The Effect of Aqueous Alteration in Antarctic Carbonaceous Chondrites from Comparative ICP-MS Bulk Chemistry

Terrestrial ages of Antarctic carbonaceous chondrites (CC) indicate that these meteorites have been preserved in or on ice for, at least, tens of thousands of years. Due to the porous structure of these chondrites formed by the aggregation of silicate-rich chondrules, refractory inclusions, metal grains, and fine-grained matrix materials, the effect of pervasive terrestrial water is relevant. Our community defends that pristine CC matrices are representing samples of scarcely processed protoplanetary disk materials as they contain stellar grains, but they might also trace parent body processes. It is important to study the effects of terrestrial aqueous alteration in promoting bulk chemistry changes, and creating distinctive alteration minerals. Particularly because it is thought that aqueous alteration has particularly played a key role in some CC groups in modifying primordial bulk chemistry, and homogenizing the isotopic content of fine-grained matrix materials. Fortunately, the mineralogy produced by parent-body and terrestrial aqueous alteration processes is distinctive. With the goal to learn more about terrestrial alteration in Antarctica we are obtaining reflectance spectra of CCs, but also performing ICP-MS bulk chemistry of the different CC groups. A direct comparison with the mean bulk elemental composition of recovered falls might inform us on the effects of terrestrial alteration in finds. With such a goal, in the current work we have analyzed some members representative of CO and CM chondrite groups

Confirmation of an exoplanet using the transit color signature: Kepler-418b, a blended giant planet in a multiplanet system

We announce confirmation of Kepler-418b, one of two proposed planets in this system. This is the first confirmation of an exoplanet based primarily on the transit color signature technique. We used the Kepler public data archive combined with multicolor photometry from the Gran Telescopio de Canarias and radial velocity follow-up using FIES at the Nordic Optical Telescope for confirmation. We report a confident detection of a transit color signature that can only be explained by a compact occulting body, entirely ruling out a contaminating eclipsing binary, a hierarchical triple, or a grazing eclipsing binary. Those findings are corroborated by our radial velocity measurements, which put an upper limit of ~1 Mjup on the mass of Kepler-418b. We also report that the host star is significantly blended, confirming the ~10% light contamination suspected from the crowding metric in the Kepler light curve measured by the Kepler team. We report detection of an unresolved light source that contributes an additional ~40% to the target star, which would not have been detected without multicolor photometric analysis. The resulting planet-star radius ratio is 0.110 +/- 0.0025, more than 25% more than the 0.087 measured by Kepler, leading to a radius of 1.20 +/- 0.16 Rjup instead of the 0.94 Rjup measured by the Kepler team. This is the first confirmation of an exoplanet candidate based primarily on the transit color signature, demonstrating that this technique is viable from ground for giant planets. It is particularly useful for planets with long periods such as Kepler-418b, which tend to have long transit durations. Additionally, multicolor photometric analysis of transits can reveal unknown stellar neighbors and binary companions that do not affect the classification of the transiting object but can have a very significant effect on the perceived planetary radius.Comment: accepted by Astronomy & Astrophysic

Mid-infrared imaging- and spectro-polarimetric subarcsecond observations of NGC 1068

We present sub-arcsecond 7.5$-$13 $\mu$m imaging- and spectro-polarimetric observations of NGC 1068 using CanariCam on the 10.4-m Gran Telescopio CANARIAS. At all wavelengths, we find: (1) A 90 $\times$ 60 pc extended polarized feature in the northern ionization cone, with a uniform $\sim$44$^{\circ}$ polarization angle. Its polarization arises from dust and gas emission in the ionization cone, heated by the active nucleus and jet, and further extinguished by aligned dust grains in the host galaxy. The polarization spectrum of the jet-molecular cloud interaction at $\sim$24 pc from the core is highly polarized, and does not show a silicate feature, suggesting that the dust grains are different from those in the interstellar medium. (2) A southern polarized feature at $\sim$9.6 pc from the core. Its polarization arises from a dust emission component extinguished by a large concentration of dust in the galaxy disc. We cannot distinguish between dust emission from magnetically aligned dust grains directly heated by the jet close to the core, and aligned dust grains in the dusty obscuring material surrounding the central engine. Silicate-like grains reproduce the polarized dust emission in this feature, suggesting different dust compositions in both ionization cones. (3) An upper limit of polarization degree of 0.3 per cent in the core. Based on our polarization model, the expected polarization of the obscuring dusty material is $\lesssim$0.1 per cent in the 8$-$13 $\mu$m wavelength range. This low polarization may be arising from the passage of radiation through aligned dust grains in the shielded edges of the clumps.Comment: 17 pages, 10 figures, accepted for publication at MNRA

