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Recovery of valuable chlorosilane intermediates by a novel waste conversion process. Technical report for phase IIIA (final) and phase IIIB (progress)
From July 1994 through May 1998, direct process residue (DPR) hydrogenolysis has been studied in the laboratory, at a small Pilot Plant, and finally at a larger Pilot Plant within Dow Corning`s Carrollton, Kentucky plant. The system reacts filtered DPR with monomer at high temperature and pressure. The process demonstrates DPR conversion up to 86%. The reaction product contains high concentrations of valuable monomers such as dimethyldichlorosilane and methyldichlorosilane. A larger DPR hydrogenolysis reactor based on these results is being designed for operation in Europe at Dow Corning`s Barry, Wales site
Stability of dark solitons in a Bose-Einstein condensate trapped in an optical lattice
We investigate the stability of dark solitons (DSs) in an effectively
one-dimensional Bose-Einstein condensate in the presence of the magnetic
parabolic trap and an optical lattice (OL). The analysis is based on both the
full Gross-Pitaevskii equation and its tight-binding approximation counterpart
(discrete nonlinear Schr{\"o}dinger equation). We find that DSs are subject to
weak instabilities with an onset of instability mainly governed by the period
and amplitude of the OL. The instability, if present, sets in at large times
and it is characterized by quasi-periodic oscillations of the DS about the
minimum of the parabolic trap.Comment: Typo fixed in Eq. (1): cos^2 -> sin^
Controlling collapse in Bose-Einstein condensates by temporal modulation of the scattering length
We consider, by means of the variational approximation (VA) and direct
numerical simulations of the Gross-Pitaevskii (GP) equation, the dynamics of 2D
and 3D condensates with a scattering length containing constant and
harmonically varying parts, which can be achieved with an ac magnetic field
tuned to the Feshbach resonance. For a rapid time modulation, we develop an
approach based on the direct averaging of the GP equation,without using the VA.
In the 2D case, both VA and direct simulations, as well as the averaging
method, reveal the existence of stable self-confined condensates without an
external trap, in agreement with qualitatively similar results recently
reported for spatial solitons in nonlinear optics. In the 3D case, the VA again
predicts the existence of a stable self-confined condensate without a trap. In
this case, direct simulations demonstrate that the stability is limited in
time, eventually switching into collapse, even though the constant part of the
scattering length is positive (but not too large). Thus a spatially uniform ac
magnetic field, resonantly tuned to control the scattering length, may play the
role of an effective trap confining the condensate, and sometimes causing its
collapse.Comment: 7 figure
Long Range Magnetic Order and the Darwin Lagrangian
We simulate a finite system of confined electrons with inclusion of the
Darwin magnetic interaction in two- and three-dimensions. The lowest energy
states are located using the steepest descent quenching adapted for velocity
dependent potentials. Below a critical density the ground state is a static
Wigner lattice. For supercritical density the ground state has a non-zero
kinetic energy. The critical density decreases with for exponential
confinement but not for harmonic confinement. The lowest energy state also
depends on the confinement and dimension: an antiferromagnetic cluster forms
for harmonic confinement in two dimensions.Comment: 5 figure
On Renyi entropies characterizing the shape and the extension of the phase space representation of quantum wave functions in disordered systems
We discuss some properties of the generalized entropies, called Renyi
entropies and their application to the case of continuous distributions. In
particular it is shown that these measures of complexity can be divergent,
however, their differences are free from these divergences thus enabling them
to be good candidates for the description of the extension and the shape of
continuous distributions. We apply this formalism to the projection of wave
functions onto the coherent state basis, i.e. to the Husimi representation. We
also show how the localization properties of the Husimi distribution on average
can be reconstructed from its marginal distributions that are calculated in
position and momentum space in the case when the phase space has no structure,
i.e. no classical limit can be defined. Numerical simulations on a one
dimensional disordered system corroborate our expectations.Comment: 8 pages with 2 embedded eps figures, RevTex4, AmsMath included,
submitted to PR
Stability and collapse of localized solutions of the controlled three-dimensional Gross-Pitaevskii equation
On the basis of recent investigations, a newly developed analytical procedure
is used for constructing a wide class of localized solutions of the controlled
