Influence of temperature, salinity and Mg:Ca ratio on microbially-mediated formation of Mg-rich carbonates by Virgibacillus strains isolated from a sabkha environment.

Studies have demonstrated that microbes facilitate the incorporation of Mg into carbonate minerals, leading to the formation of potential dolomite precursors. Most microbes that are capable of mediating Mg-rich carbonates have been isolated from evaporitic environments in which temperature and salinity are higher than those of average marine environments. However, how such physicochemical factors affect and concur with microbial activity influencing mineral precipitation remains poorly constrained. Here, we report the results of laboratory precipitation experiments using two mineral-forming Virgibacillus strains and one non-mineral-forming strain of Bacillus licheniformis, all isolated from the Dohat Faishakh sabkha in Qatar. They were grown under different combinations of temperature (20°, 30°, 40 °C), salinity (3.5, 7.5, 10 NaCl %w/v), and Mg:Ca ratios (1:1, 6:1 and 12:1). Our results show that the incorporation of Mg into the carbonate minerals is significantly affected by all of the three tested factors. With a Mg:Ca ratio of 1, no Mg-rich carbonates formed during the experiments. With a Mg:Ca ratios of 6 and 12, multivariate analysis indicates that temperature has the highest impact followed by salinity and Mg:Ca ratio. The outcome of this study suggests that warm and saline environments are particularly favourable for microbially mediated formation of Mg-rich carbonates and provides new insight for interpreting ancient dolomite formations

Remote sensing of inland Sabkha and a study of the salinity and temporal stability for sustainable development: A case study from the West coast of Qatar

The inland sabkha of the Arabian Gulf is important to study for the occurrence of minerals, rocks, soil salinity, and stability of the sabkha due to the high demand for infrastructure and agriculture development region. This study describes the spectral absorptions of evaporite minerals, discriminates rocks, maps salt crusts, gypsiferous soil flats, and soil salinity, and studies the temporal stability of an inland sabkha of the Dukhan area, west coast of the State of Qatar. This was performed using satellite data of the Hyperion of EO1, ASTER of Terra, and multispectral instrument (MSI) of Sentinel-2. The occurrence of minerals in the area is detected using Hyperion data by the linear spectral unmixing (LSU) method and studied for their spatial distribution. The different geological formations of the sabkha were discriminated by using the VNIR (visible and near-infrared) and SWIR (shortwave infrared) spectral bands from ASTER by principal component analysis (PCA). The image developed by using the principal components (R:PC2, G:PC3, B:PC5) showed the formations in different tones. Salinity of the area was mapped using monthly data of MSI from 2018 to 2020 by normalized difference salinity index (NDSI) (band11-band12)/(band11 + band12). The results of the index displayed the distribution of salinity in the area. Besides, moisture of the area was studied by using the normalized difference moisture index (NDMI) (b8-b11)/(b8 + b11) and described the temporal stability of the sabkha. All the results of image analyses were validated through field and laboratory studies. The study of laboratory spectra of evaporite minerals namely gypsum, anhydrite, and halite present in the salt crusts and gypsiferous soil flats showed their unique spectral absorptions in between 1.4–1.5 μm and 1.9–2.0 μm whereas, the calcite and dolomite minerals of the carbonate formations exhibited deep absorptions near 2.345 and 2.495 μm respectively.This study was supported by the Qatar National Research Fund under the National Priorities Research Program (grant no NPRP10-0214-170462)

Linking depositional environments and diagenetic processes to porosity evolution and destruction in the Arab Formation reservoirs, Offshore oilfields of Qatar

Introduction: The Jurassic Arab Formation is the main oil reservoir in Qatar. The Formation consists of a succession of limestone, dolomite, and anhydrite. Materials and Methods: A multi-proxy approach has been used to study the Formation. This approach is based on core analysis, thin sections, and log data in selected wells in Qatar. Results: The reservoir has been divided into a set of distinctive petrophysical units. The Arab Formation consists of cyclic sediments of oolitic grainstone/packstone, foraminifera-bearing packstone-wackestone, lagoonal mudstone and dolomite, alternating with anhydrite. The sediments underwent a series of diagenetic processes such as leaching, micritization, cementation, dolomitization and fracturing. The impact of these diagenetic processes on the different depositional fabrics created a complex porosity system. So, in some cases there are preserved depositional porosity such as the intergranular porosity in the oolitic grainstone, but in other cases, diagenetic cementation blocked the same pores and eventually destroyed them. In other cases, diagenesis improved the texture of non-porous depositional texture such as mudstone through incipient dolomitization creating inter-crystalline porosity. Dissolution created vugs and void secondary porosity in otherwise non-porous foraminiferal wackestone and packstone. Therefore, creating a matrix of depositional fabrics versus diagenetic processes enabled the identification of different situation in which porosity where either created or destroyed. Future Directions:By correlating the collected petrographic data with logs, it will become possible to identify certain "facio-diagenetic" signatures on logs which will be very useful in both exploration and production. Studying the micro and nano-porosity will provide a better understanding of the evolution and destruction of its porosity system

