Preventive conservation strategies for sustainable urban pollution control in museums

The last 40 years have seen major changes in the sources and concentrations of urban pollution (nitrogen dioxide, sulfur dioxide, hydrogen sulfide, and particulates). During this time, research has advanced our understanding of the impact of pollutants on objects in urban museums. As a consequence, pollutant control has become an important aspect of preventive conservation. There is also increased awareness of the need for pollution control strategies that are sustainable at an organizational and global level. This report, prepared by a chemist, a conservator, and two building scientists, reviews strategies for minimizing the impact of urban pollution on museum collections. The results of new research funded by the UK government identify current (1999) internal pollution levels in both naturally ventilated and air-conditioned museums with particle and gaseous filtration, in relation to external concentrations, ventilation strategies, and the characteristics of the internal fabric and finishes of these buildings. The last 40 years have seen major changes in the sources and concentrations of urban pollution (nitrogen dioxide, sulfur dioxide, hydrogen sulfide, and particulates). During this time, research has advanced our understanding of the impact of pollutants on objects in urban museums. As a consequence, pollutant control has become an important aspect of preventive conservation. There is also increased awareness of the need for pollution control strategies that are sustainable at an organizational and global level. This report, prepared by a chemist, a conservator, and two building scientists, reviews strategies for minimizing the impact of urban pollution on museum collections. The results of new research funded by the UK government identify current (1999) internal pollution levels in both naturally ventilated and air-conditioned museums with particle and gaseous filtration, in relation to external concentrations, ventilation strategies, and the characteristics of the internal fabric and finishes of these buildings

UV Interstellar Absorption Lines towards the Starburst Dwarf Galaxy NGC 1705

Archival Goddard High Resolution Spectrograph low-resolution spectra of NGC 1705, with wavelength ranges 1170.3 to 1461.7 A and 1453.5 to 1740.1 A and a velocity resolution of about 100 km\s, have been used to derive the velocity structure and equivalent widths of the absorption lines of Si II 1190.42, 1260.42, 1304.37 and 1526.71 A, S II 1253 , Al II 1670.79 Aand Fe II 1608.45 A in this sightline. Three relatively narrow absorption components are seen at LSR velocities --20 km/s, 260 km/sand 540 km/s. Arguments are presented to show these absorption features are interstellar rather than stellar in origin based on a comparison with the C III 1175.7 A absorption feature. We identify the --20 km/s component with Milky Way disk/halo gas and the 260 km/s component with an isolated high-velocity cloud HVC 487. This small HVC is located about 10 degrees from the H I gas which envelops the Magellanic Clouds and the Magellanic Stream (MS). The (Si/H) ratio for this HVC is > 0.6 (Si/H)solar which together with velocity agreement, suggests association with the Magellanic Cloud and MS gas. H-alpha emission line kinematics of NGC 1705 show the presence of a kpc-scale expanding supershell of ionized gas centered on the central nucleus with a blue-shifted emission component at 540 km/s (Meurer et al. 1992). We identify the 540 km/s absorption component seen in the GHRS spectra with the front side of this expanding, ionized supershell. The most striking feature of this component is strong Si II and Al II absorption but weak Fe II 1608 A absorption. The low Fe II column density derived is most likely intrinsic since it cannot be accounted for by ionization corrections or dust depletion. Due to their shallow gravitational potential wells, dwarf galaxies have small gravitational binding energies and are vulnerable to largeComment: 15 pages, LaTEX, 1 figure. Accepted for publication in Astrophysical Journal Letter

Investigation of Substituted-Benzene Dopants for Charge Exchange Ionization of Nonpolar Compounds by Atmospheric Pressure Photoionization

Atmospheric pressure photoionization (APPI) using a dopant enables both polar and nonpolar compounds to be analyzed by LC/MS. To date, the charge exchange ionization pathway utilized for nonpolar compounds has only been efficient under restrictive conditions, mainly because the usual charge exchange reagent ions—the dopant photoions themselves—tend to be consumed in proton transfer reactions with solvent and/or dopant neutrals. This research aims to elucidate the factors affecting the reactivities of substituted-benzene dopant ions; another, overriding, objective is to discover new dopants for better implementing charge exchange ionization in reversed-phase LC/MS applications. The desirable properties for a charge exchange dopant include low reactivity of its photoions with solvent and dopant neutrals and high ionization energy (IE). Reactivity tests were performed for diverse substituted-benzene compounds, with substituents ranging from strongly electron withdrawing (EW) to strongly electron donating (ED). The results indicate that both the tendency of a dopant's photoions to be lost through proton transfer reactions and its IE depend on the electron donating/withdrawing properties of its substituent(s): ED groups decrease reactivity and IE, while EW groups increase reactivity and IE. Exceptions to the reactivity trend for dopants with ED groups occur when the substituent is itself acidic. All told, the desirable properties for a charge exchange dopant tend towards mutual exclusivity. Of the singly-substituted benzenes tested, chloro- and bromobenzene provide the best compromise between low reactivity and high IE. Several fluoroanisoles, with counteracting EW and ED groups, may also provide improved performance relative to the established dopants

