Efficiency of radial transport of ices in protoplanetary disks probed with infrared observations: the case of CO2_2

The efficiency of radial transport of icy solid material from outer disk to the inner disk is currently unconstrained. Efficient radial transport of icy dust grains could significantly alter the composition of the gas in the inner disk. Our aim is to model the gaseous CO$_2$ abundance in the inner disk and use this to probe the efficiency of icy dust transport in a viscous disk. Features in the simulated CO$_2$ spectra are investigated for their dust flux tracing potential. We have developed a 1D viscous disk model that includes gas and grain motions as well as dust growth, sublimation and freeze-out and a parametrisation of the CO$_2$ chemistry. The thermo-chemical code DALI was used to model the mid-infrared spectrum of CO$_2$, as can be observed with JWST-MIRI. CO$_2$ ice sublimating at the iceline increases the gaseous CO$_2$ abundance to levels equal to the CO$_2$ ice abundance of $\sim 10^{-5}$, which is three orders of magnitude more than the gaseous CO$_2$ abundances of $\sim 10^{-8}$ observed by Spitzer. Grain growth and radial drift further increase the gaseous CO$_2$ abundance. A CO$_2$ destruction rate of at least $10^{-11}$ s$^{-1}$ is needed to reconcile model prediction with observations. This rate is at least two orders of magnitude higher than the fastest known chemical destruction rate. A range of potential physical mechanisms to explain the low observed CO$_2$ abundances are discussed. Transport processes in disks can have profound effects on the abundances of species in the inner disk. The discrepancy between our model and observations either suggests frequent shocks in the inner 10 AU that destroy CO$_2$, or that the abundant midplane CO$_2$ is hidden from our view by an optically thick column of low abundance CO$_2$ in to the disk surface XDR/PDR. Other molecules, such as CH$_4$ or NH$_3$, can give further handles on the rate of mass transport.Comment: Accepted for publication in A&A, 18 pages, 13 figures, abstract abridge

The 50-horsepower solar-powered irrigation facility located near Gila Bend, Arizona

The 50 horsepower solar powered irrigation facility near Gila Bend, Arizona which includes a Rankine cycle demonstrates the technical feasibility of solar powered pumping. The design of a facility specifically for the irrigation farmer using the technology that has been developed over the last four years is proposed

Interstellar grain mantles

Interstellar molecular grain mantles are an important component of the interstellar dust inside dense molecular clouds as evidenced by the detection of absorption bands at 2.97, 3.08, 4.61, 6.0 and 6.8 microns. Mantles may also be the precursors of more complex grain mantles in the diffuse interstellar medium. The molecular composition of these icy grain mantles were calculated employing gas phase as well as grain surface reactions. The calculated mixtures consist mainly of the molecules H2O, H2CO, N2, CO, O2, H2O2, NH2, and their deuterated counterparts in varying ratios. The exact compositions depend strongly on the physical conditions in the gas phase. The absorption spectra of H2O with other molecules was studied in the laboratory. Optical constants were determined for a few selected mixtures. Extinction and polarization cross sections across the 3 micron ice band were calculated. A comparison with the observations towards BN shows that the low frequency wing observed on this feature is due to absorption by a mixture of H2O and other molecules rather than scattering by large, pure H2O ice grains

The Dark Matter Contribution to Galactic Diffuse Gamma Ray Emission

Observations of diffuse Galactic gamma ray emission (DGE) by the Fermi Large Area Telescope (LAT) allow a detailed study of cosmic rays and the interstellar medium. However, diffuse emission models of the inner Galaxy underpredict the Fermi-LAT data at energies above a few GeV and hint at possible non-astrophysical sources including dark matter (DM) annihilations or decays. We present a study of the possible emission components from DM using the high-resolution Via Lactea II N-body simulation of a Milky Way-sized DM halo. We generate full-sky maps of DM annihilation and decay signals that include modeling of the adiabatic contraction of the host density profile, Sommerfeld enhanced DM annihilations, $p$-wave annihilations, and decaying DM. We compare our results with the DGE models produced by the Fermi-LAT team over different sky regions, including the Galactic center, high Galactic latitudes, and the Galactic anti-center. This work provides possible templates to fit the observational data that includes the contribution of the subhalo population to DM gamma-ray emission, with the significance depending on the annihilation/decay channels and the Galactic regions being considered.Comment: Published by PR

