Benzil bis­(ketazine)

The title compound (systematic name: 1,1′,2,2′-tetra­phenyl-2,2′-azinodiethanone), C28H20N2O2, was obtained by the reaction of benzil monohydrazone with chromium(III) nitrate. The dibenzyl­idene hydrazine unit is nearly planar (r.m.s. deviation = 0.073 Å) and the two benzoyl units are oriented almost perpendicular to it [dihedral angle = 87.81 (2), 87.81 (2)°]. The mol­ecules are linked into chains along the c axis by C—H⋯O hydrogen bonds and the chains are cross-linked via C—H⋯π inter­actions involving the benzoyl phenyl rings

N,N′-Bis(4-pyridylmethyl­ene)octane-1,8-diamine

The complete molecule of the title compound, C20H26N4, is generated by a crystallographic centre of inversion and the central eight-carbon chain adopts a fully extended conformation. In the crystal, the molecules pack in layers parallel to (010)

catena-Poly[[(triphenyl­phosphane)copper(I)]-di-μ-iodido-[(triphenyl­phosphane)copper(I)]-μ-{1,2-bis­[1-(pyridin-4-yl)ethyl­idene]hydrazine}]

In the title coordination polymer, [Cu2I2(C14H14N4)(C18H15P)2]n, the CuI atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra­hedral arrangement. A crystallographic inversion centre generates a Cu2I2 diamond with a Cu–Cu separation of 3.0120 (5) Å. The complete N,N′-(1-pyridin-4-yl-ethethyl­idene)-hydrazine mol­ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure

Changes in Extreme Ocean Wave Heights under 1.5°C, 2°C, and 3°C Global Warming

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Influence of climate variability on seasonal extreme wave height from satellite data

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hemispheric asymmetry in future seasonal wave power changes.

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Natural Climate Variability Impact on Global Extreme Wave Heights Using Satellite Data and ERA-5 Reanalysis

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Historical global ocean wave data simulated with CMIP6 anthropogenic and natural forcings

Abstract This dataset presents historical ocean wave climate during 1960–2020, simulated using the numerical model WAVEWATCH III (WW3) forced by Coupled Model Intercomparison Project phase 6 (CMIP6) simulations corresponding to natural-only (NAT), greenhouse gas-only (GHG), aerosol-only (AER) forcings, combined forcing (natural and anthropogenic; ALL), and pre-industrial control conditions. Surface wind at 3-hourly temporal resolution, and sea-ice area fraction at monthly frequency, from a CMIP6 model - MRI-ESM2.0 are used to force WW3 over the global ocean. Model calibration and validation of the significant wave height are carried out using inter-calibrated multi-mission altimeter data produced by the European Space Agency Climate Change Initiative, with additional corroboration using ERA-5 reanalysis. The simulated dataset is assessed for its skill to represent mean state, extremes, trends, seasonal cycle, time consistency, and spatial distribution over time. Numerically simulated wave parameters for different individual external forcing scenario is not available yet. This study produces a novel database particularly useful for detection and attribution analysis to quantify the relative contributions of natural and anthropogenic forcings to historical changes

Novel 3-dimensional sixfold interpenetrating diamondoid networks of copper(I) coordination polymers of polypyridyl ligands - Syntheses,characterization and crystal structures

Two new coordination polymers [Cu(L-1)(2)](n)(ClO4)(n)center dot 2nH(2)O (1), [Cu(L-2)(2)](n)(ClO4)(n)center dot 2nH(2)O (2) of polydentate imine/pyridyl ligands, L-1 and L-2 with Cu(I) ion have been synthesized and characterized by single crystal X-ray diffraction studies, elemental analyses, IR' UV-vis and NMR spectroscopy. They represent 3-dimensional, sixfold interpenetrating diamondoid network structures having large pores of dimension, 35 x 21 angstrom(2) in 1 and 38 x 19 angstrom(2) in 2, respectively

Quantifying Anthropogenic Influences on Global Wave Height Trend During 1961–2020 With Focus on Polar Ocean

International audienceThis study investigates the contribution of external forcings on global and regional ocean wave height change during 1961–2020. Historical significant wave height (Hs) produced for different CMIP6 external forcings and preindustrial control conditions following the Detection and Attribution Model Intercomparison Project (DAMIP) are employed. The internal variability ranges are compared with different external forcing scenario. Statistically significant linear trends in Hs computed over regional ocean basins are found to be mostly associated with anthropogenic forcings: greenhouse gas‐only (GHG) and aerosol‐only (AER) forcing. For Hs, GHG signals are robustly detected and dominant for most of the global ocean, except over North pacific and South Atlantic, where AER signals are dominant. These results are supported by multi‐model analysis for wind speed. The remarkable increase in Hs over the Arctic (22.3%) and Southern (8.2%) Ocean can be attributed to GHG induced sea‐ice depletion and larger effective fetch along with wind speed increase