Cap rock efficiency of geothermal systems in fold-and-thrust belts: Evidence from paleo-thermal and structural analyses in Rosario de La Frontera geothermal area (NW Argentina)

Cap rock characterization of geothermal systems is often neglected despite fracturing may reduce its efficiency and favours fluid migration. We investigated the siliciclastic cap rock of Rosario de La Frontera geothermal system (NW Argentina) in order to assess its quality as a function of fracture patterns and related thermal alteration. Paleothermal investigations (XRD on fine-grained fraction of sediments, organic matter optical analysis and fluid inclusions on veins) and 1D thermal modelling allowed us to distinguish the thermal fingerprint associated to sedimentary burial from that related to fluid migration. The geothermal system is hosted in a Neogene N-S anticline dissected by high angle NNW- and ENE-striking faults. Its cap rock can be grouped into two quality categories: • rocks acting as good insulators, deformed by NNW–SSE and E–W shear fractures, NNE-SSW gypsum- and N-S-striking calcite-filled veins that developed during the initial stage of anticline growth. Maximum paleo-temperatures (< 60 °C) were experienced during deposition to folding phases.• rocks acting as bad insulators, deformed by NNW-SSE fault planes and NNW- and WNW-striking sets of fractures associated to late transpressive kinematics. Maximum paleo-temperatures higher than about 115 °C are linked to fluid migration from the reservoir to surface (with a reservoir top at maximum depths of 2.5 km) along fault damage zones.This multi-method approach turned out to be particularly useful to trace the main pathways of hot fluids and can be applied in blind geothermal systems where either subsurface data are scarce or surface thermal anomalies are lacking.Fil: Maffucci, R.. Universita Degli Studi Della Tuscia; Italia. Universita Degli Studi Roma Tre; ItaliaFil: Corrado, Sveva. Universita Degli Studi Roma Tre; ItaliaFil: Aldega, L.. Instituto de Investigaciones Universitarias Roma la Sapienza; ItaliaFil: Bigi, S.. Instituto de Investigaciones Universitarias Roma la Sapienza; ItaliaFil: Chiodi, Agostina Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones en Energía no Convencional. Universidad Nacional de Salta. Facultad de Ciencias Exactas. Departamento de Física. Instituto de Investigaciones en Energía no Convencional; ArgentinaFil: Di Paolo, L.. Eni E&P Division; ItaliaFil: Giordano, G.. Universita Degli Studi Roma Tre; ItaliaFil: Invernizzi, C.. Universita Degli Di Camerino; Itali

Base cation mobility in vineyard soils of the Colli Albani volcanic district (Central Italy)

The quality of the Colli Albani volcanic soils has certainly contributed to the vine cultivars hence the name of one of the oldest wines (i.e., Alban wine). The alkali up to 15 wt%, SiO2 ≤ 52 wt% and the emplacement at high temperature (≤ 600 °C) are the bedrock features that have deeply influenced the soil-forming processes in the vineyards. However, the peculiar features of the Colli Albani soils are not well known. Field survey and textural, mineralogical, and chemical data obtained with SEM, EMP, XRD, and ICP-OES were used to characterize the vineyard soils of the Colli Albani. Leucite (Lct)-bearing soils and quartz (Qz)-bearing soils occur in the studied vineyard. The Qz-bearing soils represent more weathered volcanic material, depleted in primary minerals and enriched in clays, which show a lower cation exchange capacity (CEC) than the Lct-bearing soils. CEC is a misleading definition for the Colli Albani soils because the base cation mobility in the vineyard is independent from clay mineral enrichment in the soil. Actually, the release of K, Na, Ca, and Mg depends by (i) the complete dissolution of leucite and analcime, (ii) the oxy-reaction affecting the phlogopite, which releases K + Mg, and (iii) the incongruent dissolution of clinopyroxene characterized by the “gothic texture.” This texture highlights the capacity of clinopyroxene to release Ca and Mg in volcanic soils. Quantification of the texture and abundance of the primary minerals are mandatory for the management of the vineyard soils in the Colli Albani and, in general, it is significative for the vineyards in volcanic areas

Unraveling Multiple Thermotectonic Events Accommodated by Crustal\u2010Scale Faults in Northern Iberia, Spain: Insights From K-Ar Dating of Clay Gouges

Large-scale faults in the continental crust are significant features that control the evolution of sedimentary basins and intraplate mountain chains. Deciphering their evolution is a significant task because faults slip and reactivate in a variety of geological settings. In this work, clay gouges of two major orogen-scale, long-lived faults in northern Iberia, the Río Grío and Vallès-Penedès Faults, were investigated by X-ray diffraction and K-Ar isotopic analysis. Illite polytype determinations of 44 subfractions (from <0.1 to 10 Œºm) allowed us to discriminate between authigenic/synkinematic illite crystals formed during faulting and detrital illite crystals inherited from the host rock. K-Ar dating provided a detailed set of ages corresponding to key stages of the thermotectonic evolution of the Iberian Plate: (a) the Permian to Late Triassic extensional/transtensional activity associated to the emplacement of Late Variscan magmatic bodies and hydrothermal mineralizations, (b) the opening of the Central Atlantic Rift during Late Triassic-Early Jurassic times, (c) the Late Jurassic-Early Cretaceous rifting that led to the development of Mesozoic extensional/transtensional basins in northern Iberia, (d) the final stage of the anticlockwise rotation of the Iberian Plate with respect to Eurasia and the accommodation of the first Pyrenean compressional pulses in Campanian time, and (e) the positive inversion of Mesozoic extensional basins due to far-field stresses associated with the Alpine orogeny during the Paleogene. The results highlight that thermotectonic conditions characterized by high-geothermal gradients strongly favor fault movement and neoformation of clay minerals in fault gouges, regardless of the prevailing tectonic regime

