3,576 research outputs found

    Resonance energy transfer: The unified theory revisited

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    Resonanceenergy transfer (RET) is the principal mechanism for the intermolecular or intramolecular redistribution of electronic energy following molecular excitation. In terms of fundamental quantum interactions, the process is properly described in terms of a virtual photon transit between the pre-excited donor and a lower energy (usually ground-state) acceptor. The detailed quantum amplitude for RET is calculated by molecular quantum electrodynamical techniques with the observable, the transfer rate, derived via application of the Fermi golden rule. In the treatment reported here, recently devised state-sequence techniques and a novel calculational protocol is applied to RET and shown to circumvent problems associated with the usual method. The second-rank tensor describing virtual photon behavior evolves from a Green’s function solution to the Helmholtz equation, and special functions are employed to realize the coupling tensor. The method is used to derive a new result for energy transfer systems sensitive to both magnetic- and electric-dipole transitions. The ensuing result is compared to that of pure electric-dipole–electric-dipole coupling and is analyzed with regard to acceptable transfer separations. Systems are proposed where the electric-dipole–magnetic-dipole term is the leading contribution to the overall rate

    An Evaluation of Web Browsers

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    Many computational biologists would agree that, had it not been for multi-processors, the construction of multi- processors might never have occurred. In this position paper, we argue the exploration of interrupts. We present a novel heuristic for the visualization of Scheme, which we call YAWN

    The effects of an eight over Cricket bowling spell upon pace bowling biomechanics and performance within different delivery lengths

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    Pace bowlers must often perform extended bowling spells with maximal ball release speed (BRS) while targeting different delivery lengths when playing a multi-day match. This study investigated the effect of an eight over spell upon pace bowling biomechanics and performance at different delivery lengths. Nine male bowlers (age = 18.8 ± 1.7 years) completed an eight over spell, while targeting different lengths (short: 7–10 m, good: 4–7 m, full: 0–4 m from the batter’s stumps, respectively) in a randomized order. Trunk, knee and shoulder kinematics and ground reaction forces at front foot contact (FFC), as well as run-up velocity and BRS were measured. Paired sample t-tests (p ≤ 0.01), Hedges’ g effect sizes, and statistical parametrical mapping were used to assess differences between mean variables from the first and last three overs. No significant differences (p = 0.05–0.98) were found in any discrete or continuous variables, with the magnitude of difference being trivial-to-medium (g = 0.00–0.73) across all variables. Results suggest pace bowlers sustain BRS through a single eight over spell while tolerating the repeatedly high whole-body biomechanical loads as suggested by maintaining the kinematics or technique at the assessed joints during FFC. Practically, the findings are advantageous for bowling performance and support current bowling load monitoring practices

    Geology of the Fire Clay Coal in Part of the Eastern Kentucky Coal Field

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    Coal beds mined in Kentucky often are not laterally continuous in thickness, quality, or roof condition. Regional and local variation is common. Because thickness, quality, and roof conditions are the result of geologic processes that were active when the coal was deposited as a peat swamp, a better understanding of the relationships between geology and major coal resources can aid in identifying geologic trends, which can be extrapolated beyond areas of present mining. The focus of this study is on the Fire Clay (Hazard No. 4) coal, one of the leading producers in the Eastern Kentucky Coal Field with 20 million short tons of annual production. More than 3,800 thickness measurements, highwall and outcrop descriptions, borehole and geophysical-log descriptions, and proximate analyses from 97 localities were used in conjunction with previous palynologic and petrographic studies to investigate the geology of the Fire Clay coal in a 15-quadrangle area of the Eastern Kentucky Coal Field. The Fire Clay coal is commonly separated into two distinct layers or benches by a flint-clay and shale parting called the “jackrock parting” by miners. Maps of coal benches above and below the parting show that the lower bench is limited in extent and variable in thickness. In contrast, the coal above the jackrock parting occurs across most of the study area and is characterized by rectangular patterns of coal thickness. Multiple coal benches resulted from the accumulation of multiple peat deposits, each with different characteristics. The lower bench of the coal was deposited when a peat accumulated above an irregular topographic surface. Because the peat was being deposited at or below the water table, it was often flooded by sediment from lateral sources, resulting in moderate to locally high ash yields. This peat was drowned and then covered by volcanic ash, which formed the flint clay in the jackrock parting. The upper coal bench accumulated above the ash deposit, after irregularities in the topography had been filled. The relatively flat surface allowed the swamps to spread outward and dome upward above the water table in some areas. Doming of the peat resulted in areas of coal with generally low ash yields and sulfur contents. Sharp, angular changes in the upper coal bench are inferred to represent subtle fault influence on upper peat accumulation. The upper peat was buried by a series of river channels, which were bounded by levees, flood plains, and elongate bays. Several of the rivers eroded through the Fire Clay peats, forming cutouts in the coal. These cutouts often follow orientations similar to the angular trends of coal thinning, suggesting a relationship that can be extended beyond the present limits of mining. Also, additional peat swamps accumulated above the levees and flood plains bounding the channels. Along the thinning margins of these deposits, the peats came near or merged with the top of the Fire Clay coal, resulting in local areas of increased coal thickness. Rider coal benches exhibit high to moderate sulfur contents and ash yields, so that although they may increase coal thickness, total coal quality generally decreases where riders combine with the Fire Clay coal

    Available Resources of the Fire Clay Coal in Part of the Eastern Kentucky Coal Field

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    Available resources for the Fire Clay coal were calculated for a 15-quadrangle area in the Eastern Kentucky Coal Field. Original coal resources were estimated to be 1.8 billion tons (BT). Coal mined or lost in mining was estimated at 449 million tons (MT), leaving 1.3 BT of remaining Fire Clay resources in the study area. Of the remaining resources, 400 MT is restricted from mining, primarily because the coal is less than 28 in. thick, normally considered too thin to mine underground using present technology. The total coal available for mining in the study area is 911 MT, or 52 percent of the original resource. Of the 911 MT, 14.9 percent is thicker than 42 in., and only 6.1 percent is accessible by surface-mining methods. The largest block of available coal is in the Leatherwood quadrangle, is less than 42 in. thick, and mostly occurs below drainage

    Interpolated sequences and critical LL-values of modular forms

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    Recently, Zagier expressed an interpolated version of the Ap\'ery numbers for ζ(3)\zeta(3) in terms of a critical LL-value of a modular form of weight 4. We extend this evaluation in two directions. We first prove that interpolations of Zagier's six sporadic sequences are essentially critical LL-values of modular forms of weight 3. We then establish an infinite family of evaluations between interpolations of leading coefficients of Brown's cellular integrals and critical LL-values of modular forms of odd weight.Comment: 23 pages, to appear in Proceedings for the KMPB conference: Elliptic Integrals, Elliptic Functions and Modular Forms in Quantum Field Theor
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