Mapping of aeolian deposits of an industrial site in the arid region using the TIR bands of ASTER and study of physicochemical characters and stabilization of sand erosion

This study describes the spectral emissive character of silicate and carbonate minerals of aeolian deposits and maps the deposits and sand encroachments that occurred in and around the site 5/6 of Qatar Fertilizer Company (QAFCO), Qatar using thermal infrared (TIR) bands of ASTER. The results of studies show that the quartz and unaltered silicates have spectral features between 8.12 and 9.27 µm, and the calcite and dolomite have emissivity minima near 11.4 and 11.2 µm, respectively. The mapping of deposits, dunes, and carbonate formations using the bands, and quartz index (QI), and carbonate index (CI) displayed their occurrence, distribution, and direction of sand movement from NW to SE. The sand encroachment was mapped using high spatial resolution satellite data of WorldView-2. The study of physicochemical characteristics of field samples showed the occurrence of sand grains up to 99.81% and the XRD and geochemical analyses represented the presence of quartz, calcite, dolomite, albite, and halite minerals in the deposits. In addition, the bacterial strains isolated from the samples indicated high urease activity leading to precipitation of carbonate minerals via microbially induced calcite precipitation (MICP) processes, and demonstrated high potential for utilization for sand stabilization of the QAFCO site

Sentinel-2 image transformation methods for mapping oil spill – A case study with Wakashio oil spill in the Indian Ocean, off Mauritius

Although several indices have been constructed and available at the Index database (IDB) for Sentinel-2 satellite to map and study several earth resources, no indices have been developed to map oil spill. We constructed band ratios (5 + 6)/7, (3 + 4)/2, (11+12)/8 and 3/2, (3 + 4)/2, (6 + 7)/5 using the high-resolution MSI (multi-spectral instrument) visible-near infrared-shortwave infrared spectral bands of Sentinel-2 by summing-up the bands representing the shoulders of absorption features as numerator and the band located nearest to the absorption feature as denominator to discriminate oil spill, and demonstrate the potential of this method to map the Wakashio oil spill which occurred in the Indian Ocean, off Mauritius. The resulted images discriminated the oil spill well. We also decorrelated the spectral bands 4, 3 and 2 by studying the spectral band absorptions and discriminated the spill as very thick, thick and thin. The results of decorrelation stretch method exhibited the distribution of types of oil spill in a different tone, distinctly. Both the image transformation methods (band ratios and decorrelation stretch methods) showed their capability to map oil spills, and these methods are recommended to use for similar spectral bands of other sensors to map oil spills. • This study demonstrated the application of band ratios and decorrelation stretch methods to map oil spill. • The methods discriminated the oil spill off Mauritius, and showed spill thicknesses from the Sentinel-2 data. • The new methods are recommended to use for the spectral bands of other sensors to map oil spill.This work was supported by the Qatar University’s International Research Collaboration Co-Funds project (IRCC-2019-002). The authors are thankful to the Copernicus, European Space Agency for sharing the Sentinel-2 data through the Sentinel open access hub. The authors are thankful to Dr. Damià Barceló, the Editor in Chief and anonymous reviewers of the journal for their valuable reviews and constructive comments that have helped to present the work lucidly. The authors are thankful to Dr. Damià Barceló, Editor in Chief and anonymous reviewers of the journal for their valuable reviews, providing comments and suggestions that have helped to present the work lucidly. Open access funding provided by the Qatar National Library

Monitoring oil spill in Norilsk, Russia using satellite data.