Cap rock efficiency of geothermal systems in fold-and-thrust belts:evidence from paleo-thermal and structural analyses in Rosario de La Frontera geothermal area (NW Argentina)

Cap rock characterization of geothermal systems is often neglected despite fracturing may reduce its efficiency and favours fluid migration. We investigated the siliciclastic cap rock of Rosario de La Frontera geothermal system (NW Argentina) in order to assess its quality as a function of fracture patterns and related thermal alteration. Paleothermal investigations (XRD on fine-grained fraction of sediments, organic matter optical analysis and fluid inclusions on veins) and 1D thermal modelling allowed us to distinguish the thermal fingerprint associated to sedimentary burial from that related to fluid migration. The geothermal system is hosted in a Neogene N-S anticline dissected by high angle NNW- and ENE-striking faults. Its cap rock can be grouped into two quality categories: ● rocks acting as good insulators deformed by NNW–SSE and E–W shear fractures, NNE-SSW gypsum- and N-S striking calcite-filled veins formed during the initial stage of anticline growth. Maximum paleo-temperatures (<60°C) were experienced during deposition to folding phases. ● rocks acting as bad insulators deformed by NNW-SSE fault planes and NNW- and WNW-striking sets of fractures associated to late transpressive kinematics. Maximum paleo-temperatures higher than about 115°C are linked to fluid migration from the reservoir to surface (with a reservoir top at maximum depths of 2.5 km) along fault damage zones. This multi-method approach turn out to be particularly useful to trace the main pathways of hot fluids and can be applied in blind geothermal systems where either subsurface data are scarce or surface thermal anomalies are lacking

Structural characterization and K–Ar illite dating of reactivated, complex and heterogeneous fault zones: lessons from the Zuccale Fault, Northern Apennines

We studied the Zuccale Fault (ZF) on Elba, part of the Northern Apennines, to unravel the complex deformation history that is responsible for the remarkable architectural complexity of the fault. The ZF is characterized by a patchwork of at least six distinct, now tightly juxtaposed brittle structural facies (BSF), i.e. volumes of deformed rock characterized by a given fault rock type, texture, colour, composition, and age of formation. ZF fault rocks vary from massive cataclasite to foliated ultracataclasite, from clay-rich gouge to highly sheared talc phyllonite. Understanding the current spatial juxtaposition of these BSFs requires tight constraints on their age of formation during the ZF lifespan to integrate current fault geometries and characteristics over the time dimension of faulting. We present new K–Ar gouge dates obtained from three samples from two different BSFs. Two top-to-the-east foliated gouge and talc phyllonite samples document faulting in the Aquitanian (ca. 22 Ma), constraining east-vergent shearing along the ZF already in the earliest Miocene. A third sample constrains later faulting along the exclusively brittle, flat-lying principal slip surface t

Architecture and permeability structure of the Sibillini Mts. Thrust and influence upon recent, extension-related seismicity in the central Apennines (Italy) through fault-valve behavior

The central Apennines are a fold-thrust belt currently affected by post-orogenic ex-tensional seismicity. To constrain the influ-ence that the inherited thrust-related struc-tures exert on the present seismic behavior of the belt, we provide the high-resolution structural and hydraulic characterization of one of the most external exposed thrust fault systems of the central Apennines, the Sibil-lini Mts. Thrust Front (STF). We integrate structural mapping, multiscale structural analysis, and in situ air permeability on the brittle structural facies of the thrust zone. We also performed K-Ar dating of selected fault rocks to better constrain structural in-heritance. The STF is defined by a complex, similar to 300-m-thick deformation zone involving Meso-Cenozoic marl and limestone that re-sults from the accommodation of both seis-mic and aseismic slip during shortening. Permeability measurements indicate that the low permeability (10-2 divided by 10-3 D) of the marly rich host rock diminishes within the thrust zone, where the principal slip surfaces and associated S-C structures represent efficient hydraulic barriers (permeability down to similar to 3 x 10-10 D) to sub-vertical fluid flow. Field data and K-Ar dating indicate that the STF began its evolution ca. 7 Ma (early Messin-ian). We suggest that the studied thrust zone may represent a barrier for the upward migration of deep fluids at the hypocentral depth of present-day extensional earth-quakes. We also speculate on the influence that similar deformation zones may have at depth on the overall regional seismotectonic pattern by causing transient fluid overpres-sures and, possibly, triggering cyclic exten-sional earthquakes on normal faults prone to slip while crosscutting the earlier thrust zones (as per a classic fault valve behavior). This mechanism may have controlled the ori-gin of the 2016-2017 central Apennines dev-astating earthquakes

