In situ evidence for renitrification in the Arctic lower stratosphere during the polar aura validation experiment (PAVE)

In-situ measurements of nitric acid (HNO3), ozone (O3), and nitrous oxide (N2O) were made from the NASA DC-8 during the Polar Aura Validation Experiment in January/February 2005. In the lower stratosphere (9–12.5 km, potential temperature 300–350 K) characteristic compact relationships were observed between all three gases. The ratio HNO3/O3 averaged 3.5 (±0.7) ppt/ppb. Samples with enhanced HNO3/O3 (\u3e4.0) were most abundant under the edge of the Arctic Polar vortex in airmasses with enhanced mixing ratios of both gases (\u3e400 ppb O3 and \u3e2000 ppt HNO3) and reduced mixing ratios of N2O (\u3c305 ppb), indicating air from higher levels in the stratosphere. Relationships to N2O in the anomalous samples under the vortex edge indicate that increases in HNO3/O3 reflect renitrification at DC-8 flight levels, with no indication of significant O3 loss. Renitrified air was only observed at potential temperatures above 340 K, and was most abundant on the PAVE flights on 27 and 29 January

Multi-level study of C3H2: The first interstellar hydrocarbon ring

Cyclic species in the interstellar medium have been searched for almost since the first detection of interstellar polyatomic molecules. Eleven different C3H2 rotational transitions were detected; 9 of which were studied in TMC-1, a nearby dark dust cloud, are shown. The 1 sub 10 yields 1 sub 01 and 2 sub 20 yields 2 sub 11 transitions were observed with the 43 m NRAO telescope, while the remaining transitions were detected with the 14 m antenna of the Five College Radio Observatory (FCRAO). The lines detected in TMC-1 have energies above the ground state ranging from 0.9 to 17.1 K and consist of both ortho and para species. Limited maps were made along the ridge for several of the transitions. The HC3N J = 2 yields 1 transition were mapped simultaneously with the C3H2 1 sub 10 yields 1 sub 01 line and therefore can compare the distribution of this ring with a carbon chain in TMC-1. C3H2 is distributed along a narrow ridge with a SE - NW extension which is slightly more extended than the HC2N J = 2 yields 1. Gaussian fits gives a FWHP extension of 8'5 for C3H2 while HC3N has a FWHP of 7'. The data show variations of the two velocity components along the ridge as a function of transition. Most of the transitions show a peak at the position of strongest HC3N emission while the 2 sub 21 yields 2 sub 10 transition shows a peak at the NH3 position

Operating experiences of retardant bombers during firefighting operations

Data are presented on operational practices and maneuver accelerations experienced by two Douglas DC-6B airplanes converted to retardant bombers and used in firefighting operations. The data cover two fire seasons in the mountainous regions of the northwestern United States

Limits on the Position Wander of Sgr A*

We present measurements with the VLBA of the variability in the centroid position of Sgr A* relative to a background quasar at 7-mm wavelength. We find an average centroid wander of 71 +/- 45 micro-arcsec for time scales between 50 and 100 min and 113 +/- 50 micro-arcsec for timescales between 100 and 200 min, with no secular trend. These are sufficient to begin constraining the viability of the hot-spot model for the radio variability of Sgr A*. It is possible to rule out hot spots with orbital radii above 15GM_SgrA*/c^2 that contribute more than 30% of the total 7-mm flux. However, closer or less luminous hot spots remain unconstrained. Since the fractional variability of Sgr A* during our observations was ~20% on time scales of hours, the hot-spot model for Sgr A*'s radio variability remains consistent with these limits. Improved monitoring of Sgr A*'s centroid position has the potential to place significant constraints upon the existence and morphology of inhomogeneities in a supermassive black hole accretion flow.Comment: 14 pages, 3 figures submitted to Ap

The Law and Economics of Contracts

This paper, which will appear as a chapter in the forthcoming Handbook of Law and Economics (A.M. Polinsky & S. Shavell, eds.), surveys major issues arising in the economic analysis of contract law. It begins with an introductory discussion of scope and methodology, and then addresses four topic areas that correspond to the major doctrinal divisions of the law of contracts. These areas include freedom of contract (i.e., the scope of private power to create binding obligations), formation of contracts (both the procedural mechanics of exchange, and rules that govern pre-contractual behavior), contract interpretation (what consequences follow when agreements are ambiguous or incomplete), and enforcement of contractual obligations. For each of these sections, we address the economic analysis of particular legal rules and institutions, and, where relevant, connections between legal arrangements and associated topics in microeconomic theory, including welfare economics and the theory of contracts

Closed-circuit television welding- electrode guidance system

Closed-circuit TV camera is mounted parallel to electrode and moves along with it. Camera is scanned along seam so seam is viewed parallel with scan lines on TV monitor. Two fiber optics illuminators are attached to guidance system; they illuminate seam for TV camera

Impact of multiscale dynamical processes and mixing on the chemical composition of the upper troposphere and lower stratosphere during the Intercontinental Chemical Transport Experiment–North America

We use high-frequency in situ observations made from the DC8 to examine fine-scale tracer structure and correlations observed in the upper troposphere and lower stratosphere during INTEX-NA. Two flights of the NASA DC-8 are compared and contrasted. Chemical data from the DC-8 flight on 18 July show evidence for interleaving and mixing of polluted and stratospheric air masses in the vicinity of the subtropical jet in the upper troposphere, while on 2 August the DC-8 flew through a polluted upper troposphere and a lowermost stratosphere that showed evidence of an intrusion of polluted air. We compare data from both flights with RAQMS 3-D global meteorological and chemical model fields to establish dynamical context and to diagnose processes regulating the degree of mixing on each day. We also use trajectory mapping of the model fields to show that filamentary structure due to upstream strain deformation contributes to tracer variability observed in the upper troposphere. An Eulerian measure of strain versus rotation in the large-scale flow is found useful in predicting filamentary structure in the vicinity of the jet. Higher-frequency (6–24 km) tracer variability is attributed to buoyancy wave oscillations in the vicinity of the jet, whose turbulent dissipation leads to efficient mixing across tracer gradients

The adsorption and decomposition of N_2O on Ru(001)

N/