SYNTHESIS AND CHARACTERISATION OF ZINC OXIDE NANOPARTICLES USINGPHENOLIC RESINS

Phenolic gum or phenol formaldehyde (PF) tar containing distinctive level of zinc oxide (ZnO) nanoparticles was arranged and used to treat rubberwood. Three sorts of treatment arrangements were readied, in particular (1) low atomic weight phenol formaldehyde gum (LMwPF), (2) 1,5 wt % nano ZnO broke up in water (ZnO/H2O), and (3) blend of both LMwPF and 1,5 wt % nano ZnO (LMwPF/ZnO). The rubberwood tests were lowered into the treatment answers for 60, 90, and 120 min, before vacuum impregnation. The untreated rubberwood tests filled in as the controlled examples. The warm solidness conduct and opposition against white-decay parasites (Pycnoporus sanguineus) of the treated rubberwood tests were assessed. The outcomes uncover that the treated rubberwood had somewhat better warm steadiness contrasted with the untreated examples. As far as rot opposition, the rubberwood treated with LMwPF and LMwPF/ZnO have high obstruction against white-decay growths. Then again, the rubberwood treated with ZnO/H2O didn't accomplish comparable viability as the other two medicines, aside from the examples that were lowered in ZnO/H2O for 120 min. The outcomes demonstrate that 1,5 wt % nano ZnO could be adequate in giving better solidness than rubberwood given that more drawn out submersion time is embraced.&nbsp

POTENTIAL GREEN SOLVENTS FOR A BROAD VARIETY OF SOLUTES USING N-HETERO CYCLIC PALLADIUM COMPLEX

 Unpredictable natural solvents (VOS) making expanding air contamination are normal response media for some substance measures. VOS can't be effectively sepa-appraised from the ideal response items and hard to reuse. Considering mindful ness of the weakening climate, investigates are coordinated on creating elective ecological agreeable dissolvable frameworks to supplant customary unstable organics. Inside this unique circumstance, the interest of ionic fluids (ILs) as "green" solvents lives in their incredibly low fume pressing factor and high warm steadiness, which offers preferences, for example, simplicity of regulation, item recuperation, and reusing capacity. Also, ILs show significant variety in their solidness to dampness and their miscibility with atomic fluids. Properties, for example, thickness, dissolving point, water and cosolvent miscibility, consistency, extremity, corrosive/base character, and planning capacity can be customized by the suitable choice of the cation or potentially anion com-ponent. ILs have been executed as dissolvable frameworks in compound responses, sepa-proportions, extractions, electroanalytical applications and synthetic detecting, among numerous others. Likewise, they have high ionic character that improves the response rates generally in numerous responses. These highlights permit ILs to be utilized as expected elective solvents to VOS in a wide assortment of modern synthetic cycles. Besides, the utilization of ILs as mechanical solvents can bring about affordable, social, and natural effect because of their impact on the human wellbeing and climat

Indolicidin – Antibacterial activity against bacterial pathogens isolated from ocular infections

Indolicidin is a novel/ promising antimicrobial peptide (a 13 amino acid cationic antimicrobial residue present in the form of cytoplasmic granules of bovine neutrophils) and observed with a broad spectrum of antimicrobial activity against bacteria, fungi, protozoa & even viruses. In the present study, Escherichia coli was transformed with pET 21a+ plasmid carrying indolicidin gene and was expressed. The crude extracts of indolicidin samples induced with varying IPTG concentrations (5mM and 20 mM/ ml of the medium) in Min A medium were checked for antibacterial activities against clinically important ocular bacterial pathogens such as E. coli, Klebsiella sp,, Pseudomonas sp., Acenitobacter sp., Staphylococcus aureus, coagulase negative Staphylococcus aureus, Streptococcus viridans, S. pneumoniae and S. pyogens and its activity was evaluated.&nbsp

Evaluation of doctors’ performance as facilitators in basic medical science lecture classes in a new Malaysian medical school

Background: Didactic lecture is the oldest and most commonly used method of teaching. In addition, it is considered one of the most efficient ways to disseminate theories, ideas, and facts. Many critics feel that lectures are an obsolete method to use when students need to perform hands-on activities, which is an everyday need in the study of medicine. This study evaluates students’ perceptions regarding lecture quality in a new medical school. Methods: This was a cross-sectional study conducted of the medical students of Universiti Sultan Zainal Abidin. The study population was 468 preclinical medical students from years 1 and 2 of academic year 2012–2013. Data were collected using a validated instrument. There were six different sections of questions using a 5-point Likert scale. The data were then compiled and analyzed, using SPSS version 20. Results: The response rate was 73%. Among 341 respondents, 30% were male and 70% were female. Eighty-five percent of respondents agree or strongly agree that the lectures had met the criteria with regard to organization of lecture materials. Similarly, 97% of students agree or strongly agree that lecturers maintained adequate voices and gestures. Conclusion: Medical students are quite satisfied with the lecture classes and the lectures. However, further research is required to identify student-centered teaching and learning methods to promote active learning

A novel hybrid intelligence approach for 2D packing through Internet crowdsourcing