This paper studies the oil spill, which occurred in the Norilsk and Taimyr region of Russia due to the collapse of the fuel tank at the power station on May 29, 2020. We monitored the snow, ice, water, vegetation and wetland of the region using data from the Multi-Spectral Instruments (MSI) of Sentinel-2 satellite. We analyzed the spectral band absorptions of Sentinel-2 data acquired before, during and after the incident, developed true and false-color composites (FCC), decorrelated spectral bands and used the indices, i.e. Snow Water Index (SWI), Normalized Difference Water Index (NDWI) and Normalized Difference Vegetation Index (NDVI). The results of decorrelated spectral bands 3, 8, and 11 of Sentinel-2 well confirmed the results of SWI, NDWI, NDVI, and FCC images showing the intensive snow and ice melt between May 21 and 31, 2020. We used Sentinel-2 results, field photographs, analysis of the 1980-2020 daily air temperature and precipitation data, permafrost observations and modeling to explore the hypothesis that either the long-term dynamics of the frozen ground, changing climate and environmental factors, or abnormal weather conditions may have caused or contributed to the collapse of the oil tank.Open access funding provided by the Qatar National Library

Detection of Wakashio oil spill off Mauritius using Sentinel-1 and 2 data: Capability of sensors, image transformation methods and mapping

Oil spill incidents contaminate water bodies, and damage the coastal and marine environment including coral reefs and mangroves, and therefore, monitoring the oil spills is highly important. This study discriminates the Wakashio oil spill, which occurred off Mauritius, located in the Indian Ocean on August 06, 2020 using the Sentinel-1 and 2 data acquired before, during and after the spill to understand the spreading of the spill and assess its impact on the coastal environment. The interpretation of VV polarization images of Synthetic-Aperture Radar (SAR) C-band (5.404 GHz) of Sentinel-1 acquired between July 5 and September 3, 2020 showed the occurrence and distribution of oil spill as dark warped patches. The images of band ratios (5 + 6)/7, (3 + 4)/2, (11 + 12)/8 and 3/2, (3 + 4)/2, (6 + 7)/5 of the Sentinel-2 data detected the oil spill. The images of decorrelated spectral bands 4, 3 and 2 distinguished the very thick, thick and thin oil spills in a different tone and showed clearly their distribution over the lagoon and offshore, and the accumulation of spilled oil on the coral reefs and along the coast. The distribution of post-oil spill along the coast was interpreted using the images acquired after 21 August 2020. The accuracy of oil spill mapping was assessed by classifying the SAR-C data and decorrelated images of the MultiSpectral Instrument (MSI) data using the Parallelepiped supervised algorithm and confusion matrix. The results showed that the overall accuracy is on an average 91.72 and 98.77%, and Kappa coefficient 0.84 and 0.96, respectively. The satellite-derived results were validated with field studies. The MSI results showed the occurrence and spread of oil spill having different thicknesses, and supported the results of SAR. This study demonstrated the capability of Sentinel sensors and the potential of image processing methods to detect, monitor and assess oil spill impact on environment.This work was supported by the Qatar University’s International Research Collaboration Co-Funds project (IRCC-2019-002

Microbial Mats from the Khor Al-Adaid Sabkha, Qatar: Morphotypes and Association with Authigenic Minerals

The sabkhas (i.e., salt flats) of Qatar are among the rare places on Earth where carbonate and sulfate minerals similar to those constituting economically important hydrocarbon reservoirs are still forming today, under the arid conditions that characterize the coastline of the country. Since the 1960's, the sabkhas of Qatar have been studied with great interest as a modern analogue for ancient sedimentary sequences (e.g., Wells, 1962; Illing & Taylor, 1995; Alsharhan & Kendall, 2003). The results of these studies provided important insights for formulating stratigraphic models of subsurface hydrocarbon reservoirs. Notable examples of gas and oil reservoirs that formed in arid, evaporitic environments include the Permo-Triassic Khuff (which is estimated to contain about 15-20% of the world's gas reserves and is of fundamental importance for the economy of Qatar), the Jurassic Arab formations, and the Triassic Kurra Chine, all of the Middle East, and the Permian Zechstein of Northern Europe. Although extremely valuable, most of these early studies were based on purely physical and chemical approaches, which may have not fully captured the complexity of the mineralization processes occurring in the sabkha environment. Indeed, research conducted in more recent years has shown that microorganisms play an important and, as yet, poorly understood role for the mineralization processes occurring in these evaporitic environments (Bontognali et al., 2010; Bontognali et al., 2012; Bontognali et al., 2014; Brauchli et al., 2015; Paulo & Dittrich, 2013; Strohmenger et al., 2011). Here we present the results of a field campaign conducted in the Khor Al-Adaid sabkha, which is located in the southeast of Qatar, in a large tidal embayment composed of two shallow inland lagoons. The main goal of the field campaign was to identify regions of the intertidal zone that are particularly rich in microbial mats, and that represent ideal sites at which to study microbe-mineral interactions. Three sites of interest have been defined.qscienc

