Adaptation of Grid Tied Photovoltaic (GT-PV) System as Retrofit Renewable Energy Model for Single-Family House in UAE

Gulf Cooperation Countries (GCC) governments are encouraging advances in renewable energy and its deployment to reform domestic energy market policy. GCC countries including United Arab Emirates (UAE) all have begun to explore renewable energy technologies. This research intended to develop a framework model to use Grid Tied photovoltaic renewable energy (GT-PV) in the housing design of the GCC region particularly in UAE. In this regard, research has analyzed the various types of housing plans and worked out the possibilities of retrofit design to adapt renewable energy model to implement (GT-PV) in existing housing for their energy needs.  This study has determined the total energy need of each type of house, data of energy need was statically analyzed, and renewable energy output was calculated. The end result of research has surfaced a comprehensive model to design a grid-tied photovoltaic renewable energy system to cater the need for private housing in UAE

Mortality from gastrointestinal congenital anomalies at 264 hospitals in 74 low-income, middle-income, and high-income countries: a multicentre, international, prospective cohort study

Background: Congenital anomalies are the fifth leading cause of mortality in children younger than 5 years globally. Many gastrointestinal congenital anomalies are fatal without timely access to neonatal surgical care, but few studies have been done on these conditions in low-income and middle-income countries (LMICs). We compared outcomes of the seven most common gastrointestinal congenital anomalies in low-income, middle-income, and high-income countries globally, and identified factors associated with mortality. // Methods: We did a multicentre, international prospective cohort study of patients younger than 16 years, presenting to hospital for the first time with oesophageal atresia, congenital diaphragmatic hernia, intestinal atresia, gastroschisis, exomphalos, anorectal malformation, and Hirschsprung's disease. Recruitment was of consecutive patients for a minimum of 1 month between October, 2018, and April, 2019. We collected data on patient demographics, clinical status, interventions, and outcomes using the REDCap platform. Patients were followed up for 30 days after primary intervention, or 30 days after admission if they did not receive an intervention. The primary outcome was all-cause, in-hospital mortality for all conditions combined and each condition individually, stratified by country income status. We did a complete case analysis. // Findings: We included 3849 patients with 3975 study conditions (560 with oesophageal atresia, 448 with congenital diaphragmatic hernia, 681 with intestinal atresia, 453 with gastroschisis, 325 with exomphalos, 991 with anorectal malformation, and 517 with Hirschsprung's disease) from 264 hospitals (89 in high-income countries, 166 in middle-income countries, and nine in low-income countries) in 74 countries. Of the 3849 patients, 2231 (58·0%) were male. Median gestational age at birth was 38 weeks (IQR 36–39) and median bodyweight at presentation was 2·8 kg (2·3–3·3). Mortality among all patients was 37 (39·8%) of 93 in low-income countries, 583 (20·4%) of 2860 in middle-income countries, and 50 (5·6%) of 896 in high-income countries (p<0·0001 between all country income groups). Gastroschisis had the greatest difference in mortality between country income strata (nine [90·0%] of ten in low-income countries, 97 [31·9%] of 304 in middle-income countries, and two [1·4%] of 139 in high-income countries; p≤0·0001 between all country income groups). Factors significantly associated with higher mortality for all patients combined included country income status (low-income vs high-income countries, risk ratio 2·78 [95% CI 1·88–4·11], p<0·0001; middle-income vs high-income countries, 2·11 [1·59–2·79], p<0·0001), sepsis at presentation (1·20 [1·04–1·40], p=0·016), higher American Society of Anesthesiologists (ASA) score at primary intervention (ASA 4–5 vs ASA 1–2, 1·82 [1·40–2·35], p<0·0001; ASA 3 vs ASA 1–2, 1·58, [1·30–1·92], p<0·0001]), surgical safety checklist not used (1·39 [1·02–1·90], p=0·035), and ventilation or parenteral nutrition unavailable when needed (ventilation 1·96, [1·41–2·71], p=0·0001; parenteral nutrition 1·35, [1·05–1·74], p=0·018). Administration of parenteral nutrition (0·61, [0·47–0·79], p=0·0002) and use of a peripherally inserted central catheter (0·65 [0·50–0·86], p=0·0024) or percutaneous central line (0·69 [0·48–1·00], p=0·049) were associated with lower mortality. // Interpretation: Unacceptable differences in mortality exist for gastrointestinal congenital anomalies between low-income, middle-income, and high-income countries. Improving access to quality neonatal surgical care in LMICs will be vital to achieve Sustainable Development Goal 3.2 of ending preventable deaths in neonates and children younger than 5 years by 2030

