2,156 research outputs found

    The kinetics and mechanism of the uranium hydride - water vapour system under ambient conditions

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    A review of the reaction rates of uranium corrosion in water

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    The effect of sample preparation on uranium hydriding

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    AbstractThe influence of sample cleaning preparation on the early stages of uranium hydriding has been examined, by using four identical samples but concurrently prepared using four different methods. The samples were reacted together in the same corrosion cell to ensure identical exposure conditions. From the analysis, it was found that the hydride nucleation rate was proportional to the level of strain exhibiting higher number density for the more strained surfaces. Additionally, microstructure of the metal plays a secondary role regarding initial hydrogen attack on the highly strained surfaces yet starts to dominate the system while moving to more pristine samples

    Gamma Irradiation in Fibre Bragg Gratings

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    We report a preliminary study of gamma radiation effects on the current generation of optical fibre Bragg grating sensors, and the effects of relaxation after gamma irradiation, as a function of dose

    Nature of the spin-glass phase at experimental length scales

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    We present a massive equilibrium simulation of the three-dimensional Ising spin glass at low temperatures. The Janus special-purpose computer has allowed us to equilibrate, using parallel tempering, L=32 lattices down to T=0.64 Tc. We demonstrate the relevance of equilibrium finite-size simulations to understand experimental non-equilibrium spin glasses in the thermodynamical limit by establishing a time-length dictionary. We conclude that non-equilibrium experiments performed on a time scale of one hour can be matched with equilibrium results on L=110 lattices. A detailed investigation of the probability distribution functions of the spin and link overlap, as well as of their correlation functions, shows that Replica Symmetry Breaking is the appropriate theoretical framework for the physically relevant length scales. Besides, we improve over existing methodologies to ensure equilibration in parallel tempering simulations.Comment: 48 pages, 19 postscript figures, 9 tables. Version accepted for publication in the Journal of Statistical Mechanic

    On the integrability of symplectic Monge-Amp\'ere equations

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    Let u be a function of n independent variables x^1, ..., x^n, and U=(u_{ij}) the Hessian matrix of u. The symplectic Monge-Ampere equation is defined as a linear relation among all possible minors of U. Particular examples include the equation det U=1 governing improper affine spheres and the so-called heavenly equation, u_{13}u_{24}-u_{23}u_{14}=1, describing self-dual Ricci-flat 4-manifolds. In this paper we classify integrable symplectic Monge-Ampere equations in four dimensions (for n=3 the integrability of such equations is known to be equivalent to their linearisability). This problem can be reformulated geometrically as the classification of 'maximally singular' hyperplane sections of the Plucker embedding of the Lagrangian Grassmannian. We formulate a conjecture that any integrable equation of the form F(u_{ij})=0 in more than three dimensions is necessarily of the symplectic Monge-Ampere type.Comment: 20 pages; added more details of proof

    Dielectric and optical evaluation of high-emissivity coatings for temperature measurements in microwave applications

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    In this work, several commercial high-emissivity coatings have been characterized in terms of emissivity, chemical composition and dielectric properties as a function of temperature, under microwave irradiation. Accurate knowledge of their response under exposure to microwaves provides new and crucial information about their practical usability for non-contact temperature measurements in microwave environments. Due to their high metallic content, some of the studied coatings exhibited unexpected microwave-triggered reactions that hindered their use up to the maximum temperature specified by the manufacturers. Emissivity and chemical analyses before and after the heating cycles confirmed the degradation of some of the samples predicted by dielectric measurements. This work illustrates how a careful characterization of optical and dielectric properties under representative operating conditions (temperature range, microwave exposure) is vital in order to select the appropriate reference coating to obtain reliable temperature measurements in microwave applications
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