Modification of the optical and structural properties of ZnO nanowires by low-energy Ar+ ion sputtering

The electronic version of this article is the complete one and can be found online at: http://link.springer.com/article/10.1186/1556-276X-8-162The effects of low-energy (≤2 kV) Ar+ irradiation on the optical and structural properties of zinc oxide (ZnO) nanowires (NWs) grown by a simple and cost-effective low-temperature technique were investigated. Both photoluminescence spectra from ZnO NW-coated films and cathodoluminescence analysis of individual ZnO NWs demonstrated obvious evidences of ultraviolet/visible luminescent enhancement with respect to irradiation fluence. Annihilation of the thinner ZnO NWs after the ion bombardment was appreciated by means of high-resolution scanning electron microscopy and transmission electron microscopy (TEM), which results in an increasing NW mean diameter for increasing irradiation fluences. Corresponding structural analysis by TEM pointed out not only significant changes in the morphology but also in the microstructure of these NWs, revealing certain radiation-sensitive behavior. The possible mechanisms accounting for the decrease of the deep-level emissions in the NWs with the increasing irradiation fluences are discussed according to their structural modificationsThis work has been supported by the MICINN (project no. MAT2010-15206) and the EU (COST Action MP0805

Re-using an oleic by-product in the manufacturing of fired clay bricks

Background: The high demand for building bricks underscores their essential role in the construction industry, which pushes researchers to continuously improve the characteristics of these products. This study aimed to investigate the impact of incorporating oleic components (Margins) in fired bricks manufacturing of by substituting water with different percentages of margins. Methods: Fired bricks were produced at the laboratory using clays taking from the Tangier region in northern Morocco. During this process, water used in the bricks production was substituted with margins in increasing percentages ranging from 10 % up to 30 %. To validate the results obtained from the physicochemical analyses performed on the manufactured bricks, three types of vegetable samples from three different regions of Morocco were utilized. Result: The study results are very remarkable, demonstrating a significant enhancement in compressive strength. The strength increased from 15.16 MPa for conventional bricks to 33.77 MPa for bricks manufactured with a 30 % substitution. Furthermore, porosity decreased from 33 % to 19 %. Conclusion: By integrating oleic components into the manufacturing process, we were able to achieve three main objectives.1. We have improved the characteristics of the bricks, which tend towards the load-bearing wall standards.2. We reduced the water quantity used in the bricks manufacturing by 30 %.3. We minimized the processing cost of the waste resulting from olive oil production, as well as its harmful effects on the environment

Advancing circular economy: A study of drinking water sludge for potential uses

The high demand for drinking water has increased the by-products from treatment plants, notably during coagulation-flocculation, leading to substantial sludges' accumulation. This study aims to focus on the characterization of drinking water treatment sludge (DWTS) batches from the three last years and statically studying it's uniformity, as exploring potential repurposing options. The samples were characterized using X-Ray Fluorescence (XRF), X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), Thermogravimetric Analysis (TGA), Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES), Loss On Ignition (LOI), and Granulometric analysis. The results evinced that DWTS have a sandy nature, the organic fraction takes third of the DWTS’ chemical composition, the amount of Al2O3 + SiO2 + Fe2O3 is slightly different, with 55.84, 57.47, and 56.14 % for DWTS21, DWTS22, and DWTS23 respectively, as per ANOVA results, which exhibited the consistency sludge composition among the samples, providing valuable insights into repurposing DWTS, and contributing to sustainable and eco-friendly practices in the construction industry especially DWTS21, which presents higher content of CaO with 2.95 %