969 research outputs found
Doubly forbidden second-harmonic generation from isotropic suspensions: Studies on the purple membrane of Halobacteriumhalobium
Process for the preparation of polycarboranylphosphazenes
A process for the preparation of polycarboranylphosphazenes is described. Polydihalophosphazenes are allowed to react at ambient temperatures for at least one hour with a lithium carborane in a suitable inert solvent. The remaining chlorine substituents of the carboranyl polyphosphazene are then replaced with aryloxy or alkoxy groups to enhance moisture resistance. The polymers give a high char yield when exposed to extreme heat and flame and can be used as insulation
Carboranylcyclotriphosphazenes and their polymers
Carboranyl-substituted polyphosphazenes are prepared by heat polymerizing a carboranyl halocyclophosphazene at 250 C for about 120 hours in the absence of oxygen and moisture. The cyclophosphazene is obtained by allowing a lithium carborane, e.g., the reaction product of methyl-o-carborane with n-butyllithium in ethyl ether, to react with e.g., hexachlorocyclotriphosphazene at ambient temperatures and in anhydrous conditions. For greater stability in the presence of moisture, the chlorine substituents of the polymer are then replaced by aryloxy or alkoxy groups, such as CF3CH2O. The new substantially inorganic polymers are thermally stable materials which produce a high char yield when exposed to extreme temperatures, and can thus serve to insulate less heat and fire resistant substances
Quantum Time and Spatial Localization: An Analysis of the Hegerfeldt Paradox
Two related problems in relativistic quantum mechanics, the apparent
superluminal propagation of initially localized particles and dependence of
spatial localization on the motion of the observer, are analyzed in the context
of Dirac's theory of constraints. A parametrization invariant formulation is
obtained by introducing time and energy operators for the relativistic particle
and then treating the Klein-Gordon equation as a constraint. The standard,
physical Hilbert space is recovered, via integration over proper time, from an
augmented Hilbert space wherein time and energy are dynamical variables. It is
shown that the Newton-Wigner position operator, being in this description a
constant of motion, acts on states in the augmented space. States with strictly
positive energy are non-local in time; consequently, position measurements
receive contributions from states representing the particle's position at many
times. Apparent superluminal propagation is explained by noting that, as the
particle is potentially in the past (or future) of the assumed initial place
and time of localization, it has time to propagate to distant regions without
exceeding the speed of light. An inequality is proven showing the Hegerfeldt
paradox to be completely accounted for by the hypotheses of subluminal
propagation from a set of initial space-time points determined by the quantum
time distribution arising from the positivity of the system's energy. Spatial
localization can nevertheless occur through quantum interference between states
representing the particle at different times. The non-locality of the same
system to a moving observer is due to Lorentz rotation of spatial axes out of
the interference minimum.Comment: This paper is identical to the version appearing in J. Math. Phys.
41; 6093 (Sept. 2000). The published version will be found at
http://ojps.aip.org/jmp/. The paper (40 page PDF file) has been completely
revised since the last posting to this archiv
Composite absorbing potentials
The multiple scattering interferences due to the addition of several
contiguous potential units are used to construct composite absorbing potentials
that absorb at an arbitrary set of incident momenta or for a broad momentum
interval.Comment: 9 pages, Revtex, 2 postscript figures. Accepted in Phys. Rev. Let
Real clocks and the Zeno effect
Real clocks are not perfect. This must have an effect in our predictions for
the behaviour of a quantum system, an effect for which we present a unified
description encompassing several previous proposals. We study the relevance of
clock errors in the Zeno effect, and find that generically no Zeno effect can
be present (in such a way that there is no contradiction with currently
available experimental data). We further observe that, within the class of
stochasticities in time addressed here, there is no modification in emission
lineshapes.Comment: 12 a4 pages, no figure
High-fidelity trapped-ion quantum logic using near-field microwaves
We demonstrate a two-qubit logic gate driven by near-field microwaves in a
room-temperature microfabricated ion trap. We measure a gate fidelity of
99.7(1)\%, which is above the minimum threshold required for fault-tolerant
quantum computing. The gate is applied directly to Ca "atomic clock"
qubits (coherence time ) using the microwave
magnetic field gradient produced by a trap electrode. We introduce a
dynamically-decoupled gate method, which stabilizes the qubits against
fluctuating a.c.\ Zeeman shifts and avoids the need to null the microwave
field
Microwave control electrodes for scalable, parallel, single-qubit operations in a surface-electrode ion trap
We propose a surface ion trap design incorporating microwave control
electrodes for near-field single-qubit control. The electrodes are arranged so
as to provide arbitrary frequency, amplitude and polarization control of the
microwave field in one trap zone, while a similar set of electrodes is used to
null the residual microwave field in a neighbouring zone. The geometry is
chosen to reduce the residual field to the 0.5% level without nulling fields;
with nulling, the crosstalk may be kept close to the 0.01% level for realistic
microwave amplitude and phase drift. Using standard photolithography and
electroplating techniques, we have fabricated a proof-of-principle electrode
array with two trapping zones. We discuss requirements for the microwave drive
system and prospects for scalability to a large two-dimensional trap array.Comment: 8 pages, 6 figure
Free motion time-of-arrival operator and probability distribution
We reappraise and clarify the contradictory statements found in the
literature concerning the time-of-arrival operator introduced by Aharonov and
Bohm in Phys. Rev. {\bf 122}, 1649 (1961). We use Naimark's dilation theorem to
reproduce the generalized decomposition of unity (or POVM) from any
self-adjoint extension of the operator, emphasizing a natural one, which arises
from the analogy with the momentum operator on the half-line. General time
operators are set within a unifying perspective. It is shown that they are not
in general related to the time of arrival, even though they may have the same
form.Comment: 10 a4 pages, no figure
Ambiguities of arrival-time distributions in quantum theory
We consider the definition that might be given to the time at which a
particle arrives at a given place, both in standard quantum theory and also in
Bohmian mechanics. We discuss an ambiguity that arises in the standard theory
in three, but not in one, spatial dimension.Comment: LaTex, 12 pages, no figure
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