Atmospheric chemistry of gas-phase polycyclic aromatic hydrocarbons: formation of atmospheric mutagens.

The atmospheric chemistry of the 2- to 4-ring polycyclic aromatic hydrocarbons (PAH), which exist mainly in the gas phase in the atmosphere, is discussed. The dominant loss process for the gas-phase PAH is by reaction with the hydroxyl radical, resulting in calculated lifetimes in the atmosphere of generally less than one day. The hydroxyl (OH) radical-initiated reactions and nitrate (NO3) radical-initiated reactions often lead to the formation of mutagenic nitro-PAH and other nitropolycyclic aromatic compounds, including nitrodibenzopyranones. These atmospheric reactions have a significant effect on ambient mutagenic activity, indicating that health risk assessments of combustion emissions should include atmospheric transformation products

Robustness of the nodal d-wave spectrum to strongly fluctuating competing order

We resolve an existing controversy between, on the one hand, convincing evidence for the existence of competing order in underdoped cuprates, and, on the other hand, spectroscopic data consistent with a seemingly homogeneous d-wave superconductor in the very same compounds. Specifically, we show how short-range fluctuations of the competing order essentially restore the nodal d-wave spectrum from the qualitatively distinct folded dispersion resulting from homogeneous coexisting phases. The signatures of the fluctuating competing order can be found mainly in a splitting of the antinodal quasi-particles and, depending of the strength of the competing order, also in small induced nodal gaps as found in recent experiments on underdoped La{2-x}SrxCuO4.Comment: 5 pages, 4 figure

Evaluation of registration, compression and classification algorithms. Volume 1: Results

The registration, compression, and classification algorithms were selected on the basis that such a group would include most of the different and commonly used approaches. The results of the investigation indicate clearcut, cost effective choices for registering, compressing, and classifying multispectral imagery

Evaluation of registration, compression, and classification algorithms. Volume 2: Documentation

There are no author-identified significant results in this report

A study and evaluation of image analysis techniques applied to remotely sensed data

An analysis of phenomena causing nonlinearities in the transformation from Landsat multispectral scanner coordinates to ground coordinates is presented. Experimental results comparing rms errors at ground control points indicated a slight improvement when a nonlinear (8-parameter) transformation was used instead of an affine (6-parameter) transformation. Using a preliminary ground truth map of a test site in Alabama covering the Mobile Bay area and six Landsat images of the same scene, several classification methods were assessed. A methodology was developed for automatic change detection using classification/cluster maps. A coding scheme was employed for generation of change depiction maps indicating specific types of changes. Inter- and intraseasonal data of the Mobile Bay test area were compared to illustrate the method. A beginning was made in the study of data compression by applying a Karhunen-Loeve transform technique to a small section of the test data set. The second part of the report provides a formal documentation of the several programs developed for the analysis and assessments presented

On the precision of chiral-dispersive calculations of ππ\pi\pi scattering

We calculate the combination $2a_0^{(0)}-5a_0^{(2)}$ (the Olsson sum rule) and the scattering lengths and effective ranges $a_1$, $a_2^{(I)}$ and $b_1$, $b_2^{(I)}$ dispersively (with the Froissart--Gribov representation) using, at low energy, the phase shifts for $\pi\pi$ scattering obtained by Colangelo, Gasser and Leutwyler (CGL) from the Roy equations and chiral perturbation theory, plus experiment and Regge behaviour at high energy, or directly, using the CGL parameters for $a$s and $b$s. We find mismatch, both among the CGL phases themselves and with the results obtained from the pion form factor. This reaches the level of several (2 to 5) standard deviations, and is essentially independent of the details of the intermediate energy region ($0.82\leq E\leq 1.42$ GeV) and, in some cases, of the high energy behaviour assumed. We discuss possible reasons for this mismatch, in particular in connection with an alternate set of phase shifts.Comment: Version to appear in Phys. Rev. D. Graphs and sum rule added. Plain TeX fil

An integrable multicomponent quad equation and its Lagrangian formulation

We present a hierarchy of discrete systems whose first members are the lattice modified Korteweg-de Vries equation, and the lattice modified Boussinesq equation. The N-th member in the hierarchy is an N-component system defined on an elementary plaquette in the 2-dimensional lattice. The system is multidimensionally consistent and a Lagrangian which respects this feature, i.e., which has the desirable closure property, is obtained.Comment: 10 page

A spectral method for elliptic equations: the Dirichlet problem

An elliptic partial differential equation Lu=f with a zero Dirichlet boundary condition is converted to an equivalent elliptic equation on the unit ball. A spectral Galerkin method is applied to the reformulated problem, using multivariate polynomials as the approximants. For a smooth boundary and smooth problem parameter functions, the method is proven to converge faster than any power of 1/n with n the degree of the approximate Galerkin solution. Examples in two and three variables are given as numerical illustrations. Empirically, the condition number of the associated linear system increases like O(N), with N the order of the linear system.Comment: This is latex with the standard article style, produced using Scientific Workplace in a portable format. The paper is 22 pages in length with 8 figure

On the Lagrangian structure of 3D consistent systems of asymmetric quad-equations

Recently, the first-named author gave a classification of 3D consistent 6-tuples of quad-equations with the tetrahedron property; several novel asymmetric 6-tuples have been found. Due to 3D consistency, these 6-tuples can be extended to discrete integrable systems on Z^m. We establish Lagrangian structures and flip-invariance of the action functional for the class of discrete integrable systems involving equations for which some of the biquadratics are non-degenerate and some are degenerate. This class covers, among others, some of the above mentioned novel systems.Comment: 21 pp, pdfLaTe

Magnetic properties and critical behavior of disordered Fe_{1-x}Ru_x alloys: a Monte Carlo approach

We study the critical behavior of a quenched random-exchange Ising model with competing interactions on a bcc lattice. This model was introduced in the study of the magnetic behavior of Fe_{1-x}Ru_x alloys for ruthenium concentrations x=0%, x=4%, x=6%, and x=8%. Our study is carried out within a Monte Carlo approach, with the aid of a re-weighting multiple histogram technique. By means of a finite-size scaling analysis of several thermodynamic quantities, taking into account up to the leading irrelevant scaling field term, we find estimates of the critical exponents \alpha, \beta, \gamma, and \nu, and of the critical temperatures of the model. Our results for x=0% are in excellent agreement with those for the three-dimensional pure Ising model in the literature. We also show that our critical exponent estimates for the disordered cases are consistent with those reported for the transition line between paramagnetic and ferromagnetic phases of both randomly dilute and $\pm J$ Ising models. We compare the behavior of the magnetization as a function of temperature with that obtained by Paduani and Branco (2008), qualitatively confirming the mean-field result. However, the comparison of the critical temperatures obtained in this work with experimental measurements suggest that the model (initially obtained in a mean-field approach) needs to be modified