Ions at the air-water interface: An end to one hundred year old mystery?

Availability of highly reactive halogen ions at the surface of aerosols has tremendous implications for the atmospheric chemistry. Yet neither simulations, experiments, nor existing theories are able to provide a fully consistent description of the electrolyte-air interface. In this paper a new theory is proposed which allows us to explicitly calculate the ionic density profiles, the surface tension, and the electrostatic potential difference across the solution-air interface. Predictions of the theory are compared to experiments and are found to be in excellent agreement. The theory also sheds new light on one of the oldest puzzles of physical chemistry -- the Hofmeister effect

Non-renormalization for the Liouville wave function

Using an exact functional method, within the framework of the gradient expansion for the Liouville effective action, we show that the kinetic term for the Liouville field is not renormalized.Comment: 13 pages Latex, no figure

On soft capacities, quasi-stationary distributions and the pathwise approach to metastability

Motivated by the study of the metastable stochastic Ising model at subcritical temperature and in the limit of a vanishing magnetic field, we extend the notion of ($\kappa$, $\lambda$)-capacities between sets, as well as the associated notion of soft-measures, to the case of overlapping sets. We recover their essential properties, sometimes in a stronger form or in a simpler way, relying on weaker hypotheses. These properties allow to write the main quantities associated with reversible metastable dynamics, e.g. asymptotic transition and relaxation times, in terms of objects that are associated with two-sided variational principles. We also clarify the connection with the classical "pathwise approach" by referring to temporal means on the appropriate time scale.Comment: 29 pages, 1 figur