Study of Biomass Bottom Ash Efficiency as Phosphate Sorbent Material

Excessive richness of nutrients in water bodies such as rivers, lakes and ponds lead into deterioration of aquatic life as a results of dense growth of algae. Phosphate is one of the main nutrients that should be controlled to prevent this serious issue. Utilizing low cost material as a phosphate sorbent is offering a treatment method characterized as a sustainable solution. In this study the efficiency of biomass bottom ash BBA as phosphate sorbent material from aqueous solution is investigated. Batch experiments were undertaken, in which a particular mass of BBA was brought into contact with the phosphate solution. The experiments studied the influence of pH (different phosphate solutions were prepared with pH range 4 to 8), temperature (adsorption capacity measured at the temperature range of 10 to 30 °C), and contact time. In addition, the adsorption isotherm models were also applied to better understand the mechanism of phosphate sorption by BBA. The results revealed that the bonding between the cations (BBA surface) and anions (phosphate solution) is significantly affected by the pH of the solution. BBA presents an excellent phosphate sorption, especially, at low pH value and temperature around 20 oC. The method of this research can be adopted as a followed strategy for examination the capability of selected material for phosphorus removal from wastewater

Performance investigation of furnace bottom ash as a filter media for phosphate removal

This study investigates the capability of furnace bottom ash (FBA) as a filter media for phosphorus removal from wastewater effluents. Lab-scale studies were conducted, in which a mass of FBA was brought into contact with the phosphate solution (a predominant form of phosphorus in wastewater) in batch experiments and lab-scale filter. Intraparticle Diffusion Model (IPD) was applied and revealed that the mechanism of phosphate adsorption onto FBA consist of three phases; film phase occurred in the external surface and intraparticle diffusion phases take place in the wide pores and microspores. A Point Zero Charge (PZC) study was conducted and indicated that the FBA acts as anion exchanger and develops negative charge when the pH more than 9. Based on the PZC outcomes the FBA efficiency was regenerated by two washing methods (continuous and intermittent) with deionized water solution at pH 9.5 and 10. The intermittent washing method gave better results as the FBA regenerate 95% of its efficiency. FBA was achieved the phosphate permissible limit (0.1 mg/L) in synthetic solution at 150 min. While, in real wastewater sample was achieved it in 180 min. The FBA washing method based on PZC can be adopted as a strategy for absorbents efficiency regeneration and phosphorus recovery.Validerad;2020;Nivå 2;2020-07-15 (alebob)</p

Assessing the effectiveness of low-cost materials to act as filter media for phosphate sorption

In this research, an assessment was conducted for several materials to examine their efficiency for sorption phosphate and their potential use as filter media. This work focuses on seeking materials that can achieve high, rapid, and robust phosphate retention. To assess the phosphate removal efficiency, batch-mode testing was conducted. The capability of the selected materials for effectively removal the phosphate is largely influenced by their inherent properties. Therefore, this research determines the effectiveness of the material by examining its physical and chemical characteristics. The selection method for these materials was guided by the understanding that the sorbents that have the most effective behavior for phosphate tend to contain easily soluble Ca/Mg compounds or Fe/Al hydroxides. The findings of the batch experiments demonstrated that material such as Bio ash (Bio-A) exhibited superior phosphate removal performance throughout the entire duration of the experiments. In contrast, materials calcium carbonate (C-C) and conventional silica (C-S) displayed relatively poor removal performance compared to Bio-A.Godkänd;2024;Nivå 0;2024-04-08 (marisr);Full text license: CC BY</p

A Novel Coating Method for Create Filter Media Capable to Remove Phosphate from Wastewater Effectively

Filtration materials coating with metallic oxides represented a good method for phosphate sorption. However, most of the researchers utilize chemicals as a source of metallic oxides and heating process to set the chemicals over the filtration materials. This study is aimed to introduce the furnace bottom ash FBA as a source of metallic oxides; it is available free because it is dumped as a waste material from power generation plants. The method of creating new filter media involves coating the limestone and sand by FBA, and the ordinary Portland cement OPC utilized as binder to binding the mixture materials. The water is the factor which is responsible for activating the OPC. All factors such as mixed materials ratio, water content and age of reaction have subjected to optimization process. The results revealed that the optimal mixture for phosphate removal consists of 40% FBA, 5% OPC from dry weight of supporting material, 35% water ratio from the total weight of FBA and OPC, and 14 days are enough to complete the materials reaction. Limestone-furnace bottom ash LFBA indicated high capacity for phosphate sorption and possibility  of  efficiency  regenerate.  This  study  demonstrates  a  new  method  for coating the filtration materials more convenient with sustainability approach.Validerad;2020;Nivå 1;2019-12-19 (johcin)</p