Characterization of Mycobacterium tuberculosis Beijing isolates from the Mediterranean area

<p>Abstract</p> <p>Background</p> <p>The Beijing lineage of <it>Mycobacterium tuberculosis </it>is causing concern due to its global distribution and its involvement in severe outbreaks. Studies focused on this lineage are mainly restricted to geographical settings where its prevalence is high, whereas those in other areas are scarce. In this study, we analyze Beijing isolates in the Mediterranean area, where this lineage is not prevalent and is mainly associated with immigrant cases.</p> <p>Results</p> <p>Only 1% (N = 26) of the isolates from two population-based studies in Spain corresponded to Beijing strains, most of which were pan-susceptible and from Peruvian and Ecuadorian patients. Restriction fragment length polymorphism typing with the insertion sequence IS<it>6110 </it>identified three small clusters (2-3 cases). Mycobacterial interspersed repetitive unit-variable number tandem repeat typing (MIRU-15) offered low discriminatory power, requiring the introduction of five additional loci. A selection of the Beijing isolates identified in the Spanish sample, together with a sample of Beijing strains from Italy, to broaden the analysis context in the Mediterranean area, were assayed in an infection model with THP-1 cells. A wide range of intracellular growth rates was observed with only two isolates showing an increased intracellular replication, in both cases associated with contained production of TNF-α. No correlation was observed between virulence and the Beijing phylogenetic group, clustered/orphan status, or resistance. The Beijing strain responsible for extensive spread on Gran Canaria Island was also identified in Madrid, but did not lead to secondary cases and did not show high infectivity in the infection model.</p> <p>Conclusions</p> <p>The Beijing lineage in our area is a non-homogeneous family, with only certain highly virulent representatives. The specific characterization of Beijing isolates in different settings could help us to accurately identify the virulent representatives before making general assumptions about this lineage.</p

Platinum and N-doped carbon nanostructures as catalysts in hydrodechlorination reactions

Novel Pt catalysts supported on undoped and N-doped (1% N, w) carbons with well interconnected and nanostructured mesoporosity (Vmesopore = 0.65 cm3 g−1, SEXT = 730 m2 g−1) were prepared and tested in the hydrodechlorination of 4-chlorophenol in water at 30–70 °C. The growth of Pt nanoparticles was achieved using incipient wetness impregnation and a modified colloidal synthesis. Total conversion of 4chlorophenol and 100% selectivity to cyclohexanol was achieved. The remarkable activity in the hydrogenation of the phenol resulting from hydrodechlorination has not been reported before with Pt catalysts and it is of high interest because it maximizes detoxification. When the Pt NPs were synthesized by incipient wetness impregnation some influence of the N-doping of the support was observed in the size and electronic state of the NPs. However, highly reproducible Pt NPs were prepared by in situ colloidal synthesis regardless the nature of the support. In this last case similar activity was observed for the catalysts with undoped and N-doped carbon support, although the activity increased more with temperature for the later. Apparent activation energies of 15–25 kJ mol−1 were obtained for the disappearance of 4-chlorophenolThe authors also thank to Hexion Speciality Chemicals Iberica S.A. for providing the resol resin Bakelite®PF9934 FL. The authors thank financial support (CTQ2012-32821, CTQ2015-65491_R) and C. Ruiz-García for PhD grant (BES-2013-066085) to MINEC