204 research outputs found
Distribution of averages in a correlated Gaussian medium as a tool for the estimation of the cluster distribution on size
Calculation of the distribution of the average value of a Gaussian random
field in a finite domain is carried out for different cases. The results of the
calculation demonstrate a strong dependence of the width of the distribution on
the spatial correlations of the field. Comparison with the simulation results
for the distribution of the size of the cluster indicates that the distribution
of an average field could serve as a useful tool for the estimation of the
asymptotic behavior of the distribution of the size of the clusters for "deep"
clusters where value of the field on each site is much greater than the rms
disorder.Comment: 15 pages, 6 figures, RevTe
Electroluminescence and optical properties of poly(phenylenevinylene)/J-aggregate composites
Abstract A composite material of poly(phenylenevinylene) (PPV) doped by dye aggregates was prepared. A very efficient and temperature activated energy transfer (ET) from the PPV to the dye aggregates was attributed to F . orster ET accompanied by exciton diffusion. A clear complementary relation between the photoluminescence (PL) and electroluminscence (EL) images was observed for thin (15 nm) PPV-based OLEDs. So-called ''black spots'' in EL become bright ones when the photoluminescence of the same area was excited. This effect was attributed to the presence of an insulating layer between the polymer and aluminium.
Nanoparticle formation and dynamics in a complex (dusty) plasma: from the plasma ignition to the afterglow.
Complex (dusty) plasmas are a subject of growing interest. They areionized gases containing charged dust particles. In capacitively-coupled RF discharges, dust growth can occur naturally and two methods can be used to grow dust particles: chemically active plasmas or sputtering. The growth of dust particles in argon discharges by RF sputtering and the effect of dust particles on theplasma have been investigated from the plasma ignition to the afterglow. It was shown that plasma and discharge parameters are greatly affected by the dust particles. Furthermore, plasma instabilities can be triggered by the presence of the dust particles. These instabilities can be due to dust particle growth or they can be instabilities of a well established dust cloud filling the interelectrode space. When the discharge is switched off, the dust particles act like a sink for the charge carrier and consequently affect the plasma losses. It was shown that the dust particles do keep residual chargeswhich values are greatly affected by the diffusion of the charge carriers and especially the transition from ambipolar to free diffusion
Photostability of J -aggregates adsorbed on TiO 2 nanoparticles and AFM imaging of J -aggregates on a glass surface
Abstract. Spectral properties and photostability of the 5,5'-6,6'-tetrachloro-1,1'-dioctyl-3,3'-bis-(3-carboxypropyl)-benzimidacarbocyanine (Dye 1) J-aggregate was investigated in solution and upon adsorption on TiO 2 nano-particles. Dye 1 was found to photodegrade on the surface of TiO 2 . Additionally, the self-assembly of Dye 1 was studied on a glass surface by non-contact atomic force microscopy (NCAFM). The dye molecules form a well-defined fiber like structure that extends for tens of micrometers. The internal structure of the fibers was clearly resolved and showed a number of small tubes wrapped around each other to form a helical structure
Fabrication of fluorescent nanoparticles of dendronized perylenediimide by laser ablation in water
Highly fluorescent organic nanoparticles with size of about 300 nm were prepared by nanosecond laser ablation of micrometer-sized powder of dendronized perylenediimide dispersed in water. The nanoparticle colloidal solution provided a fluorescence quantum yield of 0.58. The absorption and emission spectral studies demonstrated that the bulky dendron groups at the side bays of perylenediimide chromophore efficiently suppress the interchromophoric interactions in the nanoparticles. Fluorescence measurement on several single nanoparticles underlines that the prepared nanoparticles are bright and photo-stable enough to be a useful probe for single particle fluorescence investigation.</p
Generation-Dependent Energy Dissipation in Rigid Dendrimers Studied by Femtosecond to Nanosecond Time-Resolved Fluorescence Spectroscopy
Intramolecular kinetic processes in a series of second- generation polyphenyl dendrimers with multiple peryleneimide chromophores attached to the para position of the outer phenyl ring were investigated by steady-state and femtosecond to nanosecond time-resolved fluorescence spectroscopy. The results obtained were compared to the ones of the corresponding first- generation dendrimer series. The energy-hopping rate constant, k(hopp), observed from anisotropy decay times was found to be 5 times smaller than that of the first-generation series and scales well with the difference in average distance between the chromophores. In addition to the processes observed in first- generation dendrimers in the ultrafast time domain by fluorescence up-conversion, a second. annihilation process is found in the second-generation multichromophoric dendrimer. The observation of two singlet-singlet annihilation processes in this compound can be explained by the presence of a mixture of constitutional isomers leading to a broader distribution of distances between neighboring chromophores compared to first- generation multichromophoric dendrimers
Generation-Dependent Energy Dissipation in Rigid Dendrimers Studied by Femtosecond to Nanosecond Time-Resolved Fluorescence Spectroscopy â€
Towards the Verification of Hybrid Co-simulation Algorithms
International audienceEngineering modern, hybrid systems is becoming increasingly difficult due to the heterogeneity between different subsystems. Modelling and simulation techniques have traditionally been used to tackle complexity, but with increasing heterogeneity of the subsystems, it becomes impossible to find appropriate modelling languages and tools to specify and analyse the system as a whole. Co-simulation is a technique to combine multiple models and their simulators in order to analyse the behaviour of the whole system over time. Past research, however, has shown that the na¨ıvena¨ıve combination of simulators can easily lead to incorrect simulation results, especially when co-simulating hybrid systems. This paper shows (i) how co-simulation of a family of hybrid systems can fail to reproduce the order of events that should have occurred (event ordering); (ii) how to prove that a co-simulation algorithm is correct (w.r.t. event ordering), and if it is incorrect, how to obtain a counterexample showing how the co-simulation fails; and (iii) how to correct an incorrect co-simulation algorithm. We apply the above method to two well known co-simulation algorithms used with the FMI Standard, and we show that one of them is incorrect for the family of hybrid systems under study, under the restrictions of the standard. The conclusion is that either the standard needs to be revised, or one of the algorithms should be avoided
Targeted LC–MS derivatization for aldehydes and carboxylic acids with a new derivatization agent 4-APEBA
Based on the template of a recently introduced derivatization reagent for aldehydes, 4-(2-(trimethylammonio)ethoxy)benzeneaminium dibromide (4-APC), a new derivatization agent was designed with additional features for the analysis and screening of biomarkers of lipid peroxidation. The new derivatization reagent, 4-(2-((4-bromophenethyl)dimethylammonio)ethoxy)benzenaminium dibromide (4-APEBA) contains a bromophenethyl group to incorporate an isotopic signature to the derivatives and to add additional fragmentation identifiers, collectively enhancing the abilities for detection and screening of unknown aldehydes. Derivatization can be achieved under mild conditions (pH 5.7, 10 °C). By changing the secondary reagent (1-ethyl-3-(3-dimethylaminopropyl) carbodiimide instead of sodium cyanoborohydride), 4-APEBA is also applicable to the selective derivatization of carboxylic acids. Synthesis of the new label, exploration of the derivatization conditions, characterization of the fragmentation of the aldehyde and carboxylic acid derivatives in MS/MS, and preliminary applications of the labeling strategy for the analysis of aldehydes in urine and plasma are described
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