Mortality from gastrointestinal congenital anomalies at 264 hospitals in 74 low-income, middle-income, and high-income countries: a multicentre, international, prospective cohort study

Summary Background Congenital anomalies are the fifth leading cause of mortality in children younger than 5 years globally. Many gastrointestinal congenital anomalies are fatal without timely access to neonatal surgical care, but few studies have been done on these conditions in low-income and middle-income countries (LMICs). We compared outcomes of the seven most common gastrointestinal congenital anomalies in low-income, middle-income, and high-income countries globally, and identified factors associated with mortality. Methods We did a multicentre, international prospective cohort study of patients younger than 16 years, presenting to hospital for the first time with oesophageal atresia, congenital diaphragmatic hernia, intestinal atresia, gastroschisis, exomphalos, anorectal malformation, and Hirschsprung’s disease. Recruitment was of consecutive patients for a minimum of 1 month between October, 2018, and April, 2019. We collected data on patient demographics, clinical status, interventions, and outcomes using the REDCap platform. Patients were followed up for 30 days after primary intervention, or 30 days after admission if they did not receive an intervention. The primary outcome was all-cause, in-hospital mortality for all conditions combined and each condition individually, stratified by country income status. We did a complete case analysis. Findings We included 3849 patients with 3975 study conditions (560 with oesophageal atresia, 448 with congenital diaphragmatic hernia, 681 with intestinal atresia, 453 with gastroschisis, 325 with exomphalos, 991 with anorectal malformation, and 517 with Hirschsprung’s disease) from 264 hospitals (89 in high-income countries, 166 in middleincome countries, and nine in low-income countries) in 74 countries. Of the 3849 patients, 2231 (58·0%) were male. Median gestational age at birth was 38 weeks (IQR 36–39) and median bodyweight at presentation was 2·8 kg (2·3–3·3). Mortality among all patients was 37 (39·8%) of 93 in low-income countries, 583 (20·4%) of 2860 in middle-income countries, and 50 (5·6%) of 896 in high-income countries (p<0·0001 between all country income groups). Gastroschisis had the greatest difference in mortality between country income strata (nine [90·0%] of ten in lowincome countries, 97 [31·9%] of 304 in middle-income countries, and two [1·4%] of 139 in high-income countries; p≤0·0001 between all country income groups). Factors significantly associated with higher mortality for all patients combined included country income status (low-income vs high-income countries, risk ratio 2·78 [95% CI 1·88–4·11], p<0·0001; middle-income vs high-income countries, 2·11 [1·59–2·79], p<0·0001), sepsis at presentation (1·20 [1·04–1·40], p=0·016), higher American Society of Anesthesiologists (ASA) score at primary intervention (ASA 4–5 vs ASA 1–2, 1·82 [1·40–2·35], p<0·0001; ASA 3 vs ASA 1–2, 1·58, [1·30–1·92], p<0·0001]), surgical safety checklist not used (1·39 [1·02–1·90], p=0·035), and ventilation or parenteral nutrition unavailable when needed (ventilation 1·96, [1·41–2·71], p=0·0001; parenteral nutrition 1·35, [1·05–1·74], p=0·018). Administration of parenteral nutrition (0·61, [0·47–0·79], p=0·0002) and use of a peripherally inserted central catheter (0·65 [0·50–0·86], p=0·0024) or percutaneous central line (0·69 [0·48–1·00], p=0·049) were associated with lower mortality. Interpretation Unacceptable differences in mortality exist for gastrointestinal congenital anomalies between lowincome, middle-income, and high-income countries. Improving access to quality neonatal surgical care in LMICs will be vital to achieve Sustainable Development Goal 3.2 of ending preventable deaths in neonates and children younger than 5 years by 2030

