Cover Feature: Extended Limits of Reversible Electrochemical Lithiation of Crystalline V 2

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The Downward breaststroke kick makes fast speed and increased lactate acid

In this study, we assess the effectiveness of utilizing a downward breaststroke kick with regard to the overall time, max speed and velocity per stroke when using a downward breaststroke kick technique. We analyzed breaststroke kick of knee angles from 8 elite world class swimmers. The downward breaststroke kick used in breaststroke competitions resulted in improvements average of 100 yard or 100 meter breaststroke from 1:05.10 s to 1:01.97 s. Increases in performance max speed and velocity per stroke among 9 elite world class swimmers are highly correlated to duration of the kick aerodynamic buoyant farce in breaststroke. The downward breaststroke kick also resulted in an increase in lactate acid

A Critical Assessment of the Therapeutic Potential of Resveratrol Supplements for Treating Mitochondrial Disorders

In human cells, mitochondria provide the largest part of cellular energy in the form of adenosine triphosphate generated by the process of oxidative phosphorylation (OXPHOS). Impaired OXPHOS activity leads to a heterogeneous group of inherited diseases for which therapeutic options today remain very limited. Potential innovative strategies aim to ameliorate mitochondrial function by increasing the total mitochondrial load of tissues and/or to scavenge the excess of reactive oxygen species generated by OXPHOS malfunctioning. In this respect, resveratrol, a compound that conveniently combines mitogenetic with antioxidant activities and, as a bonus, possesses anti-apoptotic properties, has come forward as a promising nutraceutical. We review the scientific evidence gathered so far through experiments in both in vitro and in vivo systems, evaluating the therapeutic effect that resveratrol is expected to generate in mitochondrial patients. The obtained results are encouraging, but clearly show that achieving normalization of OXPHOS function with this strategy alone could prove to be an unattainable goal

The Role of Semilabile Oxygen Atoms for Intercalation Chemistry of the Metal-Ion Battery Polyanion Cathodes

Using the orthorhombic layered Na₂FePO₄F cathode material as a model system we identify the bonding of the alkali metal cations to the semilabile oxygen atoms as an important factor affecting electrochemical activity of alkali cations in polyanion structures. The semilabile oxygens, bonded to the P and alkali cations, but not included into the FeO₄F₂ octahedra, experience severe undercoordination upon alkali cation deintercalation, causing an energy penalty for removing the alkali cations located in the proximity of such semilabile oxygens. Desodiation of Na₂FePO₄F proceeds through a two-phase mechanism in the Na-ion cell with a formation of an intermediate monoclinic Na_1.55FePO₄F phase with coupled Na/vacancy and Fe²⁺/Fe³⁺ charge ordering at 50% state of charge. In contrast, desodiation of Na₂FePO₄F in the Li-ion cell demonstrates a sloping charge profile suggesting a solid solution mechanism without formation of a charge-ordered intermediate phase. A combination of a comprehensive crystallographic study and extensive DFT-based calculations demonstrates that the difference in electrochemical behavior of the alkali cation positions is largely related to the different number of the nearest neighbor semilabile oxygen atoms, influencing their desodiation potential and accessibility for the Na/Li chemical exchange, triggering coupled alkali cation–vacancy ordering and Fe²⁺/Fe³⁺ charge ordering, as well as switching between the “solid solution” and “two-phase” charging mechanistic regimes

The Role of Semilabile Oxygen Atoms for Intercalation Chemistry of the Metal-Ion Battery Polyanion Cathodes

Using the orthorhombic layered Na₂FePO₄F cathode material as a model system we identify the bonding of the alkali metal cations to the semilabile oxygen atoms as an important factor affecting electrochemical activity of alkali cations in polyanion structures. The semilabile oxygens, bonded to the P and alkali cations, but not included into the FeO₄F₂ octahedra, experience severe undercoordination upon alkali cation deintercalation, causing an energy penalty for removing the alkali cations located in the proximity of such semilabile oxygens. Desodiation of Na₂FePO₄F proceeds through a two-phase mechanism in the Na-ion cell with a formation of an intermediate monoclinic Na_1.55FePO₄F phase with coupled Na/vacancy and Fe²⁺/Fe³⁺ charge ordering at 50% state of charge. In contrast, desodiation of Na₂FePO₄F in the Li-ion cell demonstrates a sloping charge profile suggesting a solid solution mechanism without formation of a charge-ordered intermediate phase. A combination of a comprehensive crystallographic study and extensive DFT-based calculations demonstrates that the difference in electrochemical behavior of the alkali cation positions is largely related to the different number of the nearest neighbor semilabile oxygen atoms, influencing their desodiation potential and accessibility for the Na/Li chemical exchange, triggering coupled alkali cation–vacancy ordering and Fe²⁺/Fe³⁺ charge ordering, as well as switching between the “solid solution” and “two-phase” charging mechanistic regimes

