The millennial atmospheric lifetime of anthropogenic CO2

The notion is pervasive in the climate science community and in the public at large that the climate impacts of fossil fuel CO2 release will only persist for a few centuries. This conclusion has no basis in theory or models of the atmosphere/ocean carbon cycle, which we review here. The largest fraction of the CO2 recovery will take place on time scales of centuries, as CO2 invades the ocean, but a significant fraction of the fossil fuel CO2, ranging in published models in the literature from 20-60%, remains airborne for a thousand years or longer. Ultimate recovery takes place on time scales of hundreds of thousands of years, a geologic longevity typically associated in public perceptions with nuclear waste. The glacial/interglacial climate cycles demonstrate that ice sheets and sea level respond dramatically to millennial-timescale changes in climate forcing. There are also potential positive feedbacks in the carbon cycle, including methane hydrates in the ocean, and peat frozen in permafrost, that are most sensitive to the long tail of the fossil fuel CO2 in the atmosphere. © 2008 The Author(s)

A nucleosome-free dG-dC-rich sequence element promotes constitutive transcription of the essential yeast RIO1 gene

RIO1 is an essential gene that encodes a protein serine kinase and is transcribed constitutively at a very low level. Transcriptional activation of RIO1 dispenses with a canonical TATA box as well as with classical transactivators or specific DNAbinding factors. Instead, a dGdCrich sequence element, that is located 40 to 48 bp upstream the single site of mRNA initiation, is essential and presumably constitutes the basal promoter. In addition, we demonstrate here that this promoter element comprises a nucleosomefree gap which is centered at the dGdC tract and flanked by two positioned nucleosomes. This element is both, necessary and sufficient, for basal transcription initiation at the RIO1 promoter and, thus, constitutes a novel type of core promoter element

X-Ray Diffraction and Reflectance Spectroscopy of Murchison Powders (CM2) After Thermal Analysis Under Reducing Conditions to Final Temperatures Between 300 and 1300c

The asteroids Ryugu and Bennu have spectral characteristics in common with CI/CM type carbonaceous chondrites and are target bodies for JAXAs Hayabusa2 and NASAs OSIRIS-Rex missions, respectively. Analog studies, based primarily on the Murchison CM2 chondrite, provide a pathway to separate spectral properties resulting space weathering from those inherent to parent-body, mineralogy, chemistry, and processes. Ryugu shares spectral properties with thermally metamorphosed and partly dehydrated CI/CM chondrites. We have undertaken a multidisciplinary study of the thermal decomposition of Murchison powder samples as an analog to metamorphic process that may have occurred on Ryugu. Bulk analyses include thermal And evolved gas analysis, X-ray diffraction (XRD), and VIS-NIR and Mssbauer spectroscopy; micro- to nanoscale analyses included scanning and transmission electron microscopy and electron probe micro analysisWe report here XRD and VIS-NIR analyses of pre- and post-heated Murchison powders, and in a companion paper report results from multiple electron beam techniques

Shoot Heterogeneity Effects on Shiraz/Richter 99 Grapevines. II. Physiological Activity

In this study, the physiology of normally developed and underdeveloped shoots is compared in an attempt toquantify the effect of shoot heterogeneity in a Shiraz/Richter 99 vineyard, located in the Stellenbosch area of theWestern Cape, South Africa. Comparisons are made between normally developed and underdeveloped shoots fromshaded and well-exposed canopies. In the first five weeks after véraison, photosynthetic and transpiration rates,stomatal conductance and water-use efficiency (WUE) decreased as berry ripening progressed, while the internalCO2 levels of the leaves increased. Since differences in activity between individual leaves from normally developedand underdeveloped shoots only became apparent in the third week after véraison, it seemed as if the leaf area pershoot played a more important role than the photosynthetic output per unit leaf area in determining photosynthetatesupply to the rest of the vine up to this stage. From the third week after véraison, higher levels of photosynthetateswere produced by normally developed shoots than by underdeveloped shoots, due to the larger effective leaf areaper shoot as well as the higher photosynthetic activity per unit leaf area. This points to premature senescence of theleaves on underdeveloped shoots. The quantity and quality of the yield from normally developed shoots are expectedto benefit from the higher physiological output of the leaves. The enhancing effect on leaf functioning induced bycanopy exposure became apparent from the third week after véraison

Shoot Heterogeneity Effects on Shiraz/Richter 99 Grapevines. III. Leaf Chlorophyll Content

