Determination of dissolved oxygen in water with leukoberbelin-blue I. A quick Winkler method. [Translation from: Z.analyt.Chem. 262 97-99, 1972.]

The reaction of Mn(II) with water-dissolved oxygen, to a higher manganese hydroxide in an alkaline medium, as with the longstanding classic Winkler method, is the first step in the method described here. The assumption for faultless results by the conventional and modified Winkler method is clean water, which contains no organic substances by Mn(III) or Mn(IV). In many cases, however, eg. in river and lake-water tests, it can be seen with the naked eye that after some time the originally brown-coloured precipitate of manganese hydroxide becomes more and more colourless. Oxygen content was analysed in the water samples and evaluated by raising the amount of the leuko-base and giving the corresponding dilution of the colouring matter solution formed still higher oxygen contents can be measured

Toric rings, inseparability and rigidity

This article provides the basic algebraic background on infinitesimal deformations and presents the proof of the well-known fact that the non-trivial infinitesimal deformations of a $K$-algebra $R$ are parameterized by the elements of cotangent module $T^1(R)$ of $R$. In this article we focus on deformations of toric rings, and give an explicit description of $T^1(R)$ in the case that $R$ is a toric ring. In particular, we are interested in unobstructed deformations which preserve the toric structure. Such deformations we call separations. Toric rings which do not admit any separation are called inseparable. We apply the theory to the edge ring of a finite graph. The coordinate ring of a convex polyomino may be viewed as the edge ring of a special class of bipartite graphs. It is shown that the coordinate ring of any convex polyomino is inseparable. We introduce the concept of semi-rigidity, and give a combinatorial description of the graphs whose edge ring is semi-rigid. The results are applied to show that for $m-k=k=3$, $G_{k,m-k}$ is not rigid while for $m-k\geq k\geq 4$, $G_{k,m-k}$ is rigid. Here $G_{k,m-k}$ is the complete bipartite graph $K_{m-k,k}$ with one edge removed.Comment: 33 pages, chapter 2 of the Book << Multigraded Algebra and Applications>> 2018, Springer International Publishing AG, part of Springer Natur

Electroweak Supersymmetry with an Approximate U(1)_PQ

A predictive framework for supersymmetry at the TeV scale is presented, which incorporates the Ciafaloni-Pomarol mechanism for the dynamical determination of the \mu parameter of the MSSM. It is replaced by (\lambda S), where S is a singlet field, and the axion becomes a heavy pseudoscalar, G, by adding a mass, m_G, by hand. The explicit breaking of Peccei-Quinn (PQ) symmetry is assumed to be sufficiently weak at the TeV scale that the only observable consequence is the mass m_G. Three models for the explicit PQ breaking are given; but the utility of this framework is that the predictions for all physics at the electroweak scale are independent of the particular model for PQ breaking. Our framework leads to a theory similar to the MSSM, except that \mu is predicted by the Ciafaloni-Pomarol relation, and there are light, weakly-coupled states in the spectrum. The production and cascade decay of superpartners at colliders occurs as in the MSSM, except that there is one extra stage of the cascade chain, with the next-to-LSP decaying to its "superpartner" and \tilde{s}, dramatically altering the collider signatures for supersymmetry. The framework is compatible with terrestrial experiments and astrophysical observations for a wide range of m_G and . If G is as light as possible, 300 keV < m_G < 3 MeV, it can have interesting effects on the radiation energy density during the cosmological eras of nucleosynthesis and acoustic oscillation, leading to predictions for N_{\nu BBN} and N_{\nu CMB} different from 3.Comment: 45 pages, 2 colour figures, a reference added, minor correction

Prevalence of marginally unstable periodic orbits in chaotic billiards

The dynamics of chaotic billiards is significantly influenced by coexisting regions of regular motion. Here we investigate the prevalence of a different fundamental structure, which is formed by marginally unstable periodic orbits and stands apart from the regular regions. We show that these structures both {\it exist} and {\it strongly influence} the dynamics of locally perturbed billiards, which include a large class of widely studied systems. We demonstrate the impact of these structures in the quantum regime using microwave experiments in annular billiards.Comment: 6 pages, 5 figure