The Role of Semilabile Oxygen Atoms for Intercalation Chemistry of the Metal-Ion Battery Polyanion Cathodes

Using the orthorhombic layered Na₂FePO₄F cathode material as a model system we identify the bonding of the alkali metal cations to the semilabile oxygen atoms as an important factor affecting electrochemical activity of alkali cations in polyanion structures. The semilabile oxygens, bonded to the P and alkali cations, but not included into the FeO₄F₂ octahedra, experience severe undercoordination upon alkali cation deintercalation, causing an energy penalty for removing the alkali cations located in the proximity of such semilabile oxygens. Desodiation of Na₂FePO₄F proceeds through a two-phase mechanism in the Na-ion cell with a formation of an intermediate monoclinic Na_1.55FePO₄F phase with coupled Na/vacancy and Fe²⁺/Fe³⁺ charge ordering at 50% state of charge. In contrast, desodiation of Na₂FePO₄F in the Li-ion cell demonstrates a sloping charge profile suggesting a solid solution mechanism without formation of a charge-ordered intermediate phase. A combination of a comprehensive crystallographic study and extensive DFT-based calculations demonstrates that the difference in electrochemical behavior of the alkali cation positions is largely related to the different number of the nearest neighbor semilabile oxygen atoms, influencing their desodiation potential and accessibility for the Na/Li chemical exchange, triggering coupled alkali cation–vacancy ordering and Fe²⁺/Fe³⁺ charge ordering, as well as switching between the “solid solution” and “two-phase” charging mechanistic regimes

MASTER Real-Time Multi-Message Observations of High Energy Phenomena

This review considers synchronous and follow-up MASTER Global Robotic Net optical observations of high energy astrophysical phenomena such as fast radio bursts (FRB), gamma-ray bursts (including prompt optical emission polarization discovery), gravitational-wave events, detected by LIGO/VIRGO (including GW170817 and independent Kilonova discovery), high energy neutrino sources (including the detection of IC-170922A progenitor) and others. We report on the first large optical monitoring campaign of the closest at that moment radio burster FRB 180916.J0158+65 simultaneously with a radio burst. We obtained synchronous limits on the optical flux of the FRB 180916.J0158+65 and FRB 200428 (soft gamma repeater SGR 1935+2154) (The CHIME/FRB Collaboration, Nature 2020, 587) at 155093 MASTER images with the total exposure time equal to 2,705,058 s, i.e., 31.3 days. It follows from these synchronous limitations that the ratio of the energies released in the optical and radio ranges does not exceed 4 × 105. Our optical monitoring covered a total of 6 weeks. On 28 April 2020, MASTER automatically following up on a Swift alert began to observe the galactic soft gamma repeater SGR 1935+2154 experienced another flare. On the same day, radio telescopes detected a short radio burst FRB 200428 and MASTER-Tavrida telescope determined the best prompt optical limit of FRB/SGR 1935+2154. Our optical limit shows that X-ray and radio emissions are not explained by a single power-law spectrum. In the course of our observations, using special methods, we found a faint extended afterglow in the FRB 180916.J0158+65 direction associated with the extended emission of the host galaxy

MASTER Real-Time Multi-Message Observations of High Energy Phenomena

This review considers synchronous and follow-up MASTER Global Robotic Net optical observations of high energy astrophysical phenomena such as fast radio bursts (FRB), gamma-ray bursts (including prompt optical emission polarization discovery), gravitational-wave events, detected by LIGO/VIRGO (including GW170817 and independent Kilonova discovery), high energy neutrino sources (including the detection of IC-170922A progenitor) and others. We report on the first large optical monitoring campaign of the closest at that moment radio burster FRB 180916.J0158+65 simultaneously with a radio burst. We obtained synchronous limits on the optical flux of the FRB 180916.J0158+65 and FRB 200428 (soft gamma repeater SGR 1935+2154) (The CHIME/FRB Collaboration, Nature 2020, 587) at 155093 MASTER images with the total exposure time equal to 2,705,058 s, i.e., 31.3 days. It follows from these synchronous limitations that the ratio of the energies released in the optical and radio ranges does not exceed 4 × 105. Our optical monitoring covered a total of 6 weeks. On 28 April 2020, MASTER automatically following up on a Swift alert began to observe the galactic soft gamma repeater SGR 1935+2154 experienced another flare. On the same day, radio telescopes detected a short radio burst FRB 200428 and MASTER-Tavrida telescope determined the best prompt optical limit of FRB/SGR 1935+2154. Our optical limit shows that X-ray and radio emissions are not explained by a single power-law spectrum. In the course of our observations, using special methods, we found a faint extended afterglow in the FRB 180916.J0158+65 direction associated with the extended emission of the host galaxy