Packing problems on its current state are being utilized for wide area of industrial applications. The aim of present research is to create and implement an intelligent system that tackles the problem of 2D packing of objects inside a 2D container, such that objects do not overlap and the container area is to be maximized. The packing problem becomes easier, when regular/rectangular objects and container are used. In most of the practical situations, the usage of irregular objects comes to existence. To solve the packing problem of irregular objects inside a rectangular container, a hybrid intelligence approach is introduced in our proposed work. The combination of machine intelligence and human intelligence is referred as the hybrid intelligence or semi-automated approach in the proposed methodology. The incorporation of human intelligence in the outcome of machine intelligence is possible to obtain using the internet crowdsourcing as we wish to handle the packing problem through internet crowdsourcing involving rural people. The proposed methodology is tested on different standard data sets and it is observed that it has clear advantage over both manual as well as fully automated heuristic based methods in terms of time and space efficiency

Nonlinear Modes of Liquid Drops as Solitary Waves

The nolinear hydrodynamic equations of the surface of a liquid drop are shown to be directly connected to Korteweg de Vries (KdV, MKdV) systems, giving traveling solutions that are cnoidal waves. They generate multiscale patterns ranging from small harmonic oscillations (linearized model), to nonlinear oscillations, up through solitary waves. These non-axis-symmetric localized shapes are also described by a KdV Hamiltonian system. Recently such ``rotons'' were observed experimentally when the shape oscillations of a droplet became nonlinear. The results apply to drop-like systems from cluster formation to stellar models, including hyperdeformed nuclei and fission.Comment: 11 pages RevTex, 1 figure p

The last integrable case of kozlov-Treshchev Birkhoff integrable potentials

We establish the integrability of the last open case in the Kozlov-Treshchev classification of Birkhoff integrable Hamiltonian systems. The technique used is a modification of the so called quadratic Lax pair for $D_n$ Toda lattice combined with a method used by M. Ranada in proving the integrability of the Sklyanin case.Comment: 13 page

Breathing Current Domains in Globally Coupled Electrochemical Systems: A Comparison with a Semiconductor Model

Spatio-temporal bifurcations and complex dynamics in globally coupled intrinsically bistable electrochemical systems with an S-shaped current-voltage characteristic under galvanostatic control are studied theoretically on a one-dimensional domain. The results are compared with the dynamics and the bifurcation scenarios occurring in a closely related model which describes pattern formation in semiconductors. Under galvanostatic control both systems are unstable with respect to the formation of stationary large amplitude current domains. The current domains as well as the homogeneous steady state exhibit oscillatory instabilities for slow dynamics of the potential drop across the double layer, or across the semiconductor device, respectively. The interplay of the different instabilities leads to complex spatio-temporal behavior. We find breathing current domains and chaotic spatio-temporal dynamics in the electrochemical system. Comparing these findings with the results obtained earlier for the semiconductor system, we outline bifurcation scenarios leading to complex dynamics in globally coupled bistable systems with subcritical spatial bifurcations.Comment: 13 pages, 11 figures, 70 references, RevTex4 accepted by PRE http://pre.aps.or

Mechanical and tribological behaviour of three-dimensional printed almond shell particles reinforced polylactic acid bio-composites

Recently, composite filament development for three-dimensional printing has emerged and is used for numerous applications. The present research work develops neat polylactic acid and Almond Shell Particles reinforced polylactic acid bio-composites for three-dimensional printing and investigates the effects of printing orientation, including 0°, 45° and 90° orientation, on the tribological and mechanical behaviours of three-dimensional printed materials. The novel almond shell particles reinforced polylactic acid filaments are extruded by the filament extrusion method with the presence of 10% almond shell particles in the polylactic acid matrix, and the samples are three-dimensional printed by the fused filament fabrication technique. Mechanical characteristics such as tensile, flexural, compressive strength, and shore hardness are evaluated with respect to various three-dimensional printing orientations. The surface quality of the three-dimensional printed polylactic acid composite samples is analysed with respect to length and diameter deviation. Length accuracy of the 90° oriented polylactic acid and almond shell particles reinforced polylactic acid bio-composite samples exploits a better accuracy of 99.12% and 98.81%, respectively. It is shown that adding almond shell particles to the polylactic acid matrix decreases the flexural and tensile strength. Among the printing orientations, 0° flat samples result in the maximum tensile strength of 36 and 28 MPa for the neat polylactic acid and almond shell particles reinforced polylactic acid composites, respectively. The lowest contact angle of 54° is observed on the almond shell particles reinforced polylactic acid bio-composites three-dimensional printed with a 90° orientation. The highest contact angle value of 94° is observed on the neat polylactic acid three-dimensional printed with a 0° printing orientation. A tribological study is carried out under dry conditions on the pin-on-disc tribometer by varying the sliding speed (1, 2, and 3 m/s) and load (10, 20, and 30 N). The result shows that the lowest coefficient of friction of 0.22 is achieved for the almond shell particles reinforced polylactic acid bio-composite samples with a 0° printing orientation under a sliding load of 10 N. These kinds of newly developed compostable materials can be used for developing disposable orthotic foot appliances