Microbially influenced formation of anhydrite at low temperature

Calcium sulfate minerals are abundant in nature – on Earth and on Mars – and important in several fields of material sciences. With respect to gypsum and bassanite, anhydrite represents the anhydrous crystalline phase in the CaSO4–H2O system. Despite years of research, the formation of anhydrite in the laboratory at low temperature remains challenging and, in the geological record, this mineral is mostly interpreted as a secondary phase that form through metamorphic dehydration of gypsum. Here, we present the results of laboratory precipitation experiments showing that anhydrite can form at 35 °C from evaporated seawater through a microbially influenced mineralization process. The experiments were conducted in the presence of extracellular polymeric substances (EPS) produced by bacterial strains isolated from a modern evaporitic environment, the Dohat Faishakh sabkha in Qatar. Without organic molecules, only gypsum formed in parallel control experiments. This finding provides a possible explanation for the origin of several natural occurrences of anhydrite that cannot be satisfactorily explained by existing models and reveals a new precipitation pathway that may have industrial applications.This publication was made possible by the grant NPRP13S-0207-200291 from the Qatar National Research Fund (a member of the Qatar Foundation). The statements made herein are solely the responsibility of the authors

Chlorophyll-a concentrations in the Arabian Gulf waters of arid region: A case study from the northern coast of Qatar

Remote sensing of spectrally active Chlorophyll-a (Chl-a) in the gulf water of an arid region is important to understand the spatial and temporal variations of phytoplankton and biomass in the water. This study characterizes the spectral absorption of Chl-a and detects and maps the Chl-a of Al Arish–Al Ghariyah coastal region of northern Qatar using the data of Hyperion of EO-1, MultiSpectral Instrument (MSI) of Sentinel-2, and Operational Land Imager (OLI) of Landsat-8 satellites. The study of image spectra of Chl-a of coastal water of the Al Ghariyah region using the Hyperion image showed spectral band absorptions near 450 and 475 nm in the blue region and around 640, 730, 760, and 830 nm in the red region. The analysis of Hyperion data using image spectra by linear spectral unmixing (LSU) method showed the occurrence of Chl-a in very shallow and shallow water. The mapping of Chl-a of the Al Arish–Al​ Ghariyah coastal region was carried out using MSI and OLI data by NDCI, 2BDA, 3BDA, and FLH violet algorithms, which showed the concentrations and distributions of the Chl-a in the region. The performance of the algorithms was studied using WorldView-3 data, which provided the R2 values of 60% and the best suitability of the NDCI algorithm and MSI data to map the concentration of Chl-a. All the results were validated using field measurements, in-situ measurements, and laboratory analyses of field samples. The measurements of Chl-a showed the occurrence of poor occurrence of Chl-a and confirmed the imagery results. The remote sensing results with physical and chemical parameters of water samples allowed us to assess Chl-a concentrations in the region. This study evaluates the sensor’s capability and applications of satellite data and algorithms to map concentrations of Chl-a in the Gulf waters of the arid region.Open Access funding provided by the Qatar National Library. This study is supported by Qatar University Grant no. QUEX-ESC-QAFCO-20/21-1. The authors are thankful for the USGS Data Management and Information Distribution (DMID) (https://glovis.usgs.gov/) for sharing the Hyperion and Landsat-8 data, and the Copernicus, European Space Agency for sharing the Sentinel-2 data through sentinel open access hub (https://sentinel.esa.int/web/sentinel/sentinel-data-access). The Digital Globe, USA is acknowledged for providing the WorldView-2 satellite image (Image ID: 104001004D7C7D00) that was acquired on n June 29, 2019. Mr. Fahad Syed Asim, Mr. Faisal Muthar Al-Quaiti, and Mr. Reyniel M. Gasang are thanked for their support in the fieldwork. Mr. Mark Edward Chatting is thanked for taking underwater photography and collecting underwater samples. The sediments, water, and biological samples for different analyses are organized by Ms. Thoraya Haidar S A Alyafei. The classification and naming of biological samples are provided by Ms. Aisha Ahmed Al Ashwal. Mr. Hamood Abdulla Alsaadi and Ms. Marwa Mustufa Al-Azhari have analyzed water samples for major and trace element concentrations. The authors are thankful to Prof. Seongjin Hong, the Associate Editor and anonymous reviewer of the journal for the valuable reviews, providing comments and suggestions that have helped to present the work lucidly