High-temperature creep of single-crystal nickel-based superalloy : microstructural changes and effects of thermal cycling

Creep tests were performed on MC2 single crystal superalloy at 950°C/200 MPa and 1150°C/80 MPa under isothermal and thermal cycling conditions with a tensile axis along the [0 0 1] direction. It was found that the thermal cycles strongly affect the creep behavior at 1150°C but not at 950°C. This was related to the repetitive precipitation and dissolution of small γ′ rafts at the higher temperature, as revealed by quantitative characterization of the γ/γ′ microstructure. The dislocation microstructure exhibits similar trends in all the tested conditions, with a very high activity of a[1 0 0]-type dislocations climbing through the rafts. Such climbing dislocations constitute a recovery process for the deformation active system. It appears that the density of a[1 0 0] dislocations, and not their climb velocity or diffusion rate, is the key parameter for the control of creep rate. The thermal cycles, which imply the creation and subsequent dissolution of rafts, provided new dislocations, which explains the acceleration of creep observed under such conditions

Hydrogen embrittlement susceptibility of a high strength steel X80

The present paper deals with hydrogen embrittlement (HE) susceptibility of a high strength steel grade (X80). The respective implication of different hydrogen populations, i.e. adsorbed, dissolved in interstitial sites, trapped on dislocations and/or microstructural elements on the associated embrittlement mechanisms has been addressed through mechanical testing in high pressure of hydrogen gas at room temperature. Tensile tests at various strain rates and hydrogen pressures have been carried out. Moreover, changes of gas (hydrogen or nitrogen) during loading have been imposed in order to get critical experiments able to discriminate among the potential hydrogen embrittlement mechanisms already proposed in the literature. The results of these tests have shown that hydrogen induces several kind of damages including decohesion along ferrite/pearlite interfaces and microcracks initiations on the specimens external surface. It is shown that decohesion is not critical under the loading paths used in the present study. On the contrary, it appears that the external microcracks initiation, followed by a quasi-cleavage fracture, is responsible for the premature failure of the material in high pressure of hydrogen gas. These experimental results have been further discussed by modeling hydrogen diffusion in order to identify hydrogen populations (adsorbed, diffusible or trapped) involved in HE. It was then demonstrated that adsorbed and near surface diffusible hydrogen are mainly responsible for embrittlement

Influence of oxide films on primary water stress corrosion cracking initiation of alloy 600

In the present study alloy 600 was tested in simulated pressurised water reactor (PWR) primary water, at 360 °C, under an hydrogen partial pressure of 30 kPa. These testing conditions correspond to the maximum sensitivity of alloy 600 to crack initiation. The resulting oxidised structures (corrosion scale and underlying metal) were characterised. A chromium rich oxide layer was revealed, the underlying metal being chromium depleted. In addition, analysis of the chemical composition of the metal close to the oxide scale had allowed to detect oxygen under the oxide scale and particularly in a triple grain boundary. Implication of such a finding on the crack initiation of alloy 600 is discussed. Significant diminution of the crack initiation time was observed for sample oxidised before stress corrosion tests. In view of these results, a mechanism for stress corrosion crack initiation of alloy 600 in PWR primary water was proposed

Assessment of the susceptibility of roads to flooding based on geographical information – test in a flash flood prone area (the Gard region, France)

International audienceIn flash flood prone areas, roads are often the first assets affected by inundations which make rescue operations difficult and represent a major threat to lives: almost half of the victims are car passengers trapped by floods. In the past years, the Gard region (France) road management services have realized an extensive inventory of the known road sub- mersions that occurred during the last 40 years. This inven- tory provided an unique opportunity to analyse the causes of road flooding in an area frequently affected by severe flash floods. It will be used to develop a road submersion suscep- tibility rating method, representing the first element of a road warning system.This paper presents the results of the analysis of this data set. A companion paper will show how the proposed road susceptibility rating method can be combined with dis- tributed rainfall-runoff simulations to provide accurate road submersion risk maps.The very low correlation between the various possible ex- planatory factors and the susceptibility to flooding measured by the number of past observed submersions implied the use of particular statistical analysis methods based on the general principals of the discriminant analysis.The analysis led to the definition of four susceptibility classes for river crossing road sections. Validation tests con- firmed that this classification is robust, at least in the con- sidered area. One major outcome of the analysis is that the susceptibility to flooding is rather linked to the location of the road sections than to the size of the river crossing structure (bridge or culvert)