Removal of bromate ions from aqueous solutions via electrodeionization

Bromate (BrO3−) is a disinfection byproduct formed during the chemical oxidation of water containing bromide. Due to the carcinogenic effect of bromate, its maximum permissible concentration in drinking water has been set to 10 μg/L by the World Health Organization. In this study, the removal of BrO3− ions from aqueous solutions via electrodeionization (EDI) was investigated. The removal rate of BrO3− varied with the applied potential, and at 10 V, a removal rate of 99% was achieved. However, further increasing the applied potential to 30 V had a negative effect on the removal rate. Additionally, a low bromate concentration in the product water was achieved by reducing Na2SO4 conductivity in the electrode compartment. The removal of BrO3− is pH dependent, and at pH 1, only 17.5% was removed. However, increasing the pH of the solution to 5 increased the removal rate to 99.6%. Increasing the operating time and number of cells in the EDI stack improved the removal rate of BrO3−, and its concentration decreased from 5 mg/L to 1.4 μg/L. The calculated flux for BrO3− was 2.17 × 10−5 mol/m2s, specific power consumption was 89.98-W/hg KBrO3, and mass-transfer coefficient was 5.4 × 10−4 m/s at 10 V. © 2023 Elsevier LtdFM-YLT-202022-24162; Ege Üniversites

Removal of tripolyphospate from water by ion exchange resins

WOS: 000415822300031In this paper, two different ion-exchange resins namely strongly basic Purolite A420S and hybrid anion exchange resin infused with iron oxide, Purolite FerrIX A33E, were evaluated for the removal of tripolyphosphate (TPP) from an aqueous medium. Resins were compared in terms of their TPP removal capacity, kinetics, and regeneration efficiency under batch conditions. The results of batch experiments show that the maximum adsorption capacities were 256.91 mg-TPP/g-resin for A420S and 222.32 mg-TPP/g-resin for FerrIX A33E resin. The sorption kinetics of TPP onto A420S is well governed by the pseudo-first-order kinetic model, and pseudo-second-order model for FerrIX A33E resin. Sorption isotherm data were well described by the Langmuir model for the resins. The regeneration studies were also examined for such resins and obtained results showed that FerrIX A33E resin can be fully regenerated with 1 M NaCl and A420S resin can be regenerated with 4 M HCl with 95% efficiency. It was also found that, the percentage removal of TPP was maintained at more than 85% as compared to the initial value, even after five sorption-regeneration cycles. Thermodynamic studies showed that the sorption of TPP onto ion exchange resins is an exothermic process. The negative values of free energy change (Delta G(0)) indicate the spontaneous nature of the sorption process

Removal of Antimony(III) and Antimony(V) from water samples through water-soluble polymer-enhanced ultrafiltration

