Teaching materials in the 21st century

We live in an era of continuous change. In the branch of engineering, beyond the usual and pressing objectives of functionality, safety and integrity, computers are now used pervasively, new economic pressures and concern for the environment are looming, and the availability of energy resources and proper functioning of materials supply chains are ever more important. Students need an education that allows them to understand and deal with these changes, in a time when growth in the number of students, expectations and pressure on teaching resources is a challenge for professors, particularly for younger academics. Engineers create things out of materials. What do engineering students need to know to select and use materials that perform as expected, are safe, economically efficient and have the least environmental impact? This question leads to the introduction of the design approach. Knowledge, data and tools are necessary for students to make decisions that meet complex design requirements. This means that science is introduced in a way that facilitates understanding how to meet design requirements and select materials and processes. This paper also introduces briefly some of the new aspects of the 2012 CES EduPack. This tool developed by Granta Design, supports professors and helps students of both introductory and advanced courses in branches such as engineering, design and science in the study of materials. CES EduPack is used in more than 850 universities and institutes around the world and is continually evolving to offer a new version each January. Changes and new features are focused on two pathways, one active (eg development of Eco Selector and Eco-audit tool) and another in response to feedback from users. The latter has made the software more intuitive and easy to use.Peer Reviewe

A catalogue of [100], [110], and [111] symmetric tilt boundaries in face-centered cubic hard sphere crystals.

Engineering and Applied Science

Wear-mechanism modelling

Goals of the program are to calculate the surface temperatures in dry sliding, develop a soft wear tester for ceramics, survey the wear mechanisms in brittle solids, and couple the temperature calculations with models to give wear maps for brittle solids. (DLC

Effects of Impurity Content on the Sintering Characteristics of Plasma-Sprayed Zirconia

Yttria-stabilized zirconia powders, containing different levels of SiO2 and Al2O3, have been plasma sprayed onto metallic substrates. The coatings were detached from their substrates and a dilatometer was used to monitor the dimensional changes they exhibited during prolonged heat treatments. It was found that specimens containing higher levels of silica and alumina exhibited higher rates of linear contraction, in both in-plane and through-thickness directions. The in-plane stiffness and the through-thickness thermal conductivity were also measured after different heat treatments and these were found to increase at a greater rate for specimens with higher impurity (silica and alumina) levels. Changes in the pore architecture during heat treatments were studied using Mercury Intrusion Porosimetry (MIP). Fine scale porosity (<_50 nm) was found to be sharply reduced even by relatively short heat treatments. This is correlated with improvements in inter-splat bonding and partial healing of intra-splat microcracks, which are responsible for the observed changes in stiffness and conductivity, as well as the dimensional changes

Multivariable model to predict an ACTH stimulation test to diagnose adrenal insufficiency using previous test results

Context The adrenocorticotropin hormone stimulation test (AST) is used to diagnose adrenal insufficiency, and is often repeated in patients when monitoring recovery of the hypothalamo–pituitary–adrenal axis. Objective To develop and validate a prediction model that uses previous AST results with new baseline cortisol to predict the result of a new AST. Methods This was a retrospective, longitudinal cohort study in patients who had undergone at least 2 ASTs, using polynomial regression with backwards variable selection, at a Tertiary UK adult endocrinology center. Model was developed from 258 paired ASTs over 5 years in 175 adults (mean age 52.4 years, SD 16.4), then validated on data from 111 patients over 1 year (51.8, 17.5) from the same center, data collected after model development. Candidate prediction variables included previous test baseline adrenocorticotropin hormone (ACTH), previous test baseline and 30-minute cortisol, days between tests, and new baseline ACTH and cortisol used with calculated cortisol/ACTH ratios to assess 8 candidate predictors. The main outcome measure was a new test cortisol measured 30 minutes after Synacthen administration. Results Using 258 sequential ASTs from 175 patients for model development and 111 patient tests for model validation, previous baseline cortisol, previous 30-minute cortisol and new baseline cortisol were superior at predicting new 30-minute cortisol (R2 = 0.71 [0.49-0.93], area under the curve [AUC] = 0.97 [0.94-1.0]) than new baseline cortisol alone (R2 = 0.53 [0.22-0.84], AUC = 0.88 [0.81-0.95]). Conclusion Results of a previous AST can be objectively combined with new early-morning cortisol to predict the results of a new AST better than new early-morning cortisol alone. An online calculator is available at https://endocrinology.shinyapps.io/sheffield_sst_calculator/ for external validation

Constraints Imposed by the Wilshire Methodology on Creep Rupture Data and Procedures for Testing the Validity of Such Constraints: Illustration Using 1Cr-1Mo-0.25V Steel

A new parametric approach, termed the Wilshire equations, offers the realistic potential of being able to accurately life materials operating at in service conditions from accelerated test results lasting no more than 5000 hours. These Wilshire equations contain discontinuities that have in the literature been interpreted either in terms of changing deformation mechanisms or changes in where deformation occurs within a material (i.e., within boundaries or crystals). This paper demonstrates that the rather restrictive nature of these discontinuities within the Wilshire equations can lead to problems in identifying an appropriate model for long-term life prediction. An alternative framework is developed that removes these restrictions but still maintains the fundamental nature and characteristics of the Wilshire methodology. Further, when this alternative structure is applied to 1Cr-1Mo-0.25V steel, it produces more accurate and realistic looking long-term predictions of the time to failure

Surface preparation of powder metallurgical tool steels by means of wire electrical discharge machining

The surface of two types of powder metallurgical (PM) tool steels (i.e., with and without nitrogen) was prepared using wire electrical discharge machining (WEDM). From each grade of tool steel, seven surfaces corresponding to one to seven passes of WEDM were prepared. The WEDM process was carried out using a brass wire as electrode and deionized water as dielectric. After eachWEDM pass the surface of the tool steels was thoroughly examined. Surface residual stresses were measured by the X-ray diffraction (XRD) technique. The measured stresses were found to be of tensile nature. The surface roughness of the WEDM specimens was measured using interference microscopy. The surface roughness as well as the residual stress measurements indicated an insignificant improvement of these parameters after four passes of WEDM. In addition, the formed recast layer was characterized by means of scanning electron microscopy (SEM), XRD, and X-ray photoelectron spectroscopy (XPS). The characterization investigation clearly shows diffusion of copper and zinc from the wire electrode into the work material, even after the final WEDM step. Finally, the importance of eliminating excessive WEDM steps is thoroughly discussed

Influence of Grain Boundary Character on Creep Void Formation in Alloy 617

Alloy 617, a high temperature creep-resistant, nickel-based alloy, is being considered for the primary heat exchanger for the Next Generation Nuclear Plant (NGNP) which will operate at temperatures exceeding 760oC. Orientation imaging microscopy (OIM) is used to characterize the grain boundaries in the vicinity of creep voids that develop during high temperature creep tests (800-1000oC at creep stresses ranging from 20-85 MPa) terminated at creep strains ranging from 5-40%. Observations using optical microscopy indicate creep rate does not significantly influence the creep void fraction at a given creep strain. Preliminary analysis of the OIM data indicates voids tend to form on grain boundaries parallel, perpendicular or 45o to the tensile axis, while few voids are found at intermediate inclinations to the tensile axis. Random grain boundaries intersect most voids while CSL-related grain boundaries did not appear to be consistently associated with void development