Lyman-alpha absorption around nearby galaxies

We have used STIS aboard HST to search for Lyman-alpha (Lya) absorption lines in the outer regions of eight nearby galaxies using background QSOs and AGN as probes. Lya lines are detected within a few hundred km/s of the systemic velocity of the galaxy in all cases. We conclude that a background line-of-sight which passes within 26-200 h-1 kpc of a foreground galaxy is likely to intercept low column density neutral hydrogen with log N(HI) >~ 13.0. The ubiquity of detections implies a covering factor of ~ 100% for low N(HI) gas around galaxies within 200 h-1 kpc. We discuss the difficulty in trying to associate individual absorption components with the selected galaxies and their neighbors, but show that by degrading our STIS data to lower resolutions, we are able to reproduce the anti-correlation of Lya equivalent width and impact parameter found at higher redshift. We also show that the equivalent width and column density of Lya complexes (when individual components are summed over ~ 1000 km/s) correlate well with a simple estimate of the volume density of galaxies brighter than M(B) = -17.5 at the same redshift as a Lya complex. We do not reject the hypothesis that the selected galaxies are directly responsible for the observed Lya lines, but our analysis indicates that absorption by clumpy intragroup gas is an equally likely explanation. (Abriged)Comment: Accepted for publication in Nov 20, 2002 issue of ApJ. Paper with all figures can be found at http://www.astro.princeton.edu/~dvb/lyapaper.ps (preferable). Minor typos fixe

Space Telescope Imaging Spectrograph slitless observations of Small Magellanic Cloud Planetary Nebulae: a study on morphology, emission line intensity, and evolution

A sample of 27 Planetary Nebulae (PNs) in the Small Magellanic Clouds (SMC) have been observed with the Hubble Space Telescope Imaging Spectrograph (HST/STIS) to determine their morphology, size, and the spatial variation of the ratios of bright emission lines. The morphologies of SMC PNs are similar to those of LMC and Galactic PNs. However, only a third of the resolved SMC PNs are asymmetric, compared to half in the LMC. The low metallicity environment of the SMC seems to discourage the onset of bipolarity in PNs. We measured the line intensity, average surface brightness (SB), and photometric radius of each nebula in halpha, hbeta, [O III] lambda4959 and 5007, [NII] 6548 and 6584, [S II] lambda6716 and 5731, He I 6678, and [OI] 6300 and 6363. We show that the surface brightness to radius relationship is the same as in LMC PNs, indicating its possible use as a distance scale indicator for Galactic PNs. We determine the electron densities and the ionized masses of the nebulae where the [S II] lines were measured accurately, and we find that the SMC PNs are denser than the LMC PNs by a factor of 1.5. The average ionized mass of the SMC PNs is 0.3 Msun. We also found that the median [O III]/hbeta intensity ratio in the SMC is about half than the corresponding LMC median. We use Cloudy to model the dependence of the [O III]/hbeta ratio on the oxygen abundance. Our models encompass very well the average observed physical quantities. We suggest that the SMC PNs are principally cooled by the carbon lines, making it hard to study their excitation based on the optical lines at our disposal.Comment: Accepted for publication in the Astrophysical Journal, 30 pages, 13 figures, 6 tables. For high resolution version of Figs 1 to 6, see http://archive.stsci.edu/hst/mcpn/home.htm

Large Magellanic Cloud Planetary Nebula Morphology: Probing Stellar Populations and Evolution

Planetary Nebulae (PNe) in the Large Magellanic Cloud (LMC) offer the unique opportunity to study both the Population and evolution of low- and intermediate-mass stars, by means of the morphological type of the nebula. Using observations from our LMC PN morphological survey, and including images available in the HST Data Archive, and published chemical abundances, we find that asymmetry in PNe is strongly correlated with a younger stellar Population, as indicated by the abundance of elements that are unaltered by stellar evolution (Ne, Ar, S). While similar results have been obtained for Galactic PNe, this is the first demonstration of the relationship for extra-galactic PNe. We also examine the relation between morphology and abundance of the products of stellar evolution. We found that asymmetric PNe have higher nitrogen and lower carbon abundances than symmetric PNe. Our two main results are broadly consistent with the predictions of stellar evolution if the progenitors of asymmetric PNe have on average larger masses than the progenitors of symmetric PNe. The results bear on the question of formation mechanisms for asymmetric PNe, specifically, that the genesis of PNe structure should relate strongly to the Population type, and by inference the mass, of the progenitor star, and less strongly on whether the central star is a member of a close binary system.Comment: The Astrophysical Journal Letters, in press 4 figure

