Phyllosilicate Transitions in Ferromagnesian Soils: Short-Range Order Materials and Smectites Dominate Secondary Phases

Analyses of X-ray diffraction (XRD) patterns taken by the CheMin instrument on the Curiosity Rover in Gale crater have documented the presence of clay minerals interpreted as smectites and a suite of amorphous to short-range order materials termed X-ray amorphous materials. These X-ray amorphous materials are commonly ironrich and aluminum poor and likely some of them are weathering products rather than primary glasses due to the presence of volatiles. Outstanding questions remain regarding the chemical composition and mineral structure of these X-ray amorphous materials and the smectites present at Gale crater and what they indicate about environmental conditions during their formation. To gain a better understanding of the mineral transitions that occur within ferromagnesian parent materials, we have investigated the development of secondary clay minerals and shortrange order materials in two soil chronosequences with varying climates developing on ultramafic bedrock. Field Sites: We investigated soil weathering within two field locations, the Klamath Mountains of Northern California, and the Tablelands of Newfoundland, Canada. Both sites possess age dated or correlated recently deglaciated soils and undated but substantially older soils. In the Klamath mountains the Trinity Ultramafic Body was deglaciated roughly 15,000 years bp while in the Tablelands a moraine was dated to about 17,600 years bp. The Klamath Mountains feature a seasonally wet and dry climate while the Tablelands are wet year-round with saturated soil conditions observed during sampling and standing water observed within 3 of 4 soil pit sampling locations

Plasma processes to detect fluorine with ICPMS as M-F+ : an argument for building a negative mode ICPMS/MS

NLAJ thanks the Malaysian Government (Grant number: RG12824-10) and National Defence University of Malaysia for financial support throughout the study period, while AB thanks the Erasmus programme of the EU. Special thanks to Swedish Research Council for additional financial support (Grant number: FORMAS 1397306) and also to Samira Al Hinai and Amanda Victor for helping in this project.Peer reviewedPostprin

Towards federated satellite systems and internet of satellites: the federation deployment control protocol

Presently, the Earth Observation community is demanding applications that provide low latency and high downlink capabilities. An increase in downlink contacts becomes essential to meet these new requirements. The Federated Satellite Systems concept addresses this demand by promoting satellite collaborations to share unused downlink opportunities. These collaborations are established opportunistically and temporarily, posing multiple technology challenges to be implemented in-orbit. This work contributes to the definition of the Federation Deployment Control Protocol which formalizes a mechanism to fairly establish and manage these collaborations by employing a negotiation process between the satellites. Moreover, this manuscript presents the results of a validation campaign of this protocol with three stratospheric balloons. In summary, more than 27 federations with 63.0% of throughput were established during the field campaign. Some of these federations were used to download data to the ground, and others were established to balance data storage between balloons. These federations allowed also the extension of the coverage of a ground station with a federation that relayed data through a balloon, and the achievement of a hybrid scenario with one balloon forwarding data from a ground device. The results demonstrate that the proposed protocol is functional and ready to be embedded in a CubeSat mission.This work has been (partially) funded by “CommSensLab” Excellence Research Unit Maria de Maeztu (MINECO grant MDM-2016-0600), the Spanish Ministerio MICINN and EU ERDF project “SPOT: Sensing with pioneering opportunistic techniques” (grant RTI2018-099008-BC21/AEI/10.13039/501100011033), by the grant PID2019-106808RA-I00/AEI/FEDER/UE from the EDRF and the Spanish Government, and by the Secretaria d’Universitats i Recerca del Departament d’Empresa i Coneixement de la Generalitat de Catalunya (2017 SGR 376, and 2017 SGR 219).Peer ReviewedPostprint (published version

Metabolomics as an emerging tool in the search for astrobiologically relevant biomarkers

