Research for Electric Energy Systems

This report documents the technical progress in investigations. The first investigation is concerned with the measurement of magnetic fields in support of epidemiogical and in vitro studies of biological field effects. NIST cohosted a workshop on exposure and biological parameters that should be considered during the vitro studies with extremely low frequency (ELF) magnetic and electric fields. Also, equations were developed to predict the magnetic field in a parallel plate magnetic field exposure system. The second investigation is concerned with two different activities: the detection of trace levels of S{sub 2}F{sub 10} in SF{sub 6} and the development of an improved stochastic analyzer for pulsating phenomena (SAPP). The detection of S{sub 2}F{sub 10} in the presence of SF{sub 6} using mass-spectrometric detection coupled to a gas chromatograph is difficult because of the similar mass spectra. A technique is described that enables the detection of S{sub 2}F{sub 10} in gaseous SF{sub 6} down to the ppb level using a modified gas chromatograph-mass spectrometer. The new system was applied to an investigation of the stochastic behavior of negative corona (Trichel pulses) and the effect of a dielectric barrier on these discharges. The third investigation is concerned with breakdown and prebreakdown phenomena in liquid dielectrics. The activity reported here was a study of negative steamers preceding electric breakdown in hexanes. Using the image preserving optical delay, the growth of the streamers associated with partial discharges at a point cathode are photographed at high magnification. The last investigation is concerned with the evaluation and improvement of methods for measuring fast transients in electrical power systems such as might be associated with an electromagnetic impulse. A compact resistive divider, NIST4, was designed. It is anticipated that this divider together with some Kerr electro-optical devices will be used as the reference system at NIST

Titanium additions to MgB2 conductors

A series of doping experiments are reported for MgB2 conductors that have been synthesized using doped boron fibers prepared by chemical vapor deposition(CVD) methods. Undoped MgB2 samples prepared from CVD prepared fibers consistently give critical current densities, Jc, in the range of 500,000 A/cm^2 in low field at 5K. These values fall by a factor of about 100 as the magnetic field increases to 3T. For heavily Ti-doped boron fibers where the B/Ti ratio is comparable to 1, there is a substantial suppression of both Tc, superconducting volume fraction, and Jc values. If, however, a sample with a few percent Ti in B is deposited on a carbon coated SiC substrate and reacted at 1100 degrees C for 15 min, then Tc is suppressed only a couple of degrees Kelvin and critical current densities are found to be approximately 2-5 x 10^6 A/cm^2 for superconducting layers ranging from 4-10 micrometers thick. These materials show Jc values over 10,000 A/cm^2 at 25K and 1.3 T.Comment: 10 pages, 6 figure

Phoretic Motion of Spheroidal Particles Due To Self-Generated Solute Gradients

We study theoretically the phoretic motion of a spheroidal particle, which generates solute gradients in the surrounding unbounded solvent via chemical reactions active on its surface in a cap-like region centered at one of the poles of the particle. We derive, within the constraints of the mapping to classical diffusio-phoresis, an analytical expression for the phoretic velocity of such an object. This allows us to analyze in detail the dependence of the velocity on the aspect ratio of the polar and the equatorial diameters of the particle and on the fraction of the particle surface contributing to the chemical reaction. The particular cases of a sphere and of an approximation for a needle-like particle, which are the most common shapes employed in experimental realizations of such self-propelled objects, are obtained from the general solution in the limits that the aspect ratio approaches one or becomes very large, respectively.Comment: 18 pages, 5 figures, to appear in European Physical Journal

Electronic structure study of double perovskites A2A_{2}FeReO6_{6} (A=Ba,Sr,Ca) and Sr2M_{2}MMoO6_{6} (M=Cr,Mn,Fe,Co) by LSDA and LSDA+U

We have implemented a systematic LSDA and LSDA+U study of the double perovskites $A_{2}$FeReO$_{6}$ (A=Ba,Sr,Ca) and Sr$_{2}$$M$MoO$_{6}$ (M=Cr,Mn,Fe,Co) for understanding of their intriguing electronic and magnetic properties. The results suggest a ferrimagnetic (FiM) and half-metallic (HM) state of $A_{2}$FeReO$_{6}$ (A=Ba,Sr) due to a pdd-$\pi$ coupling between the down-spin Re$^{5+}$/Fe$^{3+}$ $t_{2g}$ orbitals via the intermediate O $2p_{\pi}$ ones, also a very similar FiM and HM state of Sr$_{2}$FeMoO$_{6}$. In contrast, a decreasing Fe $t_{2g}$ component at Fermi level ($E_{F}$) in the distorted Ca$_{2}$FeReO$_{6}$ partly accounts for its nonmetallic behavior, while a finite $pdd$-$\sigma$ coupling between the down-spin Re$^{5+}$/Fe$^{3+}$ $e_{g}$ orbitals being present at $E_{F}$ serves to stabilize its FiM state. For Sr$_{2}$CrMoO$_{6}$ compared with Sr$_{2}$FeMoO$_{6}$, the coupling between the down-spin Mo$^{5+}$/Cr$^{3+}$ $t_{2g}$ orbitals decreases as a noticeable shift up of the Cr$^{3+}$ 3d levels, which is likely responsible for the decreasing $T_{C}$ value and weak conductivity. Moreover, the calculated level distributions indicate a Mn$^{2+}$(Co$^{2+}$)/Mo$^{6+}$ ionic state in Sr$_{2}$MnMoO$_{6}$ (Sr$_{2}$CoMoO$_{6}$), in terms of which their antiferromagnetic insulating ground state can be interpreted. While orbital population analyses show that owing to strong intrinsic pd covalence effects, Sr$_{2}M$MoO$_{6}$ (M=Cr,Mn,Fe,Co) have nearly the same valence state combinations, as accounts for the similar M-independent spectral features observed in them.Comment: 21 pages, 3 figures. to be published in Phys. Rev. B on 15th Se

