. We
calculate the probability distribution of the maximal intensity and find that,
generically, it does not coincide with the distribution of the integrated power
spectrum (i.e. roughness of the surface), nor does it obey any of the known
extreme statistics limit distributions. The Fisher-Tippett-Gumbel limit
distribution is, however, recovered in three cases: (i) in the non-dispersive
(white noise) limit, (ii) for high dimensions, and (iii) when only
short-wavelength modes are kept. In the last two cases the limit distribution
emerges in novel scenarios.Comment: 15 pages, including 7 ps figure
Universal Fluctuations of the Danube Water Level: a Link with Turbulence, Criticality and Company Growth
A global quantity, regardless of its precise nature, will often fluctuate
according to a Gaussian limit distribution. However, in highly correlated
systems, other limit distributions are possible. We have previously calculated
one such distribution and have argued that this function should apply
specifically, and in many instances, to global quantities that define a steady
state. Here we demonstrate, for the first time, the relevance of this
prediction to natural phenomena. The river level fluctuations of the Danube are
observed to obey our prediction, which immediately establishes a generic
statistical connection between turbulence, criticality and company growth
statistics.Comment: 5 pages, 1 figur
Ordered Phase of the Dipolar Spin Ice under [110]-Magnetic Fields
We find that the true ground state of the dipolar spin ice system under
[110]-magnetic fields is the ``Q=X'' structure, which is consistent with both
experiments and Monte Carlo simulations. We then perform a Monte Carlo
simulation to confirm that there exists a first order phase transition under
the [110]-field. In particular this result indicates the existence of the first
order phase transition to the ``Q=X'' phase in the field above 0.35 T for
Dy2Ti2O7. We also show the magnetic field-temperature phase diagram to
summarize the ordered states of this system.Comment: 4 pages, 5 figures, in RevTex4, submitted to J. Phys. Soc. Jp
1/f Noise and Extreme Value Statistics
We study the finite-size scaling of the roughness of signals in systems
displaying Gaussian 1/f power spectra. It is found that one of the extreme
value distributions (Gumbel distribution) emerges as the scaling function when
the boundary conditions are periodic. We provide a realistic example of
periodic 1/f noise, and demonstrate by simulations that the Gumbel distribution
is a good approximation for the case of nonperiodic boundary conditions as
well. Experiments on voltage fluctuations in GaAs films are analyzed and
excellent agreement is found with the theory.Comment: 4 pages, 4 postscript figures, RevTe
Low Temperature Spin Freezing in Dy2Ti2O7 Spin Ice
We report a study of the low temperature bulk magnetic properties of the spin
ice compound Dy2Ti2O7 with particular attention to the (T < 4 K) spin freezing
transition. While this transition is superficially similar to that in a spin
glass, there are important qualitative differences from spin glass behavior:
the freezing temperature increases slightly with applied magnetic field, and
the distribution of spin relaxation times remains extremely narrow down to the
lowest temperatures. Furthermore, the characteristic spin relaxation time
increases faster than exponentially down to the lowest temperatures studied.
These results indicate that spin-freezing in spin ice materials represents a
novel form of magnetic glassiness associated with the unusual nature of
geometrical frustration in these materials.Comment: 24 pages, 8 figure
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