2,501 research outputs found
Screening effects in flow through rough channels
A surprising similarity is found between the distribution of hydrodynamic
stress on the wall of an irregular channel and the distribution of flux from a
purely Laplacian field on the same geometry. This finding is a direct outcome
from numerical simulations of the Navier-Stokes equations for flow at low
Reynolds numbers in two-dimensional channels with rough walls presenting either
deterministic or random self-similar geometries. For high Reynolds numbers,
when inertial effects become relevant, the distribution of wall stresses on
deterministic and random fractal rough channels becomes substantially dependent
on the microscopic details of the walls geometry. In addition, we find that,
while the permeability of the random channel follows the usual decrease with
Reynolds, our results indicate an unexpected permeability increase for the
deterministic case, i.e., ``the rougher the better''. We show that this complex
behavior is closely related with the presence and relative intensity of
recirculation zones in the reentrant regions of the rough channel.Comment: 4 pages, 5 figure
Random Sequential Adsorption: From Continuum to Lattice and Pre-Patterned Substrates
The random sequential adsorption (RSA) model has served as a paradigm for
diverse phenomena in physical chemistry, as well as in other areas such as
biology, ecology, and sociology. In the present work, we survey aspects of the
RSA model with emphasis on the approach to and properties of jammed states
obtained for large times in continuum deposition versus that on lattice
substrates, and on pre-patterned surfaces. The latter model has been of recent
interest in the context of efforts to use pre-patterning as a tool to improve
selfassembly in micro- and nanoscale surface structure engineering
Organic and mineral matter changes due to oil generation, saturation and expulsion processes based on artificial maturation experiments
Hydrous pyrolysis experiments were conducted on immature organic-rich rock with type-I kerogen to evaluate petroleum generation, saturation and expulsion processes. The experiments were carried out under isothermal conditions at ten different temperatures (280° through 360°C) for nine different time spans between 18 and 144h. Rock samples recovered from the experiments were analyzed for total organic carbon (TOC-weight%), Rock-Eval pyrolysis, vitrinite reflectance (Ro%), spectral fluorescence and visual characterization of organic matter under the microscopy. TOC, S2 and HI tend to decrease with increasing temperature and duration of the experiments as expected. The Ro% values reach up to 1.14% in the most severe experiment (i.e. 360°C/96h). The Ro% is believed to be suppressed due to hydrogen incorporation from bitumen. The bitumen production was observed with the increase of transformation index (TI) and two types of bitumen were differentiated by fluorescence color. The bitumen with yellow fluorescence was mainly composed of saturate and aromatic hydrocarbons that were probably generated earlier than the bitumen with brown fluorescence which is rich in NSO compounds. The greatest bitumen saturation occurs at TI around of 41% to 45%, when the S1 reaches its highest values. The decrease of bitumen saturation and consequent oil expulsion is marked by a reduction in S1 values and fluorescence color. This phenomenon occurs simultaneously with the development of fractures and voids in the mineral matrix which reduces the oil retention capability and facilitates the expulsion process. These observations enhanced the understanding of oil generation and saturation processes, as well as primary migration, expulsion and type of generated bitumen
Organic and mineral matter changes due to oil generation, saturation and expulsion processes based on artificial maturation experiments
Hydrous pyrolysis experiments were conducted on immature organic-rich rock with type-I kerogen to evaluate petroleum generation, saturation and expulsion processes. The experiments were carried out under isothermal conditions at ten different temperatures (280° through 360°C) for nine different time spans between 18 and 144h. Rock samples recovered from the experiments were analyzed for total organic carbon (TOC-weight%), Rock-Eval pyrolysis, vitrinite reflectance (Ro%), spectral fluorescence and visual characterization of organic matter under the microscopy. TOC, S2 and HI tend to decrease with increasing temperature and duration of the experiments as expected. The Ro% values reach up to 1.14% in the most severe experiment (i.e. 360°C/96h). The Ro% is believed to be suppressed due to hydrogen incorporation from bitumen. The bitumen production was observed with the increase of transformation index (TI) and two types of bitumen were differentiated by fluorescence color. The bitumen with yellow fluorescence was mainly composed of saturate and aromatic hydrocarbons that were probably generated earlier than the bitumen with brown fluorescence which is rich in NSO compounds. The greatest bitumen saturation occurs at TI around of 41% to 45%, when the S1 reaches its highest values. The decrease of bitumen saturation and consequent oil expulsion is marked by a reduction in S1 values and fluorescence color. This phenomenon occurs simultaneously with the development of fractures and voids in the mineral matrix which reduces the oil retention capability and facilitates the expulsion process. These observations enhanced the understanding of oil generation and saturation processes, as well as primary migration, expulsion and type of generated bitumen
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