982 research outputs found
Concerted [4+2] and stepwise [2+2]cycloadditions of the triphenylallenyl cation with cyclopentadiene
Entanglement and secret-key-agreement capacities of bipartite quantum interactions and read-only memory devices
A bipartite quantum interaction corresponds to the most general quantum
interaction that can occur between two quantum systems in the presence of a
bath. In this work, we determine bounds on the capacities of bipartite
interactions for entanglement generation and secret key agreement between two
quantum systems. Our upper bound on the entanglement generation capacity of a
bipartite quantum interaction is given by a quantity called the bidirectional
max-Rains information. Our upper bound on the secret-key-agreement capacity of
a bipartite quantum interaction is given by a related quantity called the
bidirectional max-relative entropy of entanglement. We also derive tighter
upper bounds on the capacities of bipartite interactions obeying certain
symmetries. Observing that reading of a memory device is a particular kind of
bipartite quantum interaction, we leverage our bounds from the bidirectional
setting to deliver bounds on the capacity of a task that we introduce, called
private reading of a wiretap memory cell. Given a set of point-to-point quantum
wiretap channels, the goal of private reading is for an encoder to form
codewords from these channels, in order to establish secret key with a party
who controls one input and one output of the channels, while a passive
eavesdropper has access to one output of the channels. We derive both lower and
upper bounds on the private reading capacities of a wiretap memory cell. We
then extend these results to determine achievable rates for the generation of
entanglement between two distant parties who have coherent access to a
controlled point-to-point channel, which is a particular kind of bipartite
interaction.Comment: v3: 34 pages, 3 figures, accepted for publication in Physical Review
Limitations on Quantum Key Repeaters
A major application of quantum communication is the distribution of entangled
particles for use in quantum key distribution (QKD). Due to noise in the
communication line, QKD is in practice limited to a distance of a few hundred
kilometres, and can only be extended to longer distances by use of a quantum
repeater, a device which performs entanglement distillation and quantum
teleportation. The existence of noisy entangled states that are undistillable
but nevertheless useful for QKD raises the question of the feasibility of a
quantum key repeater, which would work beyond the limits of entanglement
distillation, hence possibly tolerating higher noise levels than existing
protocols. Here we exhibit fundamental limits on such a device in the form of
bounds on the rate at which it may extract secure key. As a consequence, we
give examples of states suitable for QKD but unsuitable for the most general
quantum key repeater protocol.Comment: 11+38 pages, 4 figures, Statements for exact p-bits weakened as
non-locking bound on measured relative entropy distance contained an erro
Carbocationic cyclisations and rearrangements in the damascone series
A regio- and stereoselective synthesis of the tertiary chloride 7 is described, involving the Lewis acid catalysed addition of the allyl chloride 6 to isobutene as a key step. Acid catalysed cyclisation of 7 yields the damasconoid compounds 12–15
Synthesis of cyclopentenes via [3 + 2]-cycloadditions of silylated propargyl .tautm. allenyl cations with alkenes
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