58 research outputs found
Vector meson quasinormal modes in a finite-temperature AdS/QCD model
We study the spectrum of vector mesons in a finite temperature plasma. The
plasma is holographically described by a black hole AdS/QCD model. We compute
the boundary retarded Green's function using AdS/CFT prescriptions. The
corresponding thermal spectral functions show quasiparticle peaks at low
temperatures. Then we calculate the quasinormal modes of vector mesons in the
soft-wall black hole geometry and analyse their temperature and momentum
dependences.Comment: 27 pages, 9 figure
Ultrafast Charge Carrier Dynamics in Vanadium-Modified TiO2 Thin Films and Its Relation to Their Photoelectrocatalytic Efficiency for Water Splitting
Light absorption and charge transport in oxide semiconductors can be tuned by the introduction, during deposition, of a small quantity of foreign elements, leading to the improvement of the photoelectrocatalytic performance. In this work, both unmodified and vanadium-modified TiO2 thin films deposited by radio-frequency magnetron sputtering are investigated as photoanodes for photoelectrochemical water splitting. Following a structural characterization by X-ray diffraction, atomic force microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy, photoelectrocatalysis is discussed based on ultrafast transient absorbance spectroscopy measurements. In particular, three different pump wavelengths from UV to the visible range are used (300, 390, and 530 nm) in order to cover the relevant photoactive spectral range of modified TiO2. Incident photon-to-current conversion efficiency spectra show that incorporation of vanadium in TiO2 extends water splitting in the visible range up to approximate to 530 nm, a significant improvement compared to unmodified TiO2 that is active only in the UV range less than or similar to 390 nm. However, transient absorbance spectroscopy clearly reveals that vanadium accelerates electron-hole recombination upon UV irradiation, resulting in a lower photon-to-current conversion efficiency in the UV spectral range with respect to unmodified TiO2. The new photoelectrocatalytic activity in the visible range is attributed to a V-induced introduction of intragap levels at approximate to 2.2 eV below the bottom of the conduction band. This is confirmed by long-living transient signals due to electrons photoexcited into the conduction band after visible light (530 nm) pulses. The remaining holes migrate to the semiconductor-electrolyte interface where they are captured by long-lived traps and eventually promote water oxidation under visible light
Charging Station for Electric Bikes Powered by Renewable Energy
This report serves the purpose to answer the research problem of developing a charging station for electric bicycles powered by renewable energy allowing rental companies to create a safer and more sustainable way of commuting. The report was divided into a business and a mechanical part to provide a better overview of each area of operations. The business part focuses on the establishment of the company, SolHavn, the analysis of market environment and customers, as well as the creation of a suitable marketing strategy, and the projection of the expected financial positioning of the company. On the other hand, the mechanical part demonstrates the correct and accurate method to dimension and design a solar charging station that capable of charging 10 electric bike according to appropriate mechanical calculation, assumption and analysis realized. The value of the energy consumption was estimated for the off-grid situation primarily and it mainly focus on the worst case scenario season in Barcelona, Spain. Moreover, the consideration of losses that would happen in electrical cabling and other electronic related component like step-down, charge controller and other was taken into account. Finally, the structural design for the station as demonstrated and would be able to support the load of chosen solar panel and other natural loads after detailed calculation. Besides, other simulation which involved other scenario like hybrid and on-grid was considered and analyzed. The comparison between these other scenarios helped in improving the solar station for further project.<br /
Black-hole quasinormal modes and scalar glueballs in a finite-temperature AdS/QCD model
We use the holographic AdS/QCD soft-wall model to investigate the spectrum of
scalar glueballs in a finite temperature plasma. In this model, glueballs are
described by a massless scalar field in an AdS_5 black hole with a dilaton
soft-wall background. Using AdS/CFT prescriptions, we compute the boundary
retarded Green's function. The corresponding thermal spectral function shows
quasiparticle peaks at low temperatures. We also compute the quasinormal modes
of the scalar field in the soft-wall black hole geometry. The temperature and
momentum dependences of these modes are analyzed. The positions and widths of
the peaks of the spectral function are related to the frequencies of the
quasinormal modes. Our numerical results are found employing the power series
method and the computation of Breit-Wigner resonances.Comment: Revision: Results unchanged. More discussions on the model and on the
results. References added. 28 pages, 7 figures, 5 table
Chiral symmetry breaking from five dimensional spaces
Based on the AdS/CFT correspondence we study the breaking of the chiral
symmetry in QCD using a simple five dimensional model. The model gives definite
predictions for the spectrum of vector mesons, their decay constants and
interactions as a function of one parameter related to the quark condensate. We
calculate the coefficients of the low-energy QCD chiral lagrangian, as
well as other physical quantities for the pions. All the predictions are shown
to be in good agreement with the experimental data. We also show that they are
robust under modifications of the 5D metric in the IR, and that some of them
arise as a consequence of the higher-dimensional gauge symmetry. For example,
at the tree-level, we find ,
and BR(.Comment: 20 pages, 5 figure
Benchmarking of graphene-based materials: Real commercial products versus ideal graphene
There are tens of industrial producers claiming to sell graphene and related materials (GRM), mostly as solid powders. Recently the quality of commercial GRM has been questioned, and procedures for GRM quality control were suggested using Raman Spectroscopy or Atomic Force Microscopy. Such techniques require dissolving the sample in solvents, possibly introducing artefacts. A more pragmatic approach is needed, based on fast measurements and not requiring any assumption on GRM solubility. To this aim, we report here an overview of the properties of commercial GRM produced by selected companies in Europe, USA and Asia. We benchmark: (A) size, (B) exfoliation grade and (C) oxidation grade of each GRM versus the ones of \u27ideal\u27 graphene and, most importantly, versus what reported by the producer. In contrast to previous works, we report explicitly the names of the GRM producers and we do not re-dissolve the GRM in solvents, but only use techniques compatible with industrial powder metrology. A general common trend is observed: Products having low defectivity (%sp 2 bonds >95%) feature low surface area (<200 m 2 g -1 ), while highly exfoliated GRM show a lower sp 2 content, demonstrating that it is still challenging to exfoliate GRM at industrial level without adding defects
Mesoscopic 3D Charge Transport in Solution-Processed Graphene-Based Thin Films: A Multiscale Analysis
Graphene and related 2D material (GRM) thin films consist of 3D assembly of billions of 2D nanosheets randomly distributed and interacting via van der Waals forces. Their complexity and the multiscale nature yield a wide variety of electrical characteristics ranging from doped semiconductor to glassy metals depending on the crystalline quality of the nanosheets, their specific structural organization ant the operating temperature. Here, the charge transport (CT) mechanisms are studied that are occurring in GRM thin films near the metal-insulator transition (MIT) highlighting the role of defect density and local arrangement of the nanosheets. Two prototypical nanosheet types are compared, i.e., 2D reduced graphene oxide and few-layer-thick electrochemically exfoliated graphene flakes, forming thin films with comparable composition, morphology and room temperature conductivity, but different defect density and crystallinity. By investigating their structure, morphology, and the dependence of their electrical conductivity on temperature, noise and magnetic-field, a general model is developed describing the multiscale nature of CT in GRM thin films in terms of hopping among mesoscopic bricks, i.e., grains. The results suggest a general approach to describe disordered van der Waals thin films
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