Extraction and Liquid-Membrane Preconcentration of Vincamine from Periwinkle (VincaMinor L.) Leaves. Process Modelling

An integrated process coupling solid-liquid extraction and liquid-membrane preconcentration of vincamine was studied. The effect of the ratios solid phase/extractant volume and extractant volume/liquid membrane volume on the mass transfer rate and efficiency of vincamine removal were estimated. It was found that the transfer rate and removal efficiency of the alkaloid were higher with smaller quantities of solids and membrane volume. A mathematical description of the overall integrated process was proposed, and the values of the model parameters – mass transfer coefficients – were evaluated. An agreement between the model-predicted results and the experimental data obtained was demonstrated. The four-phase integrated process provides simultaneously almost complete extraction and appreciable enrichment of the extracted product

Ferromagnetism and Lattice Distortions in the Perovskite YTiO3_3

The thermodynamic properties of the ferromagnetic perovskite YTiO$_3$ are investigated by thermal expansion, magnetostriction, specific heat, and magnetization measurements. The low-temperature spin-wave contribution to the specific heat, as well as an Arrott plot of the magnetization in the vicinity of the Curie temperature $T_C\simeq27$ K, are consistent with a three-dimensional Heisenberg model of ferromagnetism. However, a magnetic contribution to the thermal expansion persists well above $T_C$, which contrasts with typical three-dimensional Heisenberg ferromagnets, as shown by a comparison with the corresponding model system EuS. The pressure dependences of $T_C$ and of the spontaneous moment $M_s$ are extracted using thermodynamic relationships. They indicate that ferromagnetism is strengthened by uniaxial pressures $\mathbf{p}\parallel \mathbf{a}$ and is weakened by uniaxial pressures $\mathbf{p}\parallel \mathbf{b},\mathbf{c}$ and hydrostatic pressure. Our results show that the distortion along the $a$- and $b$-axes is further increased by the magnetic transition, confirming that ferromagnetism is favored by a large GdFeO$_3$-type distortion. The c-axis results however do not fit into this simple picture, which may be explained by an additional magnetoelastic effect, possibly related to a Jahn-Teller distortion.Comment: 12 pages, 13 figure

Spectroscopic distinction between the normal state pseudogap and the superconducting gap of cuprate high T_{c} superconductors

We report on broad-band infrared ellipsometry measurements of the c-axis conductivity of underdoped RBa_{2}Cu_{3}O_{7-d} (R=Y, Nd, and La) single crystals. Our data provide a detailed account of the spectral weight (SW) redistributions due to the normal state pseudogap (PG) and the superconducting (SC) gap. They show that these phenomena involve different energy scales, exhibit distinct doping dependencies and thus are likely of different origin. In particular, the SW redistribution in the PG state closely resembles the one of a conventional charge- or spin density wave (CDW or SDW) system.Comment: 4 pages, 4 figure

Recast layers on high speed steel surface after electrical discharge treatment in electrolyte

In this work are discussed some experimental data about the obtaining of recast layers on the surface of high speed tool steel after electrical discharge treatment in electrolyte. The electrical discharge treatment of steel surface in electrolyte produces a recast layer with specific combination of structure characteristics in result of nonequilibrium phase transformations. The modification goes by a high energy thermal process in electrical discharges on a very small area on the metallic surface involving melting, alloying and high speed cooling in the electrolyte. Obtained recast layers have a different structure in comparison with the metal matrix and are with higher hardness, wear- and corrosion resistance

Dipole-active optical phonons in YTiO_3: ellipsometry study and lattice-dynamics calculations

The anisotropic complex dielectric response was accurately extracted from spectroscopic ellipsometry measurements at phonon frequencies for the three principal crystallographic directions of an orthorhombic (Pbnm) YTiO_3 single crystal. We identify all twenty five infrared-active phonon modes allowed by symmetry, 7B_1u, 9B_2u, and 9B_3u, polarized along the c-, b-, and a-axis, respectively. From a classical dispersion analysis of the complex dielectric functions \tilde\epsilon(\omega) and their inverses -1/\tilde\epsilon(\omega) we define the resonant frequencies, widths, and oscillator strengths of the transverse (TO) and longitudinal (LO) phonon modes. We calculate eigenfrequencies and eigenvectors of B_1u, B_2u, and B_3u normal modes and suggest assignments of the TO phonon modes observed in our ellipsometry spectra by comparing their frequencies and oscillator strengths with those resulting from the present lattice-dynamics study. Based on these assignments, we estimate dynamical effective charges of the atoms in the YTiO_3 lattice. We find that, in general, the dynamical effective charges in YTiO_3 lattice are typical for a family of perovskite oxides. By contrast to a ferroelectric BaTiO_3, the dynamical effective charge of oxygen related to a displacement along the c-axis does not show the anomalously large value. At the same time, the dynamical effective charges of Y and ab-plane oxygen exhibit anisotropy, indicating strong hybridization along the a-axis.Comment: 8 pages, 7 figure