In this study, the leaf chlorophyll content of normally developed and underdeveloped shoots was compared in anattempt to quantify the effect of shoot heterogeneity in a Shiraz/Richter 99 vineyard, located in the Stellenbosch areaof the Western Cape, South Africa. Comparisons are also made between normally developed and underdevelopedshoots from shaded and well-exposed canopies. No positive correlation was found between the photosyntheticactivity and the chlorophyll concentration of the leaves at five weeks after véraison. Equal amounts of chlorophyllper cm2 and a non-significant difference in the assimilation rate were calculated for the leaves of normally developedand underdeveloped shoots. No significant differences were found between the shaded and well-exposed canopies. Ittherefore appears that it is the effective surface area per leaf or per shoot rather than the chlorophyll concentrationor activity that may be responsible for any apparent difference in the photosynthetic output of the leaves fromnormally developed and underdeveloped shoots in shaded or well-exposed canopies

Magnetospheric and solar wind dependences of coupled fast-mode resonances outside the plasmasphere

We investigate the magnetospheric and solar wind factors that control the occurrence probabilities, locations, and frequencies of standing Alfvén waves excited via coupled fast-mode resonances (cFMRs) in the outer magnetosphere's dawn and dusk sectors. The variation of these cFMR properties with the observed magnetospheric plasma density profiles and inputs to the semiempirically modeled magnetic field from the numerical cFMR calculations of Archer et al. (2015) are studied. The probability of cFMR occurrence increases with distance between the magnetopause and the Alfvén speed's local maximum. The latter's location depends on magnetospheric activity: during high activity it is situated slightly outside the plasmapause, whereas at low activity it is found at much larger radial distances. The frequencies of cFMR are proportional to the Alfvén speed near the magnetopause, which is affected by both density and magnetic field variations. The location of the excited resonance, however, depends on the relative steepness of the Alfvén speed radial profile. The steeper this is, the closer the resonance is to the outer boundary and vice versa. The variation of the density profiles with solar wind conditions and activity is also shown

Glacial CO 2 cycle as a succession of key physical and biogeochemical processes

During glacial-interglacial cycles, atmospheric CO2 concentration varied by about 100 ppmv in amplitude. While testing mechanisms that have led to the low glacial CO2 level could be done in equilibrium model experiments, an ultimate goal is to explain CO2 changes in transient simulations through the complete glacial-interglacial cycle. The computationally efficient Earth System model of intermediate complexity CLIMBER-2 is used to simulate global biogeochemistry over the last glacial cycle (126 kyr). The physical core of the model (atmosphere, ocean, land and ice sheets) is driven by orbital changes and reconstructed radiative forcing from greenhouses gases, ice, and aeolian dust. The carbon cycle model is able to reproduce the main features of the CO2 changes: a 50 ppmv CO2 drop during glacial inception, a minimum concentration at the last glacial maximum 80 ppmv lower than the Holocene value, and an abrupt 60 ppmv CO2 rise during the deglaciation. The model deep ocean δ13C also resembles reconstructions from deep-sea cores. The main drivers of atmospheric CO2 evolve in time: changes in sea surface temperatures and in the volume of bottom water of southern origin control atmospheric CO2 during the glacial inception and deglaciation; changes in carbonate chemistry and marine biology are dominant during the first and second parts of the glacial cycle, respectively. These feedback mechanisms could also significantly impact the ultimate climate response to the anthropogenic perturbation

Nudged Elastic Band calculation of the binding potential for liquids at interfaces

The wetting behavior of a liquid on solid substrates is governed by the nature of the effective interaction between the liquid-gas and the solid-liquid interfaces, which is described by the binding or wetting potential $g(h)$ which is an excess free energy per unit area that depends on the liquid film height $h$. Given a microscopic theory for the liquid, to determine $g(h)$ one must calculate the free energy for liquid films of any given value of $h$; i.e. one needs to create and analyze out-of-equilibrium states, since at equilibrium there is a unique value of $h$, specified by the temperature and chemical potential of the surrounding gas. Here we introduce a Nudged Elastic Band (NEB) approach to calculate $g(h)$ and illustrate the method by applying it in conjunction with a microscopic lattice density functional theory for the liquid. We show too that the NEB results are identical to those obtained with an established method based on using a fictitious additional potential to stabilize the non-equilibrium states. The advantages of the NEB approach are discussed.Comment: 5 pages, 2 figure

Frequency variability of standing Alfven waves excited by fast mode resonances in the outer magnetosphere

NASA. Grant Number: NAS5-0209