High accuracy calculations of the rotation-vibration spectrum of H3+_3^+

Calculation of the rotation-vibration spectrum of H3+, as well as of its deuterated isotopologues, with near-spectroscopic accuracy requires the development of sophisticated theoretical models, methods, and codes. The present paper reviews the state-of-the-art in these fields. Computation of rovibrational states on a given potential energy surface (PES) has now become standard for triatomic molecules, at least up to intermediate energies, due to developments achieved by the present authors and others. However, highly accurate Born--Oppenheimer energies leading to highly accurate PESs are not accessible even for this two-electron system using conventional electronic structure procedures e.g., configuration-interaction or coupled-cluster techniques with extrapolation to the complete basis set limit). For this purpose highly specialized techniques must be used, e.g., those employing explicitly correlated Gaussians and nonlinear parameter optimizations. It has also become evident that a very dense grid of \ai\ points is required to obtain reliable representations of the computed points extending from the minimum to the asymptotic limits. Furthermore, adiabatic, relativistic, and QED correction terms need to be considered to achieve near-spectroscopic accuracy during calculation of the rotation-vibration spectrum of H3+. The remaining and most intractable problem is then the treatment of the effects of non-adiabatic coupling on the rovibrational energies, which, in the worst cases, may lead to corrections on the order of several \cm. A promising way of handling this difficulty is the further development of effective, motion- or even coordinate-dependent, masses and mass surfaces. Finally, the unresolved challenge of how to describe and elucidate the experimental pre-dissociation spectra of H$_3^+$ and its isotopologues is discussed.Comment: Topical review to be published in J Phys B: At Mol Opt Phy

Interactions of keV sterile neutrinos with matter

A sterile neutrino with mass of several keV is a well-motivated dark-matter candidate, and it can also explain the observed velocities of pulsars via anisotropic emission of sterile neutrinos from a cooling neutron star. We discuss the interactions of such relic particles with matter and comment on the prospects of future direct detection experiments. A relic sterile neutrino can interact, via sterile-active mixing, with matter fermions by means of electroweak currents, with the final state containing a relativistic active neutrino. The recoil momentum impacted onto a matter fermion is determined by the sterile neutrino mass and is enough to ionize atoms and flip the spins of nuclei. While this suggests a possibility of direct experimental detection, we calculate the rates and show that building a realistic detector of the required size would be a daunting challenge.Comment: 5 pages, 1 figur

The effect of disorder on the free-energy for the Random Walk Pinning Model: smoothing of the phase transition and low temperature asymptotics

We consider the continuous time version of the Random Walk Pinning Model (RWPM), studied in [5,6,7]. Given a fixed realization of a random walk Y$ on Z^d with jump rate rho (that plays the role of the random medium), we modify the law of a random walk X on Z^d with jump rate 1 by reweighting the paths, giving an energy reward proportional to the intersection time L_t(X,Y)=\int_0^t \ind_{X_s=Y_s}\dd s: the weight of the path under the new measure is exp(beta L_t(X,Y)), beta in R. As beta increases, the system exhibits a delocalization/localization transition: there is a critical value beta_c, such that if beta>beta_c the two walks stick together for almost-all Y realizations. A natural question is that of disorder relevance, that is whether the quenched and annealed systems have the same behavior. In this paper we investigate how the disorder modifies the shape of the free energy curve: (1) We prove that, in dimension d larger or equal to three 3, the presence of disorder makes the phase transition at least of second order. This, in dimension larger or equal to 4, contrasts with the fact that the phase transition of the annealed system is of first order. (2) In any dimension, we prove that disorder modifies the low temperature asymptotic of the free energy.Comment: 18 page