Effects of Confinement on Critical Adsorption: Absence of Critical Depletion for Fluids in Slit Pores

The adsorption of a near-critical fluid confined in a slit pore is investigated by means of density functional theory and by Monte Carlo simulation for a Lennard-Jones fluid. Our work was stimulated by recent experiments for SF_6 adsorbed in a mesoporous glass which showed the striking phenomenon of critical depletion, i.e. the adsorption excess "Gamma" first increases but then decreases very rapidly to negative values as the bulk critical temperature T_c is approached from above along near-critical isochores. By contrast, our density functional and simulation results, for a range of strongly attractive wall-fluid potentials, show Gamma monotonically increasing and eventually saturating as the temperature is lowered towards T_c along both the critical (rho=rho_c) and sub-critical isochores (rho<\rho_c). Such behaviour results from the increasingly slow decay of the density profile away from the walls, into the middle of the slit, as T->T_c. For rho < rho_c we find that in the fluid the effective bulk field, which is negative and which favours desorption, is insufficient to dominate the effects of the surface fields which favour adsorption. We compare this situation with earlier results for the lattice gas model with a constant (negative) bulk field where critical depletion was found. Qualitatively different behaviour of the density profiles and adsorption is found in simulations for intermediate and weakly attractive wall-fluid potentials but in no case do we observe the critical depletion found in experiments. We conclude that the latter cannot be accounted for by a single pore model.Comment: 21 pages Revtex. Submitted to Phys. Rev.

Stability of some epoxy-encapsulated diode thermometers

The stability upon thermal cycling and handling of ten small, epoxy-encapsulated silicon diode thermometers at six temperatures in the range from liquid nitrogen temperatures to about 60 C. The nominal temperatures of measurement were -196, -78, 0, 20, 40, and 60 C, as measured on the International Practical Temperature Scale of 1968. Diodes were to be thermally cycled 15 to 20 times. Since NASA anticipates that the uncertainty in their temperature measurements will be + or - 50 mK, uncertainties as large as + or - 10 mK in the measurements of the evaluaton can be accommodated without deleteriously affecting the value of the results of the investigation

A variable rate speech compressor for mobile applications

One of the most promising speech coder at the bit rate of 9.6 to 4.8 kbits/s is CELP. Code Excited Linear Prediction (CELP) has been dominating 9.6 to 4.8 kbits/s region during the past 3 to 4 years. Its set back however, is its expensive implementation. As an alternative to CELP, the Base-Band CELP (CELP-BB) was developed which produced good quality speech comparable to CELP and a single chip implementable complexity as reported previously. Its robustness was also improved to tolerate errors up to 1.0 pct. and maintain intelligibility up to 5.0 pct. and more. Although, CELP-BB produces good quality speech at around 4.8 kbits/s, it has a fundamental problem when updating the pitch filter memory. A sub-optimal solution is proposed for this problem. Below 4.8 kbits/s, however, CELP-BB suffers from noticeable quantization noise as a result of the large vector dimensions used. Efficient representation of speech below 4.8 kbits/s is reported by introducing Sinusoidal Transform Coding (STC) to represent the LPC excitation which is called Sine Wave Excited LPC (SWELP). In this case, natural sounding good quality synthetic speech is obtained at around 2.4 kbits/s

Wick's Theorem for non-symmetric normal ordered products and contractions

We consider arbitrary splits of field operators into two parts, and use the corresponding definition of normal ordering introduced by Evans and Steer. In this case the normal ordered products and contractions have none of the special symmetry properties assumed in existing proofs of Wick's theorem. Despite this, we prove that Wick's theorem still holds in its usual form as long as the contraction is a c-number. Wick's theorem is thus shown to be much more general than existing derivations suggest, and we discuss possible simplifying applications of this result.Comment: 17 page

Spacetime Supersymmetry in a nontrivial NS-NS Superstring Background

In this paper we consider superstring propagation in a nontrivial NS-NS background. We deform the world sheet stress tensor and supercurrent with an infinitesimal B_{\mu\nu} field. We construct the gauge-covariant super-Poincare generators in this background and show that the B_{\mu\nu} field spontaneously breaks spacetime supersymmetry. We find that the gauge-covariant spacetime momenta cease to commute with each other and with the spacetime supercharges. We construct a set of "magnetic" super-Poincare generators that are conserved for constant field strength H_{\mu\nu\lambda}, and show that these generators obey a "magnetic" extension of the ordinary supersymmetry algebra.Comment: 13 pages, Latex. Published versio

Incoherent matter-wave solitons

The dynamics of matter-wave solitons in Bose-Einstein condensates (BEC) is considerably affected by the presence of a surrounding thermal cloud and by condensate depletion during its evolution. We analyze these aspects of BEC soliton dynamics, using time-dependent Hartree-Fock-Bogoliubov (TDHFB) theory. The condensate is initially prepared within a harmonic trap at finite temperature, and solitonic behavior is studied by subsequently propagating the TDHFB equations without confinement. Numerical results demonstrate the collapse of the BEC via collisional emission of atom pairs into the thermal cloud, resulting in splitting of the initial density into two solitonic structures with opposite momentum. Each one of these solitary matter waves is a mixture of condensed and noncondensed particles, constituting an analog of optical random-phase solitons.Comment: 4 pages, 2 figures, new TDHFB result