Numerical Simulation on Shoreline Change in Western Region of Badung Regency, Bali, Indonesia

Shoreline change is considered the most dynamic processes in coastal region. Coastal erosion is a global problem where 70% beaches around the world are recessional. Almost all coastal area in Bali is potential to suffer from erosion. Badung Regency in Bali has many beaches that famous as tourism area where from about 64 km shoreline length, 11,5 km were recorded suffered by erosion in 1985 and 12,1 km erosion in 2007. This study aims to determine the value of shoreline changes that occur in western of Badung Regency from 2001 to 2010 based on the predicted wave data using monthly wind data from Ngurah Rai, Tuban, Badung, Bali meteorological station. Shoreline change simulation measured the forward (accretion) or backward (erosion) distance of the shoreline on the East-West direction. Bali has wind patterns that influenced by the Northwest monsoon from November-April and Southeast monsoon from May-October. In 2001-2010, dominant wind in this region was coming from east, southeast, and west. Geographically western coast of Badung influenced by incoming winds from the west, southwest, and south. Wind blow towards the coast in 2001-2010 are dominantly come from the west with wind speed range was about 1,7-4,7 m/s. Simulation indicated that generally shoreline tends to experience accretion in the north and erosion in the south. From 16000 m of study shoreline, along 7100 m of shoreline tend to suffer by erosion. Oppositely, along 8900 m of shoreline tend to have accretion

Numerical Simulation on Shoreline Change in Western Region of Badung Regency, Bali, Indonesia

Shoreline change is considered the most dynamic processes in coastal region. Coastal erosion is a global problem where 70% beaches around the world are recessional. Almost all coastal area in Bali is potential to suffer from erosion. Badung Regency in Bali has many beaches that famous as tourism area where from about 64 km shoreline length, 11,5 km were recorded suffered by erosion in 1985 and 12,1 km erosion in 2007. This study aims to determine the value of shoreline changes that occur in western of Badung Regency from 2001 to 2010 based on the predicted wave data using monthly wind data from Ngurah Rai, Tuban, Badung, Bali meteorological station. Shoreline change simulation measured the forward (accretion) or backward (erosion) distance of the shoreline on the East-West direction. Bali has wind patterns that influenced by the Northwest monsoon from November-April and Southeast monsoon from May-October. In 2001-2010, dominant wind in this region was coming from east, southeast, and west. Geographically western coast of Badung influenced by incoming winds from the west, southwest, and south. Wind blow towards the coast in 2001-2010 are dominantly come from the west with wind speed range was about 1,7-4,7 m/s. Simulation indicated that generally shoreline tends to experience accretion in the north and erosion in the south. From 16000 m of study shoreline, along 7100 m of shoreline tend to suffer by erosion. Oppositely, along 8900 m of shoreline tend to have accretion

Divergent synthesis of isonitriles and nitriles by palladium- catalyzed benzylic substitution with TMSCN

Ligand-controlled palladium-catalyzed divergent synthesis of isonitriles and nitriles from benzylic carbonates and TMSCN has been developed. The BINAP- or DPEphos-ligated palladium catalyst selectively provides the corresponding benzylic isonitriles, whereas their regioisomers, benzylic nitriles, are formed exclusively under phosphine ligand-free conditions. Mechanistic studies reveal that isonitrile is the primary product under both conditions, but it is isomerized into nitrile in the absence of ancillary phosphine ligands.Hirano K., Miura M., Asai K.. Divergent synthesis of isonitriles and nitriles by palladium- catalyzed benzylic substitution with TMSCN. Journal of Organic Chemistry. 85(19), 12703-12714, (2020), 2 October 2020; © 2020 American Chemical Society. https://doi.org/10.1021/acs.joc.0c01861

Palladium-Catalyzed Cross-Coupling Reaction of Diarylmethanol Derivatives with Diborylmethane

A palladium-catalyzed cross-coupling reaction of diarylmethanol derivatives with diborylmethane has been developed. The reaction proceeds chemoselectively to deliver the corresponding homobenzylic boronates in good yields.Asai K., Miura M., Hirano K.. Palladium-Catalyzed Cross-Coupling Reaction of Diarylmethanol Derivatives with Diborylmethane. Journal of Organic Chemistry. 87(11), 7436-7445, (2022), 3 June 2022; © 2022 American Chemical Society. https://doi.org/10.1021/acs.joc.2c00715

Palladium-Catalyzed Benzylic Silylation of Diarylmethyl Carbonates with Silylboranes under Base-Free Conditions

A palladium-catalyzed benzylic silylation of diarylmethyl carbonates with silylboranes has been developed. The reaction proceeds smoothly even under external base-free conditions, and the corresponding benzylic silanes are formed in good to high yields. The obtained benzyl silane derivatives can work as the benzylic nucleophiles by the action of a suitable fluoride source and react with some carbon electrophiles to deliver the corresponding benzylic C−C cross-coupled products. Additionally, while still preliminary, the allylic silylation of the isoelectronic allylic carbonates is also achieved.Asai K., Hirano K., Miura M.. Palladium-Catalyzed Benzylic Silylation of Diarylmethyl Carbonates with Silylboranes under Base-Free Conditions. European Journal of Organic Chemistry 2022, e202101535 (2022); https://doi.org/10.1002/ejoc.202101535

Discovery reach for wino and higgsino dark matter with a disappearing track signature at a 100 TeV pppp collider

Within the theory of supersymmetry, the lightest neutralino is a dark matter candidate and is often assumed to be the lightest supersymmetric particle (LSP) as well. If the neutral wino or higgsino is dark matter, the upper limit of the LSP mass is determined by the observed relic density of dark matter. If the LSP is a nearly-pure neutral state of the wino or higgsino, the lightest chargino state is expected to have a significant lifetime due to a tiny mass difference between the LSP and the chargino. This article presents discovery potential of the 100 TeV future circular hadron collider (FCC) for the wino and higgsino dark matter using a disappearing-track signature. The search strategy to extend the discovery reach to the thermal limits of wino/higgsino dark matter is discussed with detailed studies on the background rate and the reference design of the FCC-hadron detector under possible running scenarios of the FCC-hadron machine. A proposal of modifying the detector layout and several ideas to improve the sensitivity further are also discussed.Comment: 10 pages, 7 figures, 4 table