Extraction and Liquid-Membrane Preconcentration of Vincamine from Periwinkle (VincaMinor L.) Leaves. Process Modelling

An integrated process coupling solid-liquid extraction and liquid-membrane preconcentration of vincamine was studied. The effect of the ratios solid phase/extractant volume and extractant volume/liquid membrane volume on the mass transfer rate and efficiency of vincamine removal were estimated. It was found that the transfer rate and removal efficiency of the alkaloid were higher with smaller quantities of solids and membrane volume. A mathematical description of the overall integrated process was proposed, and the values of the model parameters – mass transfer coefficients – were evaluated. An agreement between the model-predicted results and the experimental data obtained was demonstrated. The four-phase integrated process provides simultaneously almost complete extraction and appreciable enrichment of the extracted product

Manifestation of pseudogap in ab-plane optical characteristics

A model in which a gap forms in the renormalized electronic density of state (DOS) with missing states recovered just above the pseudogap $\Delta_{pg}$, is able to give a robust description of the striking, triangular like, peak seen in the real part of the optical self-energy of underdoped cuprates. We use this model to explore the effect of the pseudogap on the real part of the optical conductivity and on the partial sum rule associated with it. An important result is that the optical spectral weight redistributes over a much larger frequency window than it does in the DOS.Comment: 12 pages, 3 figures. Submitted to Journal of Physics: Condensed Matte

Studying Flow Close to an Interface by Total Internal Reflection Fluorescence Cross Correlation Spectroscopy: Quantitative Data Analysis

Total Internal Reflection Fluorescence Cross Correlation Spectroscopy (TIR-FCCS) has recently (S. Yordanov et al., Optics Express 17, 21149 (2009)) been established as an experimental method to probe hydrodynamic flows near surfaces, on length scales of tens of nanometers. Its main advantage is that fluorescence only occurs for tracer particles close to the surface, thus resulting in high sensitivity. However, the measured correlation functions only provide rather indirect information about the flow parameters of interest, such as the shear rate and the slip length. In the present paper, we show how to combine detailed and fairly realistic theoretical modeling of the phenomena by Brownian Dynamics simulations with accurate measurements of the correlation functions, in order to establish a quantitative method to retrieve the flow properties from the experiments. Firstly, Brownian Dynamics is used to sample highly accurate correlation functions for a fixed set of model parameters. Secondly, these parameters are varied systematically by means of an importance-sampling Monte Carlo procedure in order to fit the experiments. This provides the optimum parameter values together with their statistical error bars. The approach is well suited for massively parallel computers, which allows us to do the data analysis within moderate computing times. The method is applied to flow near a hydrophilic surface, where the slip length is observed to be smaller than 10nm, and, within the limitations of the experiments and the model, indistinguishable from zero.Comment: 18 pages, 12 figure

Nuclear spins, magnetic moments and quadrupole moments of Cu isotopes from N = 28 to N = 46: probes for core polarization effects

Measurements of the ground-state nuclear spins, magnetic and quadrupole moments of the copper isotopes from 61Cu up to 75Cu are reported. The experiments were performed at the ISOLDE facility, using the technique of collinear laser spectroscopy. The trend in the magnetic moments between the N=28 and N=50 shell closures is reasonably reproduced by large-scale shell-model calculations starting from a 56Ni core. The quadrupole moments reveal a strong polarization of the underlying Ni core when the neutron shell is opened, which is however strongly reduced at N=40 due to the parity change between the $pf$ and $g$ orbits. No enhanced core polarization is seen beyond N=40. Deviations between measured and calculated moments are attributed to the softness of the 56Ni core and weakening of the Z=28 and N=28 shell gaps.Comment: 13 pagers, 19 figures, accepted by Physical Review