Stickiness in Hamiltonian systems: from sharply divided to hierarchical phase space

We investigate the dynamics of chaotic trajectories in simple yet physically important Hamiltonian systems with non-hierarchical borders between regular and chaotic regions with positive measures. We show that the stickiness to the border of the regular regions in systems with such a sharply divided phase space occurs through one-parameter families of marginally unstable periodic orbits and is characterized by an exponent \gamma= 2 for the asymptotic power-law decay of the distribution of recurrence times. Generic perturbations lead to systems with hierarchical phase space, where the stickiness is apparently enhanced due to the presence of infinitely many regular islands and Cantori. In this case, we show that the distribution of recurrence times can be composed of a sum of exponentials or a sum of power-laws, depending on the relative contribution of the primary and secondary structures of the hierarchy. Numerical verification of our main results are provided for area-preserving maps, mushroom billiards, and the newly defined magnetic mushroom billiards.Comment: To appear in Phys. Rev. E. A PDF version with higher resolution figures is available at http://www.pks.mpg.de/~edugal

Density Functional Theory for the Photoionization Dynamics of Uracil

Photoionization dynamics of the RNA base Uracil is studied in the framework of Density Functional Theory (DFT). The photoionization calculations take advantage of a newly developed parallel version of a multicentric approach to the calculation of the electronic continuum spectrum which uses a set of B-spline radial basis functions and a Kohn-Sham density functional hamiltonian. Both valence and core ionizations are considered. Scattering resonances in selected single-particle ionization channels are classified by the symmetry of the resonant state and the peak energy position in the photoelectron kinetic energy scale; the present results highlight once more the site specificity of core ionization processes. We further suggest that the resonant structures previously characterized in low-energy electron collision experiments are partly shifted below threshold by the photoionization processes. A critical evaluation of the theoretical results providing a guide for future experimental work on similar biosystems

Structural characterization and photochemical properties of mono-and bimetallic Cu-Mabiq complexes

A series of mono- and bimetallic copper-Mabiq complexes is described. One-electron reduction of the CuII and CuICuII complexes is ligand-centered, yielding the (Mabiq•) form of the macrocycle. Both bimetallic compounds are thus mixed-valent with respect to the metal ions. The influence of the outer copper ion on the redox, spectroscopic, and photochemical properties of the central ion was examined. The two metals ions interact weakly, such that the photoactivity of the central Cu-Mabiq unit is retained

Clebsch-Gordan Construction of Lattice Interpolating Fields for Excited Baryons

Large sets of baryon interpolating field operators are developed for use in lattice QCD studies of baryons with zero momentum. Operators are classified according to the double-valued irreducible representations of the octahedral group. At first, three-quark smeared, local operators are constructed for each isospin and strangeness and they are classified according to their symmetry with respect to exchange of Dirac indices. Nonlocal baryon operators are formulated in a second step as direct products of the spinor structures of smeared, local operators together with gauge-covariant lattice displacements of one or more of the smeared quark fields. Linear combinations of direct products of spinorial and spatial irreducible representations are then formed with appropriate Clebsch-Gordan coefficients of the octahedral group. The construction attempts to maintain maximal overlap with the continuum SU(2) group in order to provide a physically interpretable basis. Nonlocal operators provide direct couplings to states that have nonzero orbital angular momentum.Comment: This manuscript provides an anlytical construction of operators and is related to hep-lat/0506029, which provides a computational construction. This e-print version contains a full set of Clebsch-Gordan coefficients for the octahedral grou

On the classification of Kahler-Ricci solitons on Gorenstein del Pezzo surfaces

We give a classification of all pairs (X,v) of Gorenstein del Pezzo surfaces X and vector fields v which are K-stable in the sense of Berman-Nystrom and therefore are expected to admit a Kahler-Ricci solition. Moreover, we provide some new examples of Fano threefolds admitting a Kahler-Ricci soliton.Comment: 21 pages, ancillary files containing calculations in SageMath; minor correction