An oxygen isotope record of lacustrine opal from a European Maar indicates climatic stability during the Last Interglacial

The penultimate temperate period, 127–110 ka before present (BP), bracketed by abrupt shifts of the global climate system initiating and terminating it, is considered as an analogue of the Holocene because of a similar low global ice‐volume. Ice core records as well as continental and marine records exhibit conflicting evidence concerning the climate variability within this period, the Last Interglacial. We present, for the first time, a high‐resolution record of oxygen isotopes in diatom opal of the Last Interglacial obtained from the Ribains Maar in France (44°50′09″N 3°49′16″E). Our results indicate that the Last Interglacial in southwestern Europe was generally a period of climatic stability. The record shows that the temperate period was initiated by an abrupt warm event followed midway by a minor climatic transition to a colder climate. An abrupt isotopic depletion that occurs simultaneously with abrupt changes in pollen and diatom assemblages marks the end of the temperate period, and is correlative with the Melisey I stadial. Variations in the isotopic composition of lake‐water related to the isotopic composition of precipitation and evaporation dominate the biogenic opal oxygen isotope record

The Influence of Prices on Within-Year Persistence by Traditional College-Age Students In Four-Year Colleges

This paper uses the 1987 National Postsecondary Student Aid Study to examine the influence of prices on within-year persistence by traditional college-age students enrolled in four-year colleges. The findings include: 1) within-year persistence was influenced by the amount of tuition charged; 2) tuition charges were negatively associated with within-year persistence in both public and private colleges; and 3) grant aid was positively associated with persistence in private colleges and negatively associated with persistence in public colleges. The authors conclude that the negative association between grants and persistence by students in public colleges is an artifact, attributable to an insufficient amount of grants available to students in public colleges

A late Pleistocene long pollen record from Lake Urmia, NW Iran

A palynological study based on two 100-m long cores from Lake Urmia in northwestern Iran provides a vegetation record spanning 200 ka, the longest pollen record for the continental interior of the Near East. During both penultimate and last glaciations, a steppe of Artemisia and Poaceae dominated the upland vegetation with a high proportion of Chenopodiaceae in both upland and lowland saline ecosystems. While Juniperus and deciduous Quercus trees were extremely rare and restricted to some refugia, Hippophaë rhamnoides constituted an important phanerophyte, particularly during the upper last glacial sediments. A pronounced expansion in Ephedra shrub-steppe occurred at the end of the penultimate late-glacial period but was followed by extreme aridity that favoured an Artemisia steppe. Very high lake levels, registered by both pollen and sedimentary markers, occurred during the middle of the last glaciation and upper part of the penultimate glaciation. The late-glacial to early Holocene transition is represented by a succession of Hippophaë, Ephedra, Betula, Pistacia and finally Juniperus and Quercus. The last interglacial period (Eemian), slightly warmer and moister than the Holocene, was followed by two interstadial phases similar in pattern to those recorded in the marine isotope record and southern European pollen sequences

Modelling Kinetics of Plant Canopy Architecture - Concepts and Applications

Most crop models simulate the crop canopy as an homogeneous medium. This approach enables modelling of mass and energy transfer through relatively simple equations, and is useful for understanding crop production. However, schematisation of an homogeneous medium cannot address the heterogeneous nature of canopies and interactions between plants or plant organs, and errors in calculation of light interception may occur. Moreover, conventional crop models do not describe plant organs before they are visible externally e.g young leaves of grasses. The conditions during early growth of individual organs are important determinants of final organ size, causing difficulties in incorporating effects of environmental stresses in such models. Limited accuracy in describing temporal source-sink relationships also contributes to difficulty in modelling dry matter distribution and paramaterisation of harvest indices. Functional-architectural modelling overcomes these limitations by (i) representing crops as populations of individual plants specified in three dimensions and (ii) by modelling whole plant growth and development from the behaviour of individual organs, based on sound models of organs such as leaves and internodes. Since individual plants consist of numerous organs, generic models of organ growth applicable across species are desirable. Consequently, we are studying the development of individual organs, and parameterising it in terms of environmental variables and plant characteristics. Models incorporating plant architecture are currently applied in education, using dynamic visual representation for teaching growth and development. In research, the 3D representation of plants addresses issues presented above and new applications including modelling of pesticide distribution, fungal spore dispersal through splashing and plant to plant heterogeneity