The polymeric conformational effect on capacitive deionization performance of graphene oxide/polypyrrole composite electrode

Exploitation of novel faradic materials is an alternative implementation for solving the problem of poor specific electrosorption capacity that conventional carbon materials are encountered in capacitive deionization. Particularly, composite electrode is just a suitable choice because of its potentially high ion-storage ability. Herein, a cyclic voltammetric treatment method with different low limit of potential window was used to manipulate the polymeric conformation and doping level of graphene oxide/polypyrrole (GO/PPy) composite electrode. Based on it, the effect of polymeric structure on the electrosorption performance was systematically studied. When the low limit of potential window is shifted negatively enough, the irreversible polymeric conformational shrinks of GO/PPy are promoted, which not only hinders the insertion process of ions, but also decreases the doping level of polymer due to the intensive interchain-action produced by more entangled polymeric chain. Thus, the number of intercalated ions should decrease, which is expressed by electrochemical impedance spectroscopy (EIS) results and is proportional to the electrosorption capacity of GO/PPy composite electrode in membrane capacitive deionization (MCDI) process. Our work suggests that the less packing density, higher doping level and more charge delocalization on PPy backbone in electrode are beneficial to enhance its capacitive deionization performance

VLBI observation of the newly discovered z=5.18 quasar SDSS J0131-0321

Few high-redshift, radio-loud quasars are known to date. The extremely luminous, radio-bright quasar, SDSS J013127.34-032100.1 was recently discovered at a redshift of $z=5.18$. We observed the source with high resolution very long baseline interferometry (VLBI) at 1.7 GHz with the European VLBI Network (EVN) and found a single compact radio component. We estimated a lower limit to the brightness temperature of the detected radio component, T_B~10^{11} K. Additionaly, when compared to archival radio data, the source showed significant flux density variation. These two findings are indicative of the blazar nature of the source.Comment: 5 pages, 2 figures. Accepted for publication in MNRAS Letter

The Absolute Magnitudes of Red Horizontal Branch Stars in the ugriz System

Based on photometric data of the central parts of eight globular clusters and one open cluster presented by An and his collaborators, we select red horizontal branch (RHB) stars in the (g-r)0-g0 diagram and make a statistical study of the distributions of their colors and absolute magnitudes in the SDSS ugriz system. Meanwhile, absolute magnitudes in the Johnson VRI system are calculated through the translation formulae between gri and VRI in the literature. The calibrations of absolute magnitude as functions of metallicity and age are established by linear regressions of the data. It is found that metallicity coefficients in these calibrations decrease, while age coefficients increase, from the blue $u$ filter to the red $z$ filter. The calibration of Mi= 0.06[Fe/H]+0.040t+0.03 has the smallest scatter of 0.04 mag, and thus i is the best filter in the $ugriz$ system when RHB stars are used for distance indicators. The comparison of the MI calibration from our data with that from red clump stars indicates that the previous suggestion that the $I$ filter is better than the V filter in distance determination may not be true because of its significant dependence on age.Comment: 19 pages, 7 figures, accepted by Ap

Sign reversal of field-angle resolved heat capacity oscillations in a heavy fermion superconductor CeCoIn5_5 and dx2−y2d_{x^2-y^2} pairing symmetry

To identify the superconducting gap symmetry in CeCoIn5 (Tc=2.3 K), we performed angle-resolved specific heat (C_\phi) measurements in a field rotated around the c-axis down to very low temperatures 0.05Tc and detailed theoretical calculations. In a field of 1 T, a sign reversal of the fourfold angular oscillation in C_\phi has been observed at T ~ 0.1Tc on entering a quasiclassical regime where the maximum of C_\phi corresponds to the antinodal direction, coinciding with the angle-resolved density of states (ADOS) calculation. The C_\phi behavior, which exhibits minima along [110] directions, unambiguously allows us to conclude d_{x^2-y^2} symmetry of this system. The ADOS-quasiclassical region is confined to a narrow T and H domain within T/Tc ~ 0.1 and 1.5 T (0.13Hc2).Comment: 4 pages, 4 figure

The radio structure of 3C 316, a galaxy with double-peaked narrow optical emission lines

The galaxy 3C\,316 is the brightest in the radio band among the optically-selected candidates exhibiting double-peaked narrow optical emission lines. Observations with the Very Large Array (VLA), Multi-Element Remotely Linked Interferometer Network (e-MERLIN), and the European VLBI Network (EVN) at 5\,GHz have been used to study the radio structure of the source in order to determine the nature of the nuclear components and to determine the presence of radio cores. The e-MERLIN image of 3C 316 reveals a collimated coherent east-west emission structure with a total extent of about 3 kpc. The EVN image shows seven discrete compact knots on an S-shaped line. However, none of these knots could be unambiguously identified as an AGN core. The observations suggest that the majority of the radio structure belongs to a powerful radio AGN, whose physical size and radio spectrum classify it as a compact steep-spectrum source. Given the complex radio structure with radio blobs and knots, the possibility of a kpc-separation dual AGN cannot be excluded if the secondary is either a naked core or radio quiet.Comment: 12 pages, 3 figures, 2 tables. Accepted for publication in the MNRA

Four dual AGN candidates observed with the VLBA

According to hierarchical structure formation models, merging galaxies are expected to be seen in different stages of their coalescence. However, currently there are no straightforward observational methods neither to select nor to confirm a large number of dual active galactic nuclei (AGN) candidates. Most attempts involve the better understanding of double-peaked narrow emission line sources, to distinguish the objects where the emission lines originate from narrow-line kinematics or jet-driven outflows from those which might harbour dual AGN. We observed four such candidate sources with the Very Long Baseline Array (VLBA) at 1.5 GHz with $\sim$ 10 milli-arcsecond angular resolution where spectral profiles of AGN optical emission suggested the existence of dual AGN. In SDSS J210449.13-000919.1 and SDSS J23044.82-093345.3, the radio structures are aligned with the optical emission features, thus the double-peaked emission lines might be the results of jet-driven outflows. In the third detected source SDSS J115523.74+150756.9, the radio structure is less extended and oriented nearly perpendicular to the position angle derived from optical spectroscopy. The fourth source remained undetected with the VLBA but it has been imaged with the Very Large Array at arcsec resolution a few months before our observations, suggesting the existence of extended radio structure. In none of the four sources did we detect two radio-emitting cores, a convincing signature of duality.Comment: 35 pages, 3 figures, 2 tables, accepted for publication in Ap

Earliest Holocene south Greenland ice sheet retreat within its late Holocene extent

Early Holocene summer warmth drove dramatic Greenland ice sheet (GIS) retreat. Subsequent insolation-driven cooling caused GIS margin readvance to late Holocene maxima, from which ice margins are now retreating. We use 10Be surface exposure ages from four locations between 69.4°N and 61.2°N to date when in the early Holocene south to west GIS margins retreated to within these late Holocene maximum extents. We find that this occurred at 11.1 ± 0.2 ka to 10.6 ± 0.5 ka in south Greenland, significantly earlier than previous estimates, and 6.8 ± 0.1 ka to 7.9 ± 0.1 ka in southwest to west Greenland, consistent with existing 10Be ages. At least in south Greenland, these 10Be ages likely provide a minimum constraint for when on a multicentury timescale summer temperatures after the last deglaciation warmed above late Holocene temperatures in the early Holocene. Current south Greenland ice margin retreat suggests that south Greenland may have now warmed to or above earliest Holocene summer temperatures