An integrated structural and magnetic fabric study to constrain the progressive extensional tectonics of the Rio do Peixe Basin, Brazil

We constrained the tectonic evolution of the intracratonic Cretaceous Rio do Peixe Basin (RPB) in NE Brazil, combining structural and Anisotropy of Magnetic Susceptibility (AMS) data. We analyzed the structural features of four sites along two major faults bordering the basin, the NE-striking Portalegre Fault and the E-W-striking Malta Fault. AMS data from 42 sites in the syn-rift sandstone suggest two stretching directions driving the opening of the RPB. The early syn-rift phase I resulted from N-S to NNE-SSW stretching direction with vertical sigma 1, producing normal fault displacement along the E-W-striking Malta Fault and right-lateral transtension along the NE-striking Portalegre Fault, Sitio Sagui and Lagoa do Forno faults. The syn-rift phase II resulted from NW-SE stretching direction with vertical sigma 1, causing normal displacement on NE-striking major faults and left-lateral transtension on E-W-striking major faults. Additionally, the NW-SE extension was responsible for forming NE-striking extensional faults and deformation bands in sedimentary units. The RPB developed due to the intraplate deformation of the Borborema Province during the early stage of the Pangea Breakup and recorded two stretching directions that gradually shifted from NNE-SSW to NW-SE as a consequence of the South America clockwise rotation. The extensional stress orthogonal to the main E-W-striking and NE-striking Precambrian shear zones facilitated the opening and evolution of the RPB

Multidisciplinary approach to constrain kinematics of fault zones at shallow depths: a case study from the Cameros–Demanda thrust (North Spain)

Determining transport direction in thrusts is one of the main issues to study deformation and to achieve reliable balanced cross-sections reconstruction of inverted basins and thrust systems. Anisotropy of Magnetic Susceptibility provides a tool to study deformation in fault rocks through the relationships between the magnetic susceptibility ellipsoid and deformational structures. The Cameros-Demanda Thrust (N Spain) shows a relatively simple history, with an average N-directed movement during the Cenozoic, and provides the possibility of determining the relationships between magnetic fabrics and transport directions in thrusts. The outcropping rocks are Mesozoic limestones in the hangingwall of the main thrust and Cenozoic conglomerates and Albian sandstones and coal in its footwall. Illite crystallinity and organic matter maturity indicate P-T conditions on the order of....The study of AMS in fault rocks (more than 400 samples distributed in 25 sites with fault gouge, breccia and microbreccia) in the Cameros thrust and its comparison with kinematic indicators (foliation, S/C structures and slickenside striations) indicates, in spite of the a priori simple relationships inferred from thrust geometry, a complex history of movements, changing from top-to-the-NW to top-to-the-NE along the history of Cenozoic thrusting. The transport direction is either oblique to the magnetic lineation and perpendicular to the strike of magnetic foliation, and can be checked with shear structures observed in thin sections and other kinematic indicators. The results obtained indicate that AMS can give clues about the transport direction in thrusts depending on the particular structures developed in each studied area

A strength inversion origin for non-volcanic tremor

Non-volcanic tremor is a particularly enigmatic form of seismic activity. In its most studied subduction zone setting, tremor typically occurs within the plate interface at or near the shallow and deep edges of the interseismically locked zone. Detailed seismic observations have shown that tremor is composed of repeating small low-frequency earthquakes, often accompanied by very-low-frequency earthquakes, all involving shear failure and slip. However, low-frequency earthquakes and very-low-frequency earthquakes within each cluster show nearly constant source durations for all observed magnitudes, which implies characteristic tremor sub-event sources of near-constant size. Here we integrate geological observations and geomechanical lab measurements on heterogeneous rock assemblages representative of the shallow tremor region offshore the Middle America Trench with numerical simulations to demonstrate that these tremor events are consistent with the seismic failure of relatively weaker blocks within a stronger matrix. In these subducting rocks, hydrothermalism has led to a strength-inversion from a weak matrix with relatively stronger blocks to a stronger matrix with embedded relatively weaker blocks. Tremor naturally occurs as the now-weaker blocks fail seismically while their surrounding matrix has not yet reached a state of general seismic failure

Preliminary data on the structure and potential of the Tocomar geothermal field (Puna plateau, Argentina).

AbstractThis study presents new stratigraphic, structural and hydrogeological data on the Tocomar geothermal volcanic area (Puna plateau, Central Andes, NW Argentina), together with preliminary geochemical and magnetotelluric data.The main geothermal reservoir is located within the fractured Pre-Palaeozoic–Ordovician units. The reservoir is recharged by meteoric waters. Geothermal fluids upwell where main regional structures intersect secondary structures associated with the development of the Tocomar basin. Preliminary data indicate a reservoir temperature of ∼ 200° C and a local geothermal gradient of ∼ 130° C/km associated with the Quaternary volcanic activity in the Tocomar area