Performance of common-mode chokes

A low-cost method for experimental investigation of common-mode chokes for reducing high-frequency motor ground-currents of inverter-based drive systems of several hundred kW is presented. It provides a powerful tool during the design stage of such chokes to verify their predicted performance. The method draws from the mainly capacitive behavior of machines at very high frequencies. Results of experimental tests for drives with peak ground-current amplitudes of more than 60 Amperes, carried out on a 4 kW test-bed, are presented. They confirm the feasibility of such tests as well as the capability of small, inexpensive, single-turn chokes to effectively reduce the ground-current

Shape-dependent CO2 hydrogenation to methanol over Cu2O nanocubes supported on ZnO

The hydrogenation of CO2 to methanol over Cu/ZnO-based catalysts is highly sensitive to the surface composition and catalyst structure. Thus, its optimization requires a deep understanding of the influence of the pre-catalyst structure on its evolution under realistic reaction conditions, including the formation and stabilization of the most active sites. Here, the role of the pre-catalyst shape (cubic vs spherical) in the activity and selectivity of ZnO-supported Cu nanoparticles was investigated during methanol synthesis. A combination of ex situ, in situ, and operando microscopy, spectroscopy, and diffraction methods revealed drastic changes in the morphology and composition of the shaped pre-catalysts under reaction conditions. In particular, the rounding of the cubes and partial loss of the (100) facets were observed, although such motifs remained in smaller domains. Nonetheless, the initial pre-catalyst structure was found to strongly affect its subsequent transformation in the course of the CO2 hydrogenation reaction and activity/selectivity trends. In particular, the cubic Cu particles displayed an increased activity for methanol production, although at the cost of a slightly reduced selectivity when compared to similarly sized spherical particles. These findings were rationalized with the help of density functional theory calculations.Peer ReviewedPostprint (published version