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Phase diagrams of La1−xCaxMnO3\rm La_{1-x}Ca_xMnO_3 in Double Exchange Model with added antiferromagnetic and Jahn-Teller interaction

The phase diagram of the multivalent manganites $\rm La_{1-x}Ca_xMnO_3$, in space of temperature and doping $x$, is a challenge for the theoretical physics. It is an important test for the model used to study these compounds and the method of calculation. To obtain theoretically this diagram for $x<0.5$, we consider the two-band Double Exchange Model for manganites with added Jahn-Teller coupling and antiferromagnetic Heisenberg term. In order to calculate Curie and N\'{e}el temperatures we derive an effective Heisenberg model for a vector which describes the local orientation of the total magnetization of the system. The exchange constants of this model are different for different space directions and depend on the density of $e_g$ electrons, antiferromagnetic constants and the Jahn-Teller energy. To reproduce the well known phase transitions from A-type antiferromagnetism to ferromagnetism at low $x$ and C-type antiferromagnetism to G-type antiferromagnetism at large $x$, we argue that the antiferromagnetic exchange constants should depend on the lattice direction. We show that ferromagnetic to A-type antiferromagnetic transition results from the Jahn-Teller distortion. Accounting adequately for the magnon-magnon interaction, Curie and N\'{e}el temperatures are calculated. The results are in very good agreement with the experiment and provide values for the model parameters, which best describe the behavior of the critical temperature for $x<0.5$.Comment: 13 pages, 5 figure

Transverse optical Josephson plasmons, equations of motion

A detailed calculation is presented of the dielectric function in superconducttors consisting of two Josephson coupled superconducting layers per unit cell, taking into account the effect of finite compressibility of the electron fluid. From the model it follows, that two longitudinal, and one transverse optical Josephson plasma resonance exist in these materials, for electric field polarization perpendicular to the planes. The latter mode appears as a resonance in the transverse dielectric function, and it couples directly to the electrical field vector of infrared radiation. A shift of all plasma frequencies, and a reduction of the intensity of the transverse optical Josephson plasmon is shown to result from the finite compressibility of the electron fluid.Comment: 17 pages, ReVTeX, 7 figures in eps forma

Anisotropic optical properties of single-crystal GdBa2Cu3O7-delta

The optical spectrum of reduced-T(c) GdBa2Cu3O7-delta has been measured for polarizations parallel and perpendicular to the ab plane. The sample was an oxygen-deficient single crystal with a large face containing the c axis. The polarized reflectance from this face was measured from 20-300 K in the spectral region from 30-3000 cm-1, with 300 K data to 30 000 cm-1. Kramers-Kronig analysis was used to determine the spectral dependence of the ab and the c components of the dielectric tensor. The optical properties are strongly anisotropic. The ab-plane response resembles that of other reduced-T(c) materials whereas the c axis, in contrast, shows only the presence of several phonons. There is a complete absence of charge carrier response along c above and below T(c). This observation allows us to set an upper limit to the free-carrier spectral weight for transport perpendicular to the CuO2 planes

Spin state and phase competition in TbBaCo_{2}O_{5.5} and the lanthanide series LnBaCo_{2}O_{5+\delta} (0<=\delta<=1)

A clear physics picture of TbBaCo$_{2}$O$_{5.5}$ is revealed on the basis of density functional theory calculations. An antiferromagnetic (AFM) superexchange coupling between the almost high-spin Co$^{3+}$ ions competes with a ferromagnetic (FM) interaction mediated by both p-d exchange and double exchange, being responsible for the observed AFM-FM transition. And the metal-insulator transition is accompanied by an xy/xz orbital-ordering transition. Moreover, this picture can be generalized to the whole lanthanide series, and it is predicted that a few room-temperature magnetoresistance materials could be found in LnBa$_{1-x}$A$_{x}$Co$_{2}$O$_{5+\delta}$ (Ln=Ho,Er,Tm,Yb,Lu; A=Sr,Ca,Mg).Comment: 13 pages, 2 figures; to be published in Phys. Rev. B on 1st Sept. Title and Bylines are added to the revised versio