2,773 research outputs found
Towards robust aero-thermodynamic predictions for re-usable single-stage to orbit vehicles
Re-usable single stage to orbit launch vehicles promise to reduce the cost of access to space, but their success will be particularly reliant on accurate and robust modelling of their aero-thermodynamic characteristics. For preliminary design and optimization studies, relatively simple numerical prediction techniques must perforce be used, but it is important that the uncertainty that is inherent in the predictions of these models be understood. Predictions of surface pressure and heat transfer obtained using a new reduced-order model that is based on the Newtonian flow assumption and the Reynolds analogy for heating are compared against those of a more physically-sophisticated Direct Simulation Monte Carlo method in order to determine the ability of the model to capture the aero-thermodynamics of vehicles with very complex configuration even when run at low enough resolution to be practical in the context of design optimization studies. Attention is focused on the high-altitude regime where lifting re-usable Single-Stage to Orbit configurations will experience their greatest thermal load during re-entry, but where non-continuum effects within the gas of the atmosphere might be important. It is shown that the reduced-order model is capable of reproducing the results of the more complex Monte Carlo formalism with surprising fidelity, but that residual uncertainties exist, particularly in the behaviour of the heating models and in the applicability of the continuum assumption given the onset of finite slip velocity on surface of vehicle. The results suggest thus that, if used with care, reduced-order models such as those described here can be used very effectively in the design and optimization of space-access vehicles with very complex configuration, as long as their predictions are adequately supported by the use of more sophisticated computational techniques
Structure/activity relationships applied to the hydrogenation of α,β-unsaturated carbonyls: The hydrogenation of 3-butyne-2-one over alumina-supported palladium catalysts
The gas phase hydrogenation of 3-butyne-2-one, an alkynic ketone, over two alumina-supported palladium catalysts is investigated using infrared spectroscopy in a batch reactor at 373 K. The mean particle size of the palladium crystallites of the two catalysts are comparable (2.4 ± 0.1 nm). One catalyst (Pd(NO3)2/Al2O3) is prepared from a palladium(II) nitrate precursor, whereas the other catalyst (PdCl2/Al2O3) is prepared using palladium(II) chloride as the Pd precursor compound. A three-stage sequential process is observed with the Pd(NO3)2/Al2O3 catalyst facilitating complete reduction all the way through to 2-butanol. However, hydrogenation stops at 2-butanone with the PdCl2/Al2O3 catalyst. The inability of the PdCl2/Al2O3 catalyst to reduce 2-butanone is attributed to the inaccessibility of edge sites on this catalyst, which are blocked by chlorine retention originating from the catalyst’s preparative process. The reaction profiles observed for the hydrogenation of this alkynic ketone are consistent with the site-selective chemistry recently reported for the hydrogenation of crotonaldehyde, an alkenic aldehyde, over the same two catalysts. Thus, it is suggested that a previously postulated structure/activity relationship may be generic for the hydrogenation of α,β-unsaturated carbonyl compounds over supported Pd catalysts
Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide
Phase equilibrium data for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules
Bogoliubov Coefficients of 2D Charged Black Holes
We exactly calculate the thermal distribution and temperature of Hawking
radiation for a two-dimensional charged dilatonic black hole after it has
settled down to an "equilibrium" state. The calculation is carried out using
the Bogoliubov coefficients. The background of the process is furnished by a
preexisting black hole and not by collapsing matter as considered by Giddings
and Nelson for the case of a Schwarzschild black hole. Furthermore, the
vanishing of the temperature and/or the Hawking radiation in the extremal case
is obtained as a regular limit of the general case.Comment: 9 pages, 1 eps figur
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Relativistic Klystron Two-Beam Accelerator studies at the RTA test facility
A prototype rf power source based on the Relativistic Klystron Two- Beam Accelerator (RK-TBA) concept is being constructed at LBNL to study physics, engineering, and costing issues. The prototype, called RTA, is described and compared to a full scale design appropriate for driving the Next Linear Collider. Specific details of the induction core test and pulsed power system are presented. Details of the 1-MeV, 1.2-kA induction gun currently under construction are described
Higher-order mutual coherence of optical and matter waves
We use an operational approach to discuss ways to measure the higher-order
cross-correlations between optical and matter-wave fields. We pay particular
attention to the fact that atomic fields actually consist of composite
particles that can easily be separated into their basic constituents by a
detection process such as photoionization. In the case of bosonic fields, that
we specifically consider here, this leads to the appearance in the detection
signal of exchange contributions due to both the composite bosonic field and
its individual fermionic constituents. We also show how time-gated counting
schemes allow to isolate specific contributions to the signal, in particular
involving different orderings of the Schr\"odinger and Maxwell fields.Comment: 11 pages, 2 figure
First-principles study of nucleation, growth, and interface structure of Fe/GaAs
We use density-functional theory to describe the initial stages of Fe film
growth on GaAs(001), focusing on the interplay between chemistry and magnetism
at the interface. Four features appear to be generic: (1) At submonolayer
coverages, a strong chemical interaction between Fe and substrate atoms leads
to substitutional adsorption and intermixing. (2) For films of several
monolayers and more, atomically abrupt interfaces are energetically favored.
(3) For Fe films over a range of thicknesses, both Ga- and As-adlayers
dramatically reduce the formation energies of the films, suggesting a
surfactant-like action. (4) During the first few monolayers of growth, Ga or As
atoms are likely to be liberated from the interface and diffuse to the Fe film
surface. Magnetism plays an important auxiliary role for these processes, even
in the dilute limit of atomic adsorption. Most of the films exhibit
ferromagnetic order even at half-monolayer coverage, while certain
adlayer-capped films show a slight preference for antiferromagnetic order.Comment: 11 two-column pages, 12 figures, to appear in Phys. Rev.
Dark Energy and Extending the Geodesic Equations of Motion: Its Construction and Experimental Constraints
With the discovery of Dark Energy, , there is now a universal
length scale, , associated with the
universe that allows for an extension of the geodesic equations of motion. In
this paper, we will study a specific class of such extensions, and show that
contrary to expectations, they are not automatically ruled out by either
theoretical considerations or experimental constraints. In particular, we show
that while these extensions affect the motion of massive particles, the motion
of massless particles are not changed; such phenomena as gravitational lensing
remain unchanged. We also show that these extensions do not violate the
equivalence principal, and that because Mpc, a
specific choice of this extension can be made so that effects of this extension
are not be measurable either from terrestrial experiments, or through
observations of the motion of solar system bodies. A lower bound for the only
parameter used in this extension is set.Comment: 19 pages. This is the published version of the first half of
arXiv:0711.3124v2 with corrections include
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