Addressing antimony (Sb) contamination, which is caused by the use of Sb compounds in various industries, is crucial. This study aims to compare two different Sb removal mechanisms: ion exchange and chelation. There-fore, two different water-soluble polymers-glycidyl methacrylate-N-methyl-D-glucamine and poly 2-(acryl-oyloxy)ethyl trimethylammonium chloride-were synthesized and used to remove Sb(III) and Sb(V) using the polymer-enhanced ultrafiltration (PEUF) method. The removal of Sb(III) was pH-dependent and extremely difficult at a pH of 1.2. However, when the pH of the solution was increased to 11, the Sb(III) removal rate increased to 77%. The Sb(III) removal rate was 28% at an Sb(III):polymer mole ratio of 1:5, which increased to 77% at a mole ratio of 1:20. Sb(III) removal was discovered to be unaffected by the low concentrations of Na+, K+, Ca2+, and Mg2+ ions in the solution, maintaining a Sb(III) removal rate of 77%. The test parameters showed different characteristics for Sb(V) removal. Increasing the pH of the solution from 1 to 9 correspondingly increased the removal rate from 0% to 45%, but increasing it further to 11 decreased the removal rate to 14%. The removal rate of Sb(V) was 67% at a Sb(V):polymer mole ratio of 1:60. Sb(V) removal was discovered to be unaffected by low concentrations of SO42-, NO3-, and PO43- anions in the solution. However, notably, the Sb(V) removal rate decreased from 67% to 58% in the presence of Cl ions. The results demonstrate that Sb removal via chelation was more effective than by ion exchange, and it remained unaffected by the presence of interfering ions.Scientific Research Projects Coordination Office of Ege University [FGA -2019-20716]; Ege University Planning and Monitoring Coordination of Organizational Development and Directorate of Library and DocumentationThis study is supported by the Scientific Research Projects Coordination Office of Ege University (project number: FGA -2019-20716) . We are grateful to Ege University Planning and Monitoring Coordination of Organizational Development and Directorate of Library and Documentation for their support in editing and proofreading this paper

Removal of boron from aqueous solution by modified cellulose

Cellulose is a promising alternative material as a sorbent for the removal of pollutants. The availability of hydroxyl groups on cellulose allows for the application of various modification reactions for the development of novel sorbents with different functional groups. In this work, a cellulose sorbent modified with N-methyl-glucamine was prepared and tested for the removal of boron. A batch adsorption process was used to further explore the boron sorption kinetics, isotherms, thermodynamics, mechanism, and reuse of the prepared sorbent. It was found that the optimum sorbent dose for boron removal was 0.2 g/25 mL. Moreover, the initial pH of the solution was found to affect the removal rate and was found to be >= 4. The sorption of boron reached equilibrium within 60 min. The maximum sorption capacity was calculated to be 4.7 mg B/g sorbent. The sorption process was found to be exothermic and the negative value of increment S in the range of 30-60 degrees C is related to a decrease in randomness at the solid/solution interface during the sorption of boron on the sorbent. The sorption/regeneration experiments have shown that the removal rate of the sorbent remains the same over 5 cycles.Ege University [FLP-2020-22167]This study is supported by Ege University Scientific Research Projects Coordination Unit (Project Number: FLP-2020-22167).; Ege Universitesi,FLP-2020-22167,Ozgur Ara

Predictive modeling for breast cancer based on machine learning algorithms and features selection methods

Breast cancer is one of the leading causes of death among women worldwide. However, early prediction of breast cancer plays a crucial role. Therefore, strong needs exist for automatic accurate early prediction of breast cancer. In this paper, machine learning (ML) classifiers combined with features selection methods are used to build an intelligent tool for breast cancer prediction. The Wisconsin diagnostic breast cancer (WDBC) dataset is used to train and test the model. Classification algorithms, including support vector machine (SVM), light gradient boosting machine (LightGBM), random forest (RF), logistic regression (LR), k-nearest neighbors (k-NN), and naïve Bayes, were employed. Performance measures for each of them were obtained, namely: accuracy, precision, recall, F-score, Kappa, Matthews correlation coefficient (MCC), and time. The results indicate that without feature selection, LightGBM achieves the highest accuracy at 95%. With minimum redundancy maximum relevance (mRMR) feature selection (15 features), LightGBM outperforms other classifiers, achieving an accuracy of 98%. For Pearson correlation coefficient feature selection (15 features), LightGBM also excels with a 95% accuracy rate. Lasso feature selection (5 features) produces varied results across classifiers, with logistic regression achieving the highest accuracy at 96%. These findings underscore the importance of feature selection in refining model performance and in improving detection for breast cancer