Energy-dependent spatial texturing of the charge order in 1T1T-Cux_xTiSe2_2

We report a detailed study of the microscopic effects of Cu intercalation on the charge density wave (CDW) in 1\textit{T}-Cu$_x$TiSe$_2$. Scanning tunneling microscopy and spectroscopy (STM/STS) reveal a unique, Cu driven spatial texturing of the charge ordered phase, with the appearance of energy dependent CDW patches and sharp $\pi$-phase shift domain walls ($\pi$DWs). The energy and doping dependencies of the patchwork are directly linked to the inhomogeneous potential landscape due to the Cu intercalants. They imply a CDW gap with unusual features, including a large amplitude, the opening below the Fermi level and a shift to higher binding energy with electron doping. Unlike the patchwork, the $\pi$DWs occur independently of the intercalated Cu distribution. They remain atomically sharp throughout the investigated phase diagram and occur both in superconducting and non-superconducting specimen. These results provide unique atomic-scale insight on the CDW ground state, questioning the existence of incommensurate CDW domain walls and contributing to understand its formation mechanism and interplay with superconductivity

Dimensional cross-over of the charge density wave order parameter in thin exfoliated 1T-VSe2_2

The capability to isolate one to few unit-cell thin layers from the bulk matrix of layered compounds opens fascinating prospects to engineer novel electronic phases. However, a comprehensive study of the thickness dependence and of potential extrinsic effects are paramount to harness the electronic properties of such atomic foils. One striking example is the charge density wave (CDW) transition temperature in layered dichalcogenides whose thickness dependence remains unclear in the ultrathin limit. Here we present a detailed study of the thickness and temperature dependences of the CDW in VSe$_2$ by scanning tunnelling microscopy (STM). We show that mapping the real-space CDW periodicity over a broad thickness range unique to STM provides essential insight. We introduce a robust derivation of the local order parameter and transition temperature based on the real space charge modulation amplitude. Both quantities exhibit a striking non-monotonic thickness dependence that we explain in terms of a 3D to 2D dimensional crossover in the FS topology. This finding highlights thickness as a true tuning parameter of the electronic ground state and reconciles seemingly contradicting thickness dependencies determined in independent transport studies

Holographic imaging of the complex charge density wave order parameter

The charge density wave (CDW) in solids is a collective ground state combining lattice distortions and charge ordering. It is defined by a complex order parameter with an amplitude and a phase. The amplitude and wavelength of the charge modulation are readily accessible to experiment. However, accurate measurements of the corresponding phase are significantly more challenging. Here we combine reciprocal and real space information to map the full complex order parameter based on topographic scanning tunneling microscopy (STM) images. Our technique overcomes limitations of earlier Fourier space based techniques to achieve distinct amplitude and phase images with high spatial resolution. Applying this analysis to transition metal dichalcogenides provides striking evidence that their CDWs consist of three individual charge modulations whose ordering vectors are connected by the fundamental rotational symmetry of the crystalline lattice. Spatial variations in the relative phases of these three modulations account for the different contrasts often observed in STM topographic images. Phase images further reveal topological defects and discommensurations, a singularity predicted by theory for a nearly commensurate CDW. Such precise real space mapping of the complex order parameter provides a powerful tool for a deeper understanding of the CDW ground state whose formation mechanisms remain largely unclear

Subharmonic gap structures and Josephson effect in MgB2/Nb micro-constrictions

Superconducting micro-constrictions between Nb tips and high quality MgB$_{2}$ pellets have been realized by means of a point-contact inset, driven by a micrometric screw. Measurements of the current-voltage characteristics and of the dynamical conductance versus bias have been performed in the temperature range between 4.2 K and 500 K. Above the Nb critical temperature T$_{C}^{Nb}$, the conductance of the MgB$_2$/normal-metal constrictions behaves as predicted by the BTK model for low resistance contacts while high resistance junctions show quasiparticle tunneling characteristics. Consistently, from the whole set of data we infer the value $\Delta_{\pi} = 2.5 \pm 0.2$ meV for the three-dimensional gap of MgB$_2$. Below T$_{C}^{Nb}$, low resistance contacts show Josephson current and subharmonic gap structures (SGS), due to multiple Andreev reflections. Simultaneous observations of both features, unambiguously indicate coupling of the 3D band of MgB$_2$ with the Nb superconducting order parameter. We found that the temperature dependence of the Josephson critical current follows the classical Ambegaokar-Baratoff behavior with a value $I_CR_N=(2.1 \pm 0.1)$ meV at low temperatures.Comment: 8 pages, 5 figures. Replaced with published versio

Point Contact Spectra on YBa2_2Cu3_3O7−x_{7-x}/La0.7_{0.7}Ca0.3_{0.3}MnO3_3 bilayers

We present conductance characteristics of point contact junctions realized between a normal Pt-Ir tip and YBa$_2$Cu$_3$O$_{7-x}$/La$_{0.7}$Ca$_{0.3}$MnO$_3$ (YBCO/LCMO) bilayers. The point contact characteristics show a zero bias conductance peak, as a consequence of the formation of Andreev bound states at the YBCO Fermi level. The temperature evolution of the spectra reveals a depressed zero bias peak and a reduced superconducting energy gap, both explainable in terms of spin polarization effects due to the LCMO layer.Comment: 4 pages, 4 EPS figures. Proceedings of EUCAS 2005. Accepted in Journal of Physics: Conference Serie

Towards surface diffusion potential mapping on atomic length scale

The surface diffusion potential landscape plays an essential role in a number of physical and chemical processes such as self-assembly and catalysis. Diffusion energy barriers can be calculated theoretically for simple systems, but there is currently no experimental technique to systematically measure them on the relevant atomic length scale. Here, we introduce an atomic force microscopy based method to semiquantitatively map the surface diffusion potential on an atomic length scale. In this proof of concept experiment, we show that the atomic force microscope damping signal at constant frequency-shift can be linked to nonconservative processes associated with the lowering of energy barriers and compared with calculated single-atom diffusion energy barriers.Comment: 8 pages and 3 figure

Adsorption Behavior of Asymmetric Pd Pincer Complexes on a Cu(111) Surface

We address the adsorption of asymmetric Pd pincer complexes on a Cu(111) surface by scanning tunneling microscopy. The structural asymmetry is manifested in the observation of two chiral enantiomers. To enable an unambiguous identification of individual constituents, three closely related complexes with small modifications are investigated in parallel. Thereby, methyl substituents determine attractive molecule-molecule interaction. Depending on their distribution, dimerization and tetramerization can be observed

Imaging the spontaneous formation of vortex-antivortex pairs in planar superconductor/ferromagnet hybrid structures

Low-temperature magnetic force microscopy has been used to visualize spontaneous formation of vortex-antivortex pairs in hybrid ferromagnet/superconductor systems. Vortex-antivortex pairs are induced by the periodic stray field of the ferromagnet. We find general equilibrium conditions for which spontaneous vortex-antivortex pairs are formed during zero-field cooling of the hybrid ferromagnet/superconductor bilayers. Vortices can be generated by the ferromagnet domains in the absence of an external field and they are thermodynamically stable for values of the stray field and the period of the stripe magnetic domains that exceed a certain threshold