Ca II and Na I Quasar Absorption-Line Systems in an Emission-Selected Sample of SDSS DR7 Galaxy/Quasar Projections: I. Sample Selection

The aim of this project is to identify low-redshift host galaxies of quasar absorption-line systems by selecting galaxies which are seen in projection onto quasar sightlines. To this end, we use the Seventh Data Release of the Sloan Digital Sky Survey (SDSS-DR7) to construct a parent sample of 97489 galaxy/quasar projections at impact parameters of up to 100 kpc to the foreground galaxy. We then search the quasar spectra for absorption line systems of Ca II and Na I within +- 500 km/s of the galaxy's velocity. This yields 92 Ca II and 16 Na I absorption systems. We find that most of the Ca II and Na I systems are sightlines through the Galactic disk, through High Velocity Cloud complexes in our halo, or Virgo cluster sightlines. Placing constraints on the absorption line rest equivalent width significance (>=3.0 sigma), the Local Standard of Rest velocity along the sightline (>= 345 km/s), and the ratio of the impact parameter to the galaxy optical radius (<=5.0), we identify 4 absorption line systems that are associated with low-redshift galaxies at high confidence, consisting of two Ca II systems (one of which also shows Na I), and two Na I systems. These 4 systems arise in blue, L_r^* galaxies. Tables of the 108 absorption systems are provided to facilitate future follow up.Comment: 13 pages, 11 figures, 6 tables; online data included in electronic version as 1 FITS table and 2 machine readable tables; to be published in The Astronomical Journa

Thermal Pressures in Neutral Clouds inside the Local Bubble, as Determined from C I Fine-Structure Excitations

High-resolution spectra covering absorption features from interstellar C I were recorded for four early-type stars with spectrographs on HST, in a program to measure the fine-structure excitation of this atom within neutral clouds inside or near the edge of the Local Bubble, a volume of hot (T ~ 10^6 K) gas that emits soft x-rays and extends out to about 100 pc away from the Sun. The excited levels of C I are populated by collisions, and the ratio of excited atoms to those in the ground level give a measure of the local thermal pressure. Absorptions from the two lowest levels of C I were detected toward alpha Del and delta Cyg, while only marginal indications of excited C I were obtained for gamma Ori, and lambda Lup. Along with temperature limits derived by other means, the C I fine-structure populations indicate that for the clouds in front of gamma Ori, delta Cyg and alpha Del, 10^3 < p/k < 10^4 cm^{-3}K at about the +-1 sigma confidence level in each case. The results for lambda Lup are not as well constrained, but still consistent with the other three stars. The results indicate that the thermal pressures are below generally accepted estimates p/k > 10^4 cm^{-3}K for the Local Bubble, based on the strength of x-ray and EUV emission from the hot gas. This inequality of pressure for these neutral clouds and their surroundings duplicates a condition that exists for the local, partly-ionized cloud that surrounds the Sun. An appendix in the paper describes a direct method for determining and eliminating small spectral artifacts arising from variations of detector sensitivity with position.Comment: 33 pages, 7 figures, submitted to the Astrophysical Journa

Interstellar and Circumstellar Optical & Ultraviolet Lines Towards SN1998S

We have observed SN1998S which exploded in NGC3877, with the UES at the WHT and with the E230M echelle of STIS aboard HST. Both data sets were obtained at two seperate epochs. From our own Galaxy we detect interstellar absorption lines of CaII, FeII, MgI, and probably MnII from the edge of the HVC Complex M. We derive gas-phase abundances which are very similar to warm disk clouds in the local ISM, which we believe argues against the HVC material having an extragalactic origin. At the velocity of NGC3877 we detect interstellar MgI, MgII, MnII, CaII, & NaI. Surprisingly, one component is seen to increase by a factor of ~1 dex in N(NaI) and N(MgI) between the two epochs over which the data were taken. Unusually, our data also show narrow Balmer, HeI, and metastable FeII P-Cygni profiles, with a narrow absorption component superimposed on the bottom of the profile's absorption trough. Both the broad and narrow components of the optical lines are seen to increase substantially in strength between the two epochs. Most of the low-ionization absorption can be understood in terms of gas co-rotating with the disk of NGC 3877, providing the SN is at the back of an HI disk with a similar thickness to that of our own Galaxy. However, the variable absorption components, and the classic P-Cygni emission profiles, most likely arise in slow-moving circumstellar outflows originating from the red supergiant progenitor of SN1998S. [Abridged.]Comment: Accepted by ApJ, 26 pages including 9 figure