three-dimensional (3D) Gross-Pitaevskii equation (GPE) that governs the
dynamics of Bose-Einstein condensates (BECs). The controlled 3D GPE is
decomposed into a two-dimensional (2D) linear Schr\"{o}dinger equation and a
one-dimensional (1D) nonlinear Schr\"{o}dinger equation, constrained by a
variational condition for the controlling potential. Then, the above class of
localized solutions are constructed as the product of the solutions of the
transverse and longitudinal equations. On the basis of these exact 3D
analytical solutions, a stability analysis is carried out, focusing our
attention on the physical conditions for having collapsing or non-collapsing
solutions.Comment: 21 pages, 14 figure
Bloodstream infections in community hospitals in the 21st century: A multicenter cohort study
Background: While the majority of healthcare in the US is provided in community hospitals, the epidemiology and treatment of bloodstream infections in this setting is unknown. Methods and Findings: We undertook this multicenter, retrospective cohort study to 1) describe the epidemiology of bloodstream infections (BSI) in a network of community hospitals and 2) determine risk factors for inappropriate therapy for bloodstream infections in community hospitals. 1,470 patients were identified as having a BSI in 9 community hospitals in the southeastern US from 2003 through 2006. The majority of BSIs were community-onset, healthcare associated (n = 823, 56%); 432 (29%) patients had community-acquired BSI, and 215 (15%) had hospital-onset, healthcare-associated BSI. BSIs due to multidrug-resistant pathogens occurred in 340 patients (23%). Overall, the three most common pathogens were S. aureus (n = 428, 28%), E. coli (n = 359, 24%), coagulase-negative Staphylococci (n = 148, 10%), though type of infecting orgaism varied by location of acquisition (e.g., community-acquired). Inappropriate empiric antimicrobial therapy was given to 542 (38%) patients. Proportions of inappropriate therapy varied by hospital (median = 33%, range 21-71%). Multivariate logistic regression identified the following factors independently associated with failure to receive appropriate empiric antimicrobial therapy: hospital where the patient received care (p,0.001), assistance with $3 ADLs (p = 0.005), Charlson score (p = 0.05), community-onset, healthcare-associated infection (p = 0.01), and hospital-onset, healthcareassociated infection (p = 0.02). Important interaction was observed between Charlson score and location of acquisition. Conclusions: Our large, multicenter study provides the most complete picture of BSIs in community hospitals in the US to date. The epidemiology of BSIs in community hospitals has changed: community-onset, healthcare-associated BSI is most common, S. aureus is the most common cause, and 1 of 3 patients with a SI receives inappropriate empiric antimicrobial therapy. Our data suggest that appropriateness of empiric antimicrobial therapy is an important and needed performance metric for physicians and hospital stewardship programs in community hospitals
The future of sovereignty in multilevel governance Europe: a constructivist reading
Multilevel governance presents a depiction of contemporary structures in EU Europe as consisting of overlapping authorities and competing competencies. By focusing on emerging non-anarchical structures in the international system, hence moving beyond the conventional hierarchy/anarchy dichotomy to distinguish domestic and international arenas, this seems a radical transformation of the familiar Westphalian system and to undermine state sovereignty. Paradoxically, however, the principle of sovereignty proves to be resilient despite its alleged empirical decline. This article argues that social constructivism can explain the paradox, by considering sovereign statehood as a process-dependent institutional fact, and by showing that multilevel governance can feed into this process
Weak Localization Effect in Superconductors by Radiation Damage
Large reductions of the superconducting transition temperature and
the accompanying loss of the thermal electrical resistivity (electron-phonon
interaction) due to radiation damage have been observed for several A15
compounds, Chevrel phase and Ternary superconductors, and in
the high fluence regime. We examine these behaviors based on the recent theory
of weak localization effect in superconductors. We find a good fitting to the
experimental data. In particular, weak localization correction to the
phonon-mediated interaction is derived from the density correlation function.
It is shown that weak localization has a strong influence on both the
phonon-mediated interaction and the electron-phonon interaction, which leads to
the universal correlation of and resistance ratio.Comment: 16 pages plus 3 figures, revtex, 76 references, For more information,
Plesse see http://www.fen.bilkent.edu.tr/~yjki
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