Mapping the 13CO/C18O abundance ratio in the massive star forming region G29.96-0.02

Estimating molecular abundances ratios from the direct measurement of the emission of the molecules towards a variety of interstellar environments is indeed very useful to advance in our understanding of the chemical evolution of the Galaxy, and hence of the physical processes related to the chemistry. It is necessary to increase the sample of molecular clouds, located at different distances, in which the behavior of molecular abundance ratios, such as the 13CO/C18O ratio (X), is studied in detail. We selected the well-studied high-mass star-forming region G29.96-0.02, located at a distance of about 6.2 kpc, which is an ideal laboratory to perform this kind of studies. To study the X towards this region it was used 12CO J=3-2 data obtained from COHRS, 13CO and C18O J=3-2 data from CHIMPS, and 13CO and C18O J=2-1 data retrieved from the CDS database (observed with the IRAM 30m telescope). The distribution of column densities and X throughout the molecular cloud was studied based on LTE and non-LTE methods. Values of X between 1.5 to 10.5, with an average of 5, were found, showing that, besides the dependency between X and the galactocentric distance, the local physical conditions may strongly affect this abundance ratio. We found that correlating the X map with the location of the ionized gas and dark clouds allows us to suggest in which regions the far-UV radiation stalls in dense gaseous components, and in which ones it escapes and selectively photodissociates the C18O isotope. The non-LTE analysis shows that the molecular gas has very different physical conditions, not only spatially across the cloud, but also along the line of sight. This kind of studies may represent a tool to indirectly estimate (from molecular lines observations) the degree of photodissociation in molecular clouds, which is indeed useful to study the chemistry in the interstellar medium.Comment: Accepted in A&A (July 10, 2018

Topological freeness for C∗C^*-correspondences

We study conditions that ensure uniqueness theorems of Cuntz-Krieger type for relative Cuntz-Pimsner algebras $\mathcal{O}(J,X)$ associated to a $C^*$-correspondence $X$ over a $C^*$-algebra $A$. We give general sufficient conditions phrased in terms of a multivalued map $\widehat{X}$ acting on the spectrum $\widehat{A}$ of $A$. When $X(J)$ is of Type I we construct a directed graph dual to $X$ and prove a uniqueness theorem using this graph. When $X(J)$ is liminal, we show that topological freeness of this graph is equivalent to the uniqueness property for $\mathcal{O}(J,X)$, as well as to an algebraic condition, which we call $J$-acyclicity of $X$. As an application we improve the Fowler-Raeburn uniqueness theorem for the Toeplitz algebra $\mathcal{T}_X$. We give new simplicity criteria for $\mathcal{O}_X$. We generalize and enhance uniqueness results for relative quiver $C^*$-algebras of Muhly and Tomforde. We also discuss applications to crossed products by endomorphisms.Comment: We have updated the list of references, fixed some typos and made other minor improvements. This is the version that will be publishe

The Right Match: A Strong Principal in Every Public School

This report has one central premise: Keeping great principals starts with hiring the right principal. Even as Chicago fights to retain principals long enough to make student learning and school culture gains more permanent, we must recognize some principal attrition is inevitable.More than 70,000 students started the 2016-17 school year with a new principal, and at least 60 schools will need a new principal each year for the foreseeable future. The stakes are high: No great public school exists without great leadership. In fact, variation in principal quality accounts for about 25 percent of a school's total impact on student learning. Yet, more than four out of every 10 public school principals in Chicago leave before they begin their fifth year. To keep great principals, we have to make the right match from the start

Evaluation of the economic and environmental performance of low-temperature heat to power conversion using a reverse electrodialysis - Multi-effect distillation system

In the examined heat engine, reverse electrodialysis (RED) is used to generate electricity from the salinity difference between two artificial solutions. The salinity gradient is restored through a multi-effect distillation system (MED) powered by low-temperature waste heat at 100 ◦C. The current work presents the first comprehensive economic and environmental analysis of this advanced concept, when varying the number of MED effects, the system sizing, the salt of the solutions, and other key parameters. The levelized cost of electricity (LCOE) has been calculated, showing that competitive solutions can be reached only when the system is at least medium to large scale. The lowest LCOE, at about 0.03 €/kWh, is achieved using potassium acetate salt and six MED effects while reheating the solutions. A similar analysis has been conducted when using the system in energy storage mode, where the two regenerated solutions are stored in reservoir tanks and the RED is operating for a few hours per day, supplying valuable peak power, resulting in a LCOE just below 0.10 €/kWh. A life-cycle assessment has been also carried out, showing that the case with the lowest environmental impact is the same as the one with the most attractive economic performance. Results indicate that the material manufacturing has the main impact; primarily the metallic parts of the MED. Overall, this study highlights the development efforts required in terms of both membrane performance and cost reduction, in order to make this technology cost effective in the future

GPU accelerated real-time multi-functional spectral-domain optical coherence tomography system at 1300 nm.

We present a GPU accelerated multi-functional spectral domain optical coherence tomography system at 1300 nm. The system is capable of real-time processing and display of every intensity image, comprised of 512 pixels by 2048 A-lines acquired at 20 frames per second. The update rate for all four images with size of 512 pixels by 2048 A-lines simultaneously (intensity, phase retardation, flow and en face view) is approximately 10 frames per second. Additionally, we report for the first time the characterization of phase retardation and diattenuation by a sample comprised of a stacked set of polarizing film and wave plate. The calculated optic axis orientation, phase retardation and diattenuation match well with expected values. The speed of each facet of the multi-functional OCT CPU-GPU hybrid acquisition system, intensity, phase retardation, and flow, were separately demonstrated by imaging a horseshoe crab lateral compound eye, a non-uniformly heated chicken muscle, and a microfluidic device. A mouse brain with thin skull preparation was imaged in vivo and demonstrated the capability of the system for live multi-functional OCT visualization

Evolutionary Genomics Suggests That CheV Is an Additional Adaptor for Accommodating Specific Chemoreceptors within the Chemotaxis Signaling Complex

Escherichia coli and Salmonella enterica are models for many experiments in molecular biology including chemotaxis, and most of the results obtained with one organism have been generalized to another. While most components of the chemotaxis pathway are strongly conserved between the two species, Salmonella genomes contain some chemoreceptors and an additional protein, CheV, that are not found in E. coli. The role of CheV was examined in distantly related species Bacillus subtilis and Helicobacter pylori, but its role in bacterial chemotaxis is still not well understood. We tested a hypothesis that in enterobacteria CheV functions as an additional adaptor linking the CheA kinase to certain types of chemoreceptors that cannot be effectively accommodated by the universal adaptor CheW. Phylogenetic profiling, genomic context and comparative protein sequence analyses suggested that CheV interacts with specific domains of CheA and chemoreceptors from an orthologous group exemplified by the Salmonella McpC protein. Structural consideration of the conservation patterns suggests that CheV and CheW share the same binding spot on the chemoreceptor structure, but have some affinity bias towards chemoreceptors from different orthologous groups. Finally, published experimental results and data newly obtained via comparative genomics support the idea that CheV functions as a “phosphate sink” possibly to off-set the over-stimulation of the kinase by certain types of chemoreceptors. Overall, our results strongly suggest that CheV is an additional adaptor for accommodating specific chemoreceptors within the chemotaxis signaling complex