© The Author(s), 2020. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Seyler, L., Kujawinski, E. B., Azua-Bustos, A., Lee, M. D., Marlow, J., Perl, S. M., & Cleaves, H. J. Metabolomics as an emerging tool in the search for astrobiologically relevant biomarkers. Astrobiology, (2020), doi:10.1089/ast.2019.2135.It is now routinely possible to sequence and recover microbial genomes from environmental samples. To the degree it is feasible to assign transcriptional and translational functions to these genomes, it should be possible, in principle, to largely understand the complete molecular inputs and outputs of a microbial community. However, gene-based tools alone are presently insufficient to describe the full suite of chemical reactions and small molecules that compose a living cell. Metabolomic tools have developed quickly and now enable rapid detection and identification of small molecules within biological and environmental samples. The convergence of these technologies will soon facilitate the detection of novel enzymatic activities, novel organisms, and potentially extraterrestrial life-forms on solar system bodies. This review explores the methodological problems and scientific opportunities facing researchers who hope to apply metabolomic methods in astrobiology-related fields, and how present challenges might be overcome.This study was partially supported by the ELSI Origins Network (EON), which is supported by a grant from the John Templeton Foundation. The opinions expressed in this publication are those of the authors and do not necessarily reflect the views of the John Templeton Foundation. This work was partially supported by a JSPS KAKENHI Grant-in-Aid for Scientific Research on Innovative Areas “Hadean Bioscience,” grant number JP26106003, and also partially supported by Project “icyMARS,” funded by the European Research Council, ERC Starting Grant No. 307496. A.A-B thanks the contribution from the Project “MarsFirstWater,” funded by the European Research Council, ERC Consolidator Grant No. 818602 and the HFSP Project UVEnergy RGY0066/2018

Relativistic effects on the nuclear magnetic shielding tensor

A new approach for calculating relativistic corrections to the nuclear magnetic shieldings is presented. Starting from a full relativistic second order perturbation theory expression a two-component formalism is constructed by transforming matrix elements using the elimination of small component scheme and separating out the contributions from the no-virtual pair and the virtual pair part of the second order corrections to the energy. In this way we avoid a strong simplification used previously in the literature. We arrive at final expressions for the relativistic corrections which are equivalent to those of Fukui et al. J. Chem Phys. 105, 3175 (1996) and at some other additional terms correcting both the paramagnetic and the diamagnetic part of the nuclear magnetic shielding. Results for some relativistic corrections to the shieldings of the heavy and light nuclei in HX and CHȝX (X=Br,I) at both random phase and second order polarization propagator approach levels are given.Fil: Melo, Juan Ignacio. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Física de Buenos Aires. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Física de Buenos Aires; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; ArgentinaFil: Ruiz de Azua, Martín César. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; ArgentinaFil: Giribet, Claudia Gloria. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Departamento de Física; ArgentinaFil: Aucar, Gustavo Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura. Departamento de Física; ArgentinaFil: Romero, Rodolfo Horacio. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad Nacional del Nordeste. Facultad de Ciencias Exactas y Naturales y Agrimensura. Departamento de Física; Argentin

Metabolomics As an Emerging Tool in the Search for Astrobiologically Relevant Biomarkers

It is now routinely possible to sequence and recover microbial genomes from environmental samples. To the degree it is feasible to assign transcriptional and translational functions to these genomes, it should be possible, in principle, to largely understand the complete molecular inputs and outputs of a microbial community. However, gene-based tools alone are presently insufficient to describe the full suite of chemical reactions and small molecules that compose a living cell. Metabolomic tools have developed quickly and now enable rapid detection and identification of small molecules within biological and environmental samples. The convergence of these technologies will soon facilitate the detection of novel enzymatic activities, novel organisms, and potentially extraterrestrial life-forms on solar system bodies. This review explores the methodological problems and scientific opportunities facing researchers who hope to apply metabolomic methods in astrobiology-related fields, and how present challenges might be overcome

Design of a deployable helix antenna at L-Band for a 1-Unit CubeSat: from theoretical analysis to flight model results

The 3Cat-4 mission aims at demonstrating the capabilities of a CubeSat to perform Earth Observation (EO) by integrating a combined GNSS-R and Microwave Radiometer payload into a 1-Unit CubeSat. One of the greatest challenges is the design of an antenna that respects the 1-Unit CubeSat envelope while operating at the different frequency bands: Global Positioning System (GPS) L1 and Galileo E1 band (1575 MHz), GPS L2 band (1227 MHz), and the microwave radiometry band (1400–1427 MHz). Moreover, it requires between 8 and 12 dB of directivity depending on the band whilst providing at least 10 dB of front-to-back lobe ratio in L1 and L2 GPS bands. After a trade-off analysis on the type of antenna that could be used, a helix antenna was found to be the most suitable option to comply with the requirements, since it can be stowed during launch and deployed once in orbit. This article presents the antenna design from a radiation performance point of view starting with a theoretical analysis, then presenting the numerical simulations, the measurements in an Engineering Model (EM), and finally the final design and performance of the Flight Model (FM)This work was supported by the Spanish Ministry of Economy and Competitiveness, by the Spanish Ministry of Science, Innovation and Universities, “Sensing with Pioneering Opportunistic Techniques”, grant RTI2018-099008-B-C21/AEI/10.13039/501100011033, also funded in part by the Secretaria d’Universitats i Recerca del Departament d’Empresa i Coneixement de la Generalitat de Catalunya 2017 SGR 219. Finally, this research was possible thanks to the FI-2019 grant from AGAUR-Generalitat de Catalunya.Peer ReviewedPostprint (published version

Design and validation of a dual-band circular polarization patch antenna and stripline combiner for the FSSCat mission

The FMPL-2 payload on board the 3Cat-5/A 6 Unit CubeSat, part of the FSSCat CubeSat mission, includes a dual L-Band Microwave Radiometer and a Global Navigation Satellite System Reflectometer, in one instrument, implemented in a Software Defined Radio. One of the design challenges of this payload was its Nadir looking Antenna, which had to be directive (> 12 dB), dual-band at 1400–1427 MHz and 1575.42 MHz, left-hand circularly polarized, and with important envelope restrictions, notably with a low profile. After a trade-off analysis, the best design solution appeared to be an array of six elements each of them being a stacked dual-band patch antenna, with diagonal feed to create the circular polarization, and a six to one stripline combiner. The design process of the elementary antennas first includes a theoretical analysis, to obtain the approximate dimensions. Then, by means of numerical simulations, prototyping, and adjusting the results in the simulations, the manufacturing errors and dielectric constant tolerances, to which patch antennas are very sensitive, can be characterized. A similar approach is taken with the combiner. This article includes the theoretical analysis, simulations, and prototype results, including the Flight Model assembly and characterizationThis work was by the Programa Estatal para Impulsar la Investigación Científico-Técnica y su Transferencia, del Plan Estatal de Investigación Científica, Técnica y de Innovación 2021-2023 (Spain) and in part by the European Social Fund (ESF). It is also funded in part by the Secretaria d’Universitats i Recerca del Departament d’Empresa i Coneixement de la Generalitat de Catalunya 2017 SGR 376 and 2017 SGR 219. This work has also been founded by the grant PID2019-106808RA-I00 funded by MCIN/AEI/10.13039/501100011033. Finally, this research was possible thanks to the FI-2019 grant from AGAUR-Generalitat de Catalunya, Spain.Peer ReviewedPostprint (published version

Novel non-targeted analysis of perfluorinated compounds using fluorine-specific detection regardless of their ionisability (HPLC-ICPMS/MS-ESI-MS)

NLAJ thanks the Malaysian Government (Grant number: RG12824-10) and the National Defence University of Malaysia for financial support throughout the study period, while JFD thanks the Erasmus program of the EU. Special thanks to the Swedish Research Council (Grant number: FORMAS 1397306) for additional financial